Identification and characterization of secondary minerals formed in tungsten mine tailings using transmission electron microscopy

Secondary minerals formed in tailings derived from a W-rich deposit were investigated in detail using transmission electron microscopy (TEM). The study focused on secondary minerals that formed in the vicinity of oxidized sphalerite [ZnS] and tennantite [Cu₁₀(Fe,Zn)₂As₄S₁₃] grains. Samples for TEM analysis were prepared directly from petrographic thin sections using a focused ion beam instrument. This method insured that spatial relationships among primary grains, secondary minerals and the pore spaces were maintained. The results from this study indicate that the secondary coatings associated with sphalerite and tennantite are composed of several discrete phases. The phases identified in this study include an Fe–Zn–As–O phase, secondary sulfides, native Cu, an Fe–Si–O phase, an In–O phase, and wulfenite [PbMoO₄]. The Fe–Zn–As–O phase precipitates directly from the pore water and the nearby primary mineral grains act as a source for some of the elements (e.g., Zn from sphalerite, As from tennantite). Secondary Cu sulfides were found at the outer margins of sphalerite and roquesite [CuInS₂] grains. It is likely that these Cu sulfides form as a result of interactions between the primary grain and aqueous Cu(II) present in the pore water, similar to what occurs in supergene environments. A secondary sulfide that was composed of variable amounts of Cu, Zn, As, Fe and S was also identified along the outer margins of tennantite. Native Cu was found in association with chalcopyrite [CuFeS₂] inclusions that were present in one of the sphalerite grains and probably represents a low-temperature secondary phase. The oxidation of chalcopyrite in the presence of aqueous Si leads to the formation of a nanocrystalline or amorphous Fe–Si–O phase. Roquesite oxidation leads to the formation of a crystalline In–O phase, which is likely dzhalindite [In(OH)₃]. Wulfenite was found in the interstitial voids present in the Fe–Zn–As–O phase suggesting that it forms by direct precipitation from the local pore water. The results from this study indicate that secondary coatings consist of complex secondary phases that may only be distinguished at the nanoscale. The TEM investigations reveal details regarding mineralogical sinks and sources for aqueous components that may otherwise be overlooked.     

Abundance of seagrass (Zostera marina L.) and macroalgae in relation to the salinity-temperature gradient in Yaquina Bay, Oregon, USA

The relative abundances of the seagrass,Zostera marina L., and associated macroalgae were examined for Yaquina Bay, Oregon, U.S.A., to investigate variability in autotroph abundance along the salinity-temperature gradient and the potential for nuisance algal blooms. Possible explanations for the patterns in autotroph abundances were explored through examination of their correlations with the physicochemical characteristics of the water column. Study sites were established in each of three zones in the estuary defined by temperature and salinity and were sampled monthly June through September 1998 and in July 1999.Z. marina and macroalgal cover andZ. marina shoot density were measured in 0.25-m² plots at each site. After cover estimates and shoot counts were made, material was harvested for determination ofZ. marina and macroalgal biomass. Water column variables were measured from stations near each study site and composited on a depth-averaged, monthly basis for each zone. BothZ. marina and green macroalgal abundance differed between sites, over the summer in 1998, and between years. Seasonal patterns were most obvious forZ. marina at the site closest to the ocean while the pattern in macroalgal abundance suggested a bloom moving up river as summer progressed. The physicochemical characteristics of the zones differed with the season and could be related to the patterns inZ. marina and macroalgal abundance. In particular, salinity was positively correlated withZ. marina abundance, while abundance of both autotrophs was related to light availability.Z. marina biomass ranged 19–109 g dry weight m^?2; green macroalgae biomass ranged 5–234 g dry weight m^?2. The biomass of the green macroalgae at several sites and dates equaled or exceed that of theZ. marina suggesting the potential for nuisance algal blooms does exist in Yaquina Bay.     

A peculiar H i cloud near the distant globular cluster Pal 4

We present 21-cm observations of four Galactic globular clusters, as part of the on-going Galactic Arecibo L-band Feed Array (GALFA) H  i survey at Arecibo. We discovered a peculiar H  i cloud in the vicinity of the distant (109 kpc) cluster Pal 4, and discuss its properties and likelihood of association with the cluster. We conclude that an association of the H  i cloud and Pal 4 is possible, but that a chance coincidence between Pal 4 and a nearby compact high-velocity cloud cannot be ruled out altogether. New, more stringent upper limits were derived for the other three clusters: M 3, NGC 5466, and Pal 13. We briefly discuss the fate of globular cluster gas and the interaction of compact clouds with the Galactic halo gas.     

Cleavage strain in the Variscan fold belt,County Cork,Ireland, estimated from stretched arsenopyrite rosettes

In south-west Ireland, hydrothermally formed arsenopyrite crystals in a Devonian mudstone have responded to Variscan deformation by brittle extension fracture and fragment separation. The interfragment gaps and terminal extension zones of each crystal are infilled with fibrous quartz. Stretches within the cleavage plane have been calculated by the various methods available, most of which can be modified to incorporate terminal extension zones. The Strain Reversal Method is the most accurate currently available but still gives a minimum estimate of the overall strain. The more direct Hossain method, which gives only slightly lower estimates with this data, is more practical for field use. A strain ellipse can be estimated from each crystal rosette composed of three laths (assuming the original interlimb angles were all 60°) and, because actual rather than relative stretches are estimated, this provides a lower bound to the area increase in the plane of cleavage. Based on the average of our calculated strain ellipses this area increase is at least 114% and implies an average shortening across the cleavage of at least 53%. However, several lines of evidence suggest that the cleavage deformation was more intense and more oblate than that calculated, and we argue that a 300% area increase in the cleavage plane and 75% shortening across the cleavage are more realistic estimates of the true strain. Furthermore, the along-strike elongation indicated is at least 80%, which may be regionally significant. Estimates of orogenic contraction derived from balanced section construction should therefore take into account the possibility of a substantial strike elongation, and tectonic models that can accommodate such elongations need to be developed.     

An integrated model of clastic injectites and basin floor lobe complexes: implications for stratigraphic trap plays

Injectites sourced from base‐of‐slope and basin‐floor parent sandbodies are rarely reported in comparison to submarine slope channel systems. This study utilizes the well‐constrained palaeogeographic and stratigraphic context of three outcrop examples exposed in the Karoo Basin, South Africa, to examine the relationship between abrupt stratigraphic pinchouts in basin‐floor lobe complexes, and the presence, controls, and character of injectite architecture. Injectites in this palaeogeographic setting occur where there is: (i) sealing mudstone both above and below the parent sand to create initial overpressure; (ii) an abrupt pinchout of a basin‐floor lobe complex through steep confinement to promote compaction drive; (iii) clean, proximal sand beds aiding fluidization; and (iv) a sharp contact between parent sand and host lithology generating a source point for hydraulic fracture and resultant injection of sand. In all outcrop cases, dykes are orientated perpendicular to palaeoslope, and the injected sand propagated laterally beneath the parent sand, paralleling the base to extend beyond its pinchout. Understanding the mechanisms that determine and drive injection is important in improving the prediction of the location and character of clastic injectites in the subsurface. Here, we highlight the close association of basin‐floor stratigraphic traps and sub‐seismic clastic injectites, and present a model to explain the presence and morphology of injectites in these locations.     

Timing and thermochemical constraints on multi-element mineralisation at the Nori/RA Cu–Mo–U prospect, Great Bear magmatic zone, Northwest Territories, Canada

The timing of Cu–Mo–U mineralisation at the Nori/RA prospect in the Paleoproterozoic Great Bear magmatic zone has been investigated using Re–Os molybdenite and ⁴⁰Ar–³⁹Ar biotite geochronology. The Re–Os molybdenite ages presented are the first robust sulphide mineralisation ages derived from the Great Bear magmatic zone. Cu–Mo–U mineralisation is hosted in early to syn-deformational hydrothermal veins consisting of quartz and K-feldspar or more commonly tourmaline-biotite-quartz-K-feldspar, with associated wall-rock alteration assemblages being predominantly biotite. Sulphide and oxide minerals consist of chalcopyrite, molybdenite and uraninite with lesser pyrite and magnetite. Elevated light rare earth elements and tungsten concentrations associated with the Cu–Mo–U mineralisation have also been reported at the prospect by previous workers. Molybdenite and uraninite occur intimately in dravitic tourmaline growth zones and at grain margins, attesting to their syngenetic nature (with respect to hydrothermal veining). Two molybdenite separates yield Re–Os model ages of 1,874.4 ± 8.7 (2σ) and 1,872.4 ± 8.8 Ma (2σ) with a weighted average model age of 1,873.4 ± 6.1 Ma (2σ). Laser step heating of biotite from the marginal alteration of the wall-rock adjacent to the veins yields a ⁴⁰Ar–³⁹Ar maximum cooling age of 1,875 ± 8 Ma (MSWD = 3.8; 2σ), indistinguishable from the Re–Os molybdenite model age and a previously dated ‘syn-tectonic’ aplitic dyke in the region. Dravitic tourmaline hosts abundant primary liquid–vapour–solid-bearing fluid inclusions. Analytical results indicate liquid–vapour homogenisation at >260°C constraining the minimum temperature of mineralisation. The solids, which are possibly trapped, did not homogenise with the liquid–vapour by 400°C. Salinities in the inclusions are variable. Raman spectra identify that at least some of the solids are calcite and anhydrite. Raman spectra also confirm the vapour phases contain some CO₂; whereas clathrates or CH₄ was not observed or detected. Quartz grains only host secondary fluid inclusions, which fluoresce under ultraviolet light, indicating trapped hydrocarbons. We speculate that these resulted from Phanerozoic fluid circulation through the Proterozoic basement. The collective interpretation of the age, hydrothermal character and associated metals, high temperature and variable salinity suggests that the Nori/RA Cu–Mo–U mineralisation can be linked with the earliest stages of plutonism in the Great Bear magmatic zone. From a regional perspective, the mineralisation may pre-date the extensive multi-element mineralisation now recognised as part of the iron oxide copper–gold (IOCG) spectrum of deposits. As IOCG provinces generally contain a variety of mineralisation styles, we interpret this as the earliest phase of the extensive mineralising system.     

Determination of variables in the prediction of strontium distribution coefficients for selected sediments

Idaho State University and the US Geological Survey, in cooperation with the US Department of Energy, conducted a study to determine and evaluate strontium distribution coefficients (K_ds) of subsurface materials at the Idaho National Engineering and Environmental Laboratory (INEEL). The K_ds were determined to aid in assessing the variability of strontium K_ds and their effects on chemical transport of strontium-90 in the Snake River Plain aquifer system. Data from batch experiments done to determine strontium K_ds of five sediment-infill samples and six standard reference material samples were analyzed by using multiple linear regression analysis and the stepwise variable-selection method in the statistical program, Statistical Product and Service Solutions, to derive an equation of variables that can be used to predict strontium K_ds of sediment-infill samples. The sediment-infill samples were from basalt vesicles and fractures from a selected core at the INEEL; strontium K_ds ranged from ~201 to 356 ml g^-1. The standard material samples consisted of clay minerals and calcite. The statistical analyses of the batch-experiment results showed that the amount of strontium in the initial solution, the amount of manganese oxide in the sample material, and the amount of potassium in the initial solution are the most important variables in predicting strontium K_ds of sediment-infill samples.     

全球重要农业文化遗产(GIAHS)保护与适应性管理(英文)

世界各地世代居住的农牧民,以多样化的自然资源为基础,通过因地制宜的生产实践活动,创造、形成并保持着许多独具特色的农业系统和景观。这些在本土知识和传统经验基础上所建立起来的农业文化遗产巧夺天工,充分反映了人类及其文化多样性和与自然环境之间深刻关系的演进历程。这些系统不仅维持并适应了具有全球重要意义的农业生物多样性,形成了丰富的本土知识体系,而且更为重要的是,还为人类持续提供了多样化的产品和服务,保障了食物安全和生计安全,提高了人们的生活质量。但是,许多这样的农业生产系统正面临着包括全球化在内的多种影响因素的威胁。2002年,联合国粮农组织发起了一个国际合作计划"全球重要农业文化遗产(GIAHS)保护与适应性管理"。这一全球性倡议旨在建立这些农业文化遗产及其有关的生物多样性、食物与生计安全、景观与文化的保护体系,并在世界范围内得到认可,实现动态保护和可持续管理。     

A Large-Scale Seasonal Modeling Study of the California Current System

A high-resolution, multi-level, primitive equation ocean model has been used to investigate the combined role of seasonal wind forcing, seasonal thermohaline gradients, and coastline irregularities on the formation of currents, meanders, eddies, and filaments in the entire California Current System (CCS) region, from Baja to the Washington-Canada border. Additional objectives are to further characterize the meandering jet south of Cape Blanco and the seasonal variability off Baja. Model results show the following: All of the major currents of the CCS (i.e., the California Current, the California Undercurrent, the Davidson Current, the Southern California Countercurrent, and the Southern California Eddy) as well as filaments, meanders and eddies are generated. The results are consistent with the generation of eddies from instabilities of the southward current and northward undercurrent via barotropic and baroclinic instability processes. The meandering southward jet, which divides coastally-influenced water from water of offshore origin, is a continuous feature in the CCS, and covers an alongshore distance of over 2000 km from south of Cape Blanco to Baja. Off Baja, the southward jet strengthens (weakens) during spring and summer (fall and winter). The area off southern Baja is a highly dynamic environment for meanders, filaments, and eddies, while the region off Point Eugenia, which represents the largest coastline perturbation along the Baja peninsula, is shown to be a persistent cyclonic eddy generation region. This revised version was published online in July 2006 with corrections to the Cover Date.