全文获取类型
收费全文 | 222篇 |
免费 | 8篇 |
专业分类
测绘学 | 3篇 |
大气科学 | 8篇 |
地球物理 | 65篇 |
地质学 | 44篇 |
海洋学 | 50篇 |
天文学 | 43篇 |
综合类 | 1篇 |
自然地理 | 16篇 |
出版年
2021年 | 2篇 |
2019年 | 4篇 |
2018年 | 4篇 |
2017年 | 7篇 |
2016年 | 8篇 |
2015年 | 3篇 |
2014年 | 7篇 |
2013年 | 14篇 |
2012年 | 10篇 |
2011年 | 15篇 |
2010年 | 7篇 |
2009年 | 10篇 |
2008年 | 13篇 |
2007年 | 7篇 |
2006年 | 5篇 |
2005年 | 12篇 |
2004年 | 7篇 |
2003年 | 11篇 |
2002年 | 9篇 |
2001年 | 1篇 |
2000年 | 12篇 |
1999年 | 4篇 |
1998年 | 4篇 |
1997年 | 3篇 |
1996年 | 2篇 |
1995年 | 3篇 |
1994年 | 2篇 |
1993年 | 7篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1989年 | 3篇 |
1988年 | 1篇 |
1986年 | 2篇 |
1985年 | 5篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1977年 | 3篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 2篇 |
1973年 | 1篇 |
1972年 | 3篇 |
1971年 | 1篇 |
排序方式: 共有230条查询结果,搜索用时 296 毫秒
61.
We have investigated the kinetics of Fe(III) complexation by several organic ligands including fulvic acid, citrate and ethylenediaminetetraacetic acid (EDTA). Particular attention was given to examination of the effect of competitive divalent cations (Me: Ca2+ and Mg2+) at concentrations typical of seawater on the complexation rate. All experiments were conducted in 0.5 M NaCl solution buffered with 2 mM bicarbonate at pH 8.0 in the absence and presence of Me (25 μM-250 mM). The rate constants of complex formation determined by using the competitive ligand (5-sulfosalicylic acid) method combined with visible spectrophotometry ranged from 3.3 × 104 to 3.2 × 106 M−1 s−1. The mechanism of complexation was then examined based on a kinetic model. When EDTA was used as a ligand, Me at concentrations comparable to the ligand markedly retarded the rate of iron complex formation due to the predominance of an adjunctive pathway (where iron-ligand complex is formed via direct association of iron to Me-ligand complex). In contrast, the competing effect of Me on iron complexation by citrate and fulvic acid was observed only when the Me concentration was in excess of the ligand by more than a factor of 10-1000. The kinetic model suggests that iron complexation by fulvic acid occurs predominantly via a disjunctive pathway (where iron complexation by ligand occurs after dissociation of Me from Me-ligand complex) at concentrations of divalent cations and natural organic matter typical of natural waters including seawater and freshwater. 相似文献
62.
Local time variation of geomagnetic transfer functions 总被引:1,自引:0,他引:1
Masahiko Takeda 《Geophysical Journal International》1997,130(3):765-770
The local time (LT) variation of the geomagnetic transfer function at the 32-min period was examined for observatories distributed worldwide. Two distinct variation types (types 1 and 2) were found in the real part of A. Type 1 is conspicuous at lower latitudes and its seasonal variation is small, whereas type 2 is found at higher latitudes and has its maximum in summer. These two types of LT variation are seen globally and are conspicuous when solar activity is high. The amplitudes of both types of variation vary from 0.018 to 0.078, and are independent of the mean values at each observatory. These values are relatively small, but the amplitude of Chambon la Foret is larger than the mean value, which shows that Au changes its sign in local time. The amplitudes of type 1 and 2 variations decrease and increase with geomagnetic latitude, respectively. These features suggest that they are generated by some global external fields. The most probable cause is the Sq field, although the Dp field may contribute to type 1 variation. On the other hand, for the islands of the Pacific Ocean at low latitudes, such as Honolulu and Chichijima, the type 1 variation appears not in the real but in the imaginary part of A, which suggests that currents induced in the ocean also contribute to the local time variation. 相似文献
63.
64.
65.
Eriko Kamiya Shinji Izumiyama Masahiko Nishimura James G. Mitchell Kazuhiro Kogure 《Journal of Oceanography》2007,63(1):101-112
Flow cytometry (FCM) is now becoming a routine tool for the enumeration and optical characterization of bacteria in marine
environments. We investigated the effects of sample fixation and storage upon flow cytometric determination of marine bacteria.
Fixed and unfixed seawater samples were analyzed by FCM immediately aboard ship and/or later in the laboratory, and the appearances
of the fluorescence signals and bacterial counts of these samples were compared. Fixation and storage led to the formation
of multiple peaks in fluorescence histograms; this was also seen in 22 out of 36 samples frozen in liquid nitrogen. Fixation
did not, but storage did induce a decrease of bacterial counts: a rapid decrease during the first 3 days followed by a slower
decline. The decline of cell numbers in stored samples was expressed by a regression model. Our studies indicate that precaution
is necessary when interpreting the data from fixed and/or stored marine bacterial samples analyzed by FCM. The possibility
that the procedure of fixation and storage leads to the appearance of high DNA and low DNA bacterial groups should be considered. 相似文献
66.
Changes in the lower limit of mountain permafrost between 1973 and 2004 in the Khumbu Himal, the Nepal Himalayas 总被引:2,自引:0,他引:2
Kotaro Fukui Yoshiyuki Fujii Yutaka Ageta Katsuhiko Asahi 《Global and Planetary Change》2007,55(4):251-256
Because the Khumbu Himal of the Nepal Himalayas lacks long-term climate records from weather stations, mountain permafrost degradation serves as an important indicator of climate warming. In 1973, the permafrost lower limit was estimated to be 5200–5300 m above sea level (ASL) on southern-aspect slopes in this region. Using ground-temperature measurements, we examined the mountain permafrost lower limit on slopes with the same aspect in 2004. The results indicate that the permafrost lower limit was 5400–5500 m ASL in 2004. The permafrost lower limit was estimated to be 5400 to 5500 m on slopes with a southern aspect in the Khumbu Himal in 1991 using seismic reflection soundings. Thus, it is possible that the permafrost lower limit has risen 100–300 m between 1973 and 1991, followed by a stable limit of 5400 to 5500 m over the last decade. An increase in mean annual air temperature of approximately 0.2 to 0.4 °C from the 1970s to the 1990s has indicated a rise in the permafrost lower limit of 40 to 80 m at the Tibetan Plateau. The rise in the mountain permafrost lower limit in the Khumbu Himal exceeds that of the Tibetan Plateau, suggesting the possibility of greater climate warming in the Khumbu Himal. 相似文献
67.
Kurihara R Watanabe E Ueda Y Kakuno A Fujii K Shiraishi F Hashimoto S 《Marine pollution bulletin》2007,54(9):1315-1320
Estrogenic activity was determined in sediments collected from Tokyo Bay. Sampling was performed at five stations including the site near the sewage treatment plant. The most estrogenic sediment collected near the sewage treatment plant was fractionated into ten fractions using normal-phase high-performance liquid chromatography. Chemical analysis was carried out for each fraction and nonylphenol (NP, 20,700 ng g−1 dry wt) was detected at a higher concentration than estron (2.39 ng g−1 dry wt) and 17β-estradiol (<0.7 ng g−1 dry wt). Furthermore, each fraction was administered to male mummichogs (Fundulus heteroclitus), and vitellogenin (Vtg) was measured after two weeks. The induction of Vtg was observed; this estrogenic potency could be attributed to the NP content in this fraction. This is the first report to suggest that the high NP concentration in the sediments from Tokyo Bay has the potential to induce Vtg in wild fish. 相似文献
68.
Yuichi Fujii 《Icarus》2009,201(2):795-801
We performed low-velocity impact experiments of gypsum spheres with porosity ranging from 0 to 61% and diameter ranging from 25 to 83 mm. The impact velocity was from 0.2 to 22 m/s. The target was an iron plate. The outcome of gypsum spheres with porosity 31-61% was different from those of non-porous ice [Higa M., Arakawa, M., Maeno, N., 1996. Planet. Space Sci. 44, 917-925; Higa M., Arakawa, M., Maeno, N., 1998. Icarus 133, 310-320] and non-porous gypsum. In between the intact and fragmentation modes, the outcome of the non-porous ice and gypsum was crack growth at the impact point. However, the outcome of the porous gypsum was compaction. We found that the restitution coefficients of the porous gypsum spheres were all in a similar range, in spite of the difference of the porosity and size at impact velocities up to about 10 m/s where they begin to be fragmented in pieces. Moreover, there is not a large difference between the restitution coefficient of porous and non-porous gypsum. These results collectively indicate that restitution coefficient of gypsum spheres of cm-size is not strongly dependent upon the porosity and compaction process. 相似文献
69.
Frédéric Moynier Toshiyuki Fujii Francis Albarède 《Meteoritics & planetary science》2009,44(11):1735-1742
Abstract— We explore the possibility that Te isotopic anomalies measured in Ca‐Al‐rich inclusions (Fehr et al. 2009) and in leachates of carbonaceous chondrites (Fehr et al. 2006) may be due to mass‐independent effects controlled by nuclear field shift rather than to nucleosynthetic processes. Fehr et al.'s spectrum of mass‐independent anomalies of Te isotopes shows a smooth correlation with mass number and nuclear charge distribution. Ratios of even to odd isotopes, as the 125Te/126Te ratio used by these authors for normalization are particularly prone to nuclear field shift effects. We show that the alternative normalization of isotopic ratios to 130Te/126Te strongly reduces the trend of isotopic fractionation with mass number, leaving only 125Te as truly anomalous. For both normalizations (125Te/126Te and 130Te/126Te), Fehr et al.'s results fit the theory of Bigeleisen (1996), which suggests that the nuclear field shift effect can potentially account for the observed Te isotope abundances, as an alternative to nucleosynthetic processes. We propose that these mass‐independent effects may be acquired during accretion of sulfides from the solar nebula. 相似文献
70.
Wataru Kanda Mitsuru Utsugi Yoshikazu Tanaka Takeshi Hashimoto Ikuko Fujii Toshiaki Hasenaka Nobuaki Shigeno 《Journal of Volcanology and Geothermal Research》2010,189(1-2):158-171
Since August 2000, we have recorded the total intensity of the geomagnetic field at the summit area of Kuchi-erabu-jima volcano, where phreatic eruptions have repeatedly occurred. A time series analysis has shown that the variations in the geomagnetic field since 2001 have a strong relationship to an increase in volcanic activity. These variations indicate thermal demagnetization of the subsurface around the presently active crater. The demagnetization source for the early variations, until summer 2002, was estimated at about 200 m below sea level. For the variations since 2003, the source was modeled on the basis of the expansion of a uniformly magnetized ellipsoid. The modeling result showed that the source is located at 300 m above sea level beneath the crater. We carried out an audio-frequency magnetotelluric survey with the aim of obtaining a relation between the demagnetization source and the shallow structure of the volcano. A two-dimensional inversion applied to the data detected two good conductors, a shallow thin one which is restricted to a region around the summit area, while the other extends over the edifice at depths between 200 and 800 m. These conductors are regarded as clay-rich layers with low permeability, which were assumed to be generated through hydrothermal alteration. The demagnetization source for the early variations was possibly located at the lower part of the deep conductor and the source after 2003 lies between the two conductors, where groundwater is considered to be abundant. Based on these results, as well as on seismological, geodetic, and geochemical information, we propose a heating process of the Kuchi-erabu-jima volcano. In the initial stage, high-temperature volcanic gases supplied from the deep-seated magma remained temporarily at the level around the lower part of the less permeable deep conductor since the ascent path had not yet been established. Then, when the pathway developed as a result of repeated earthquakes, it became possible for a massive flux of volcanic gases to ascend through the conductor. The high temperature gases reached the aquifer located above the conductor and the heat was efficiently transported to the surrounding rocks through the groundwater. As a consequence, an abrupt increase of the gas flux and diffusion of the heat through the aquifer occurred and the high-temperature zone expanded. Since the high-temperature zone is located beneath another conductor, which acts as caprock, we assume that the energy of the phreatic explosion is accumulated there. 相似文献