Ore and Skarn Mineralogy of the Yamato Mine,Yamaguchi Prefecture,Japan, with Emphasis on Silver‐, Bismuth‐, Cobalt‐, and Tin‐bearing Sulfides

Assemblages and chemical compositions of ore minerals from the Yamato mine, Yamaguchi Prefecture, Japan, were investigated in detail to clarify its characteristics as a skarn deposit. Special attention was paid to silver‐, bismuth‐, cobalt‐, and tin‐bearing sulfide minerals and native gold at the mine, which are described here for the first time. Samples of arsenopyrite‐dominant massive ore, and garnet‐rich, clinopyroxene‐garnet‐rich, and wollastonite‐bearing skarn ores were collected from the mine dump. Arsenopyrite is the most abundant ore mineral (>80 vol.%) in the massive ore, in association with both As‐poor/free and As‐bearing pyrite. The major ore minerals in the skarn specimens are pyrite, pyrrhotite, arsenopyrite, chalcopyrite, galena, and sphalerite, along with minor argentite, Ag‐Pb‐Bi sulfate, matildite, bismuthinite, native bismuth, molybdenite, scheelite, stannite, stannoidite, cassiterite, cobaltite, gersdorffite, and Co‐rich violarite. In addition, native gold is observed in the interstices of gangue minerals. Based on the mineral assemblages and textures of the specimens examined, the major ore minerals formed in the early stage of mineralization, and the Bi‐, Ag‐, Co‐, Ni‐, As‐ and Sn‐mineralization occurred in the middle stage. Native gold was deposited in the late stage. The estimated formation temperature of the middle mineralization stage was 312±5 °C, according to iron and zinc partitioning between stannite and coexisting sphalerite. The mineralogical properties and mineralization process of the Yamato mine are consistent with those of common skarn‐ and vein‐type ore deposits associated with ilmenite‐series granitoids in the San‐yo and San‐in districts.     

Perturbed physics ensemble using the MIROC5 coupled atmosphere–ocean GCM without flux corrections: experimental design and results

In this study, we constructed a perturbed physics ensemble (PPE) for the MIROC5 coupled atmosphere–ocean general circulation model (CGCM) to investigate the parametric uncertainty of climate sensitivity (CS). Previous studies of PPEs have mainly used the atmosphere-slab ocean models. A few PPE studies using a CGCM applied flux corrections, because perturbations in parameters can lead to large radiation imbalances at the top of the atmosphere and climate drifts. We developed a method to prevent climate drifts in PPE experiments using the MIROC5 CGCM without flux corrections. We simultaneously swept 10 parameters in atmosphere and surface schemes. The range of CS (estimated from our 35 ensemble members) was not wide (2.2–3.2?°C). The shortwave cloud feedback related to changes in middle-level cloud albedo dominated the variations in the total feedback. We found three performance metrics for the present climate simulations of middle-level cloud albedo, precipitation, and ENSO amplitude that systematically relate to the variations in shortwave cloud feedback in this PPE.     

赤道不稳定波对海气相互作用影响的数值模拟分析

赤道不稳定波 (tropical instability waves) 存在于热带东太平洋赤道附近, 通常于每年的春末夏初出现, 以约0.6 m/s速度向西传播, 波周期为20～40天左右, 波长约为1000～2000 km.本文利用一个全球高分辨率海气耦合模式对赤道不稳定波在赤道附近的热量输送进行分析, 表明赤道不稳定波产生指向赤道的热通量, 从而部分抵消了热带东太平洋地区由Ekman辐散和温度平流导致的强冷却效应, 维持热带地区的热量平衡.其对赤道冷舌区的增暖作用可以消除和减弱气候模式中热带东太平洋地区的系统性冷偏差, 能使冷舌的强度和分布得到合理的改善, 对气候模式的改进和发展具有潜在贡献.赤道不稳定波还可以改变赤道海洋上空低层大气层结稳定度, 导致近地层强的风场辐合辐散, 并进一步影响大气混合层的温度、 风场等气象要素.模拟分析结果还表明, 赤道不稳定波对大气强迫产生二次响应, 改变赤道上空逆温层的垂直位移和逆温强度.研究赤道不稳定波对热带海洋气候及其海气相互作用机理的理解具有重要意义.     

Trans-boundary and in-country transport of air pollutants observed in Kobe,Japan by high frequent filter pack sampling method

The seasonal intensive sampling of gases and particulate matter in ambient air was conducted at the site established in urban area of Japan to study the seasonal difference of the temporal variation of gases and particulate matter concentrations in urban atmosphere as well as to illustrate the different transport regimes that impacts air pollutants. The sample was collected by the four-stage filter-pack method with 6-h interval for one week in four seasons (spring, summer, autumn and winter). The trans-boundary transport of air pollutants with high concentration was characteristically observed in the spring sampling. On the other hand, we could successfully detect the in-country transports of air pollutants in the summer sampling. Four-season’s intensive survey considered, we could show the characteristic transport of air pollutants to provide the episodic high concentration for ambient air in the urban area of Japan, and successfully illustrate the seasonal-dependent transport regimes to impact on air pollutants.     

Geochemistry of Mesozoic intracontinental basalts from Yunnan, southern China: Implications for geochemical evolution of the subcontinental lithosphere

Summary Southwestern Yunnan, comprising the Yangtze and Shan-Thai microcontinents and the Simao block, has successively undergone subduction of an oceanic plate, followed by a collision of the microcontinents and intracontinental rifting associated with basaltic volcanism during Late Paleozoic to Mesozoic.The Triassic Nanjian basalts, erupted on the Yangtze microcontinent, have more enriched isotopic ratios and higher LREE/HFSE and LREE/HREE ratios. This suggests the existence of an enriched subcontinental lithosphere under the Yangtze microcontinent which stabilized over long periods of the earth's history (> 2Ga).The Middle Jurassic Simao basalts have more depleted geochemical features and also have element enrichments characteristic of a subduction zone environment, although the basalts were erupted in an intracontinental graben. It may be inferred that the lithospheric mantle of the Simao block was modified by subduction processes during Latest Carboniferous to Late Triassic prior to the onset of the Middle Jurassic continental rifting. The lack of correlation between depletion of HFSE, Y and HREE, and relative enriched Nd isotopic ratios suggests that the source depletion of the Simao basalts is not an old feature and has been contemporaneous with the subduction-related enrichment through mantle metasomatism shortly before the basalts were produced.The Middle Jurassic Baoshan basalts which erupted during the continental rifting on the Shan-Thai microcontinent have an Sr-Nd isotopic composition similar to the bulk earth and higher concentrations of incompatible trace elements. These features suggest that the subcontinental lithosphere under the Shan-Thai microcontinent underwent mantle metasomatism just prior to eruption of the Baoshan basalt.

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Geochemie mesozoischer interkontinentaler Basalte aus Jünnan, Südchina: Hinweise auf die geochemische Entwicklung der subkontinentalen Lithosphäre

Zusammenfassung Südwestjünnan umfaßt den Jangtse und den Shan-Thai Mikrokontinent und den Simao Block. Das Gebiet wurde von aufeinander folgenden Subduktionsphasen einer ozeanischen Platte betroffen, auf die Kollision der Mikrokontinente und interkontinentales Rifting folgte. Dieses war mit basaltischem Vulkanismus während des späten Paläozoikums bis ins Mesozoikum assoziiert.Die triassischen Nanjian-Basalte, die auf dem Jangtse Mikrokontinent eruptierten, haben mehr angereicherte Isotopenverhältnisse und höhere LREE/HFSE und LREE/HREE Verhältnisse. Dieses weist auf eine angereicherte subkontinentale Lithosphäre unter dem Jangtse Mikrokontinent hin, die sich während langer Perioden der Erdgeschichte stabilisierte (>2Ga).Die mittel jurassischen Simao-Basalte haben eine mehr verarmte geochemische Signatur aber auch Elementanreicherungen, die für ein Subduktionszonen-Milieu charakteristisch sind, obwohl die Basalte in einem interkontinentalen Graben ausgetreten sind. Man kann daraus schließen, daß der lithosphärische Mantel des Simao-Blockes durch Subduktionsprozesse während des jüngsten Karbons bis in die späte Trias vor dem Beginn des mittel-jurassischen kontinentalen Riftings modifiziert worden war. Das Fehlen einer Korrelation zwischen der Anreicherung von HFSE, Y und HREE und relativ angereicherter Nd-Isotopenverhältnisse weist darauf hin, daß die Verarmung der Quelle der Simaobasalte nicht weit zurückreicht. Sie dürfte viel eher gleichaltrig mit der subduktions-bedingten Anreicherung durch Mantel-Metasomatose kurz vor der Entstehung der Basalte sein.Die mittel-jurassischen Baoshan-Basalte, die während des kontinentalen Riftings auf den Shan-Thai Mikrokontintent eruptierten, haben eine Sr-Nd-Isotopensignatur, die ähnlich der Gesamterde ist, jedoch höhere Konzentrationen inkompatibler Spurenelemente zeigt. All dies legt nahe, daß die subkontinentale Lithosphäre unter dem Shan-Thai-Mikrokontinent kurz vor der Eruption der Baoshan-Basalte von Mantel-Metasomatose betroffen worden ist.

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With 8 Figures

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Visiting Fellow, Geology Department, Australian National University, Australia     

Ventilation revealed by the observation of dissolved oxygen concentration south of the Kuroshio Extension during 2012–2013

From the moored buoy observation at \(33.9^{\circ }\)N, \(144.9^{\circ }\)E south of the Kuroshio Extension (KE), we obtained Eulerian time series of dissolved oxygen concentration (DO) at 200, 400, and 600 m depths from June 2012 to March 2013. We observed ventilation by meso- and submesoscale processes that transport water southward across the KE jet. First, the cyclonic mesoscale eddy in June 2012 substantially depressed DO at depths of 400 and 600 m but maintained DO at 200 m, suggesting near-surface lateral transport of high-DO water derived from the north of the KE. Second, subduction of high-DO (>230 \({\upmu }\)mol kg\(^{-1}\)) water to a depth of 600 m was observed from early February to March 2013, associated with a mesoscale/submesoscale meandering of the KE jet. In mid-March 2013, shipboard hydrographic data were collected where the water mass at the mooring site would be advected by the eastward current on the southern flank of the KE. Based on these data, the subduction event was identified as an intrusion of an anomalously thick water mass from approximately 400–900 dbar. Ventilation of the subtropical mode water at a depth of 200 m around a subsurface DO maximum layer was detected as a rapid rise in DO in January 2013. This occurred after a significant seasonal decrease in DO at a rate of \(-0.130 \pm 0.007\) \({\upmu }\)mol kg\(^{-1}\) day\(^{-1}\) from July to December 2012.     

Global distribution and atmospheric transport of chlorinated hydrocarbons: HCH (BHC) isomers and DDT compounds in the Western Pacific,Eastern Indian and Antarctic Oceans

Concentrations of chlorinated hydrocarbons such as HCH isomers and DDT compounds were determined in air and surface water samples taken from the Western Pacific, Eastern Indian and Antarctic Oceans. The most interesting finding was their presence in measurable concentrations in the Antarctic Ocean. Chlorinated hydrocarbon pesticides are widely distributed in the open ocean environment over both the northern and southern hemispheres, and some characteristic distribution patterns of pesticide species in different oceanic regions were observed both in air and water samples. HCH residues found in the northern hemisphere were much higher in concentration than those in the southern hemisphere. On the other hand, higher concentrations of DDT residues were found in the tropical regions, but their levels were not so different between both the northern and southern hemispheres. HCH isomers found in the northern hemisphere had the following order of concentrations:-HCH> HCH>-HCH, while in the southern hemisphere-HCH was apparently dominant. DDT compound compositions were rather uniform in all the oceans surveyed, and more than 50% wasp,p-DDT. These facts can be explained by the world wide situation regarding pesticide use and the physicochemical properties of the pesticides such as their vapor pressures and water solubilities. In addition, the meridional circulation of the atmosphere, particularly the mass flows of the Hadley and Ferrel cells in the troposphere, also contributes to the atmospheric transport and global distribution of these pesticides.     

Time-series observation of dissolved inorganic carbon and nutrients in the northwestern North Pacific

Time-series measurements of dissolved inorganic carbon (DIC) and nutrient concentrations were conducted in the northwestern North Pacific from October 2002 to August 2004. Assuming that data obtained in different years represented time-series seasonal data for a single year, vertical distributions of DIC and nutrients showed large seasonal variabilities in the surface layer (∼100 m). Seasonal variabilities in normalized DIC (nDIC) and nitrate concentrations at the sea surface were estimated to be 81–113 μmol kg⁻¹ and 12.7–15.7 μmol kg⁻¹, respectively, in the Western Subarctic Gyre. The variability in nutrients between May and July was generally at least double that in other seasons. In the Western Subarctic Gyre, estimations based on statistical analyses revealed that seasonal new production was 39–61 gC m⁻² and tended to be higher in the southwestern regions or coastal regions. The seasonal new productions in the northwestern North Pacific were two or more times higher than in the North Pacific subtropical gyre and the northeastern North Pacific. It is likely that this difference is due to spatial variations in the concentrations of trace metals and the species of phytoplankton present. In addition, from estimations of surface pCO₂ it was verified that the Western Subarctic Gyre is a source of atmospheric CO₂ between February and May and a sink for CO₂ between July and October.     

赤道不稳定波能量收支的数值模拟分析

最新海表温度卫星观测资料分析表明在赤道东太平洋和大西洋附近存在赤道不稳定波（tropical instability waves）。赤道不稳定波通常于每年春末夏初出现,以约0.6 m/s速度向西传播,周期为20~40天左右,波长约为1 000~2 000 km,可改变赤道附近海洋的热量平衡,并引发强烈的局地海气作用。利用CCSR/NIES/FRCGC AOGCM MIROC 100年的模式输出结果,计算了赤道不稳定波的爆发时间、波长、传播速度、周期,并与观测资料作对比分析,以考察模式对赤道不稳定波的模拟能力。结果表明,模式较好地再现了热带太平洋的海洋内部中尺度动力-热力作用过程,成功模拟了赤道不稳定波的基本特征,发现赤道不稳定波主要存在赤道南北不超过6个纬度的浅层海洋中,除赤道表层外4~6 ?N海洋温跃层中也有赤道不稳定波。对赤道不稳定波的能量进行诊断分析表明其能量主要来自赤道附近洋流经向切变产生的正压不稳定,赤道以北海洋温跃层中赤道不稳定波能量主要来自由浮力作用产生的斜压不稳定,两者的共同作用形成了赤道不稳定波的赤道不对称结构。     

New approach for optimal perturbation method in ensemble climate prediction with empirical singular vector

In this study, a new method is developed to generate optimal perturbations in ensemble climate prediction. In this method, the optimal perturbation in initial conditions is the 1st leading singular vector, calculated from an empirical linear operator based on a historical model integration. To verify this concept, this method is applied to a hybrid coupled model. It is demonstrated that the 1st leading singular vector from the empirical linear operator, to a large extent, represents the fast-growing mode in the nonlinear integration. Therefore, the forecast skill with the optimal perturbations is improved over most lead times and regions. In particular, the improvement of the forecast skill is significant where the signal-to-noise ratio is small, indicating that the optimal perturbation method is effective when the initial uncertainty is large. Therefore, the new optimal perturbation method has the potential to improve current seasonal prediction with state-of-the-art coupled GCMs.