Thermal alteration experiments on organic matter in recent marine sediment—II. Isoprenoids

Several isoprenoid compounds were isolated from a heat-treated marine sediment in the southern California continental shelf (from Tanner Basin) which were not present in the original sediment. Among the compounds identified were: phytol, dihydrophytol, C₁₈-isoprenoid ketone, phytanic and pristanic acids, C₁₉- and C₂₀-monoolefins, and the alkanes 2,6,10-trimethylpentadecane, pristane and phytane. The significance and possible routes leading to these compounds is discussed.     

Thermal alteration experiments on organic matter in recent marine sediment—III. Aliphatic and steroidal alcohols

Recent sediments from Tanner Basin (off southern California) and Bandaras Bay (in Gulf of California) have been analyzed for normal, isoprenoid and steroidal alcohols using chromatographic (column, GLC, TLC), and spectroscopic (u.v., i.r., MS) methods, prior to and after heat-treatment (from 65 to 150°C). Normal saturated alcohols (C₁₄-C₂₄) and monounsaturated alcohols (C₂₂-C₂₄) were identified, as well as the isoprenoid alcohols, phytol and dihydrophytol.Two series of sterols (Δ⁵ and Δ⁷) were found in Tanner Basin, and Δ⁵-sterols and triterpenes, in Bandaras Bay sediment. Sterols from both sediments contained the corresponding stanols.     

Amphibole zonation in metabasites as a guide to the evolution of metamorphic conditions

In low grade metabasites the amphibole components tremolite, glaucophane, edenite and tschermakite have their activities controlled by interactions with the excess components albite, clinozoisite, chlorite, quartz and H₂O vapor. Three types of reaction are involved, (i) Those in which only components of condensed phases take part: isopleths of equilibrium constant are straight lines in the P-T plane. (ii) Dehydration reactions in which entropy change due to change in Al coordination is of the same sign as that due to dehydration: isopleths of constant K are positive at low pressure and negative at high pressure. (iii) Dehydration reactions in which entropy change due to Al coordination change is opposite in sign to that of dehydration: isopleths of constant K loop in the P-T plane with positive slopes at low and at high pressure. Zonation in naturally occurring amphiboles records the evolution of metamorphic conditions in particular rocks. In an example from the eastern Alps (Austria) early conditions calculated as 15 kb, 200 ° C evolve upgrade to 6 kb, 525 ° C implying concurrent heating and erosion. The record of evolving conditions may span some 30 Ma of geological history.     

Some thermodynamical and microphysical aspects of monsoon clouds

The thermodynamical and microphysical characteristics of monsoon clouds in the Poona, Bombay and Rihand regions were investigated using extensive aircraft in-cloud observations. The number of clouds sampled at Poona, Bombay and Rihand is 2199, 169 and 104 respectively. The temperatures inside the cloud are colder than its environment at Poona and Rihand. The maximum difference is about 3°C at the cloud base level and the difference decreased with height. At Bombay the difference is less than 1°C and at some levels the temperatures inside the cloud are warmer than its environment. The lapse rates of temperatures inside the cloud are slightly less than those in the immediate environment of the cloud. The environmental lapse rates are nearly equal to the saturated adiabatic value. The positive increments in liquid water content (LWC) are associated with the increments in temperature inside the cloud. Similarly positive increments in temperatures inside the cloud are associated with the increments in temperature of its immediate environment at the same level or the layer immediately above. The maximum cloud lengths observed at Poona and Bombay respectively are 14 and 3 km. The horizontal cross-section of LWC showed a maximum number of 13 peaks in clouds at Poona while only 7 peaks were observed at Bombay. The location of maximum LWC in the horizontal cross-section is more or less at the centre of the cloud. The LWC profile showed an increase with height from the base of the cloud at Poona and Bombay. There is no marked variation of LWC with height at Rihand. The total droplet concentration at different altitudes at Poona and Bombay is in the range 28–82 cm^?3. The size distribution of cloud droplets experienced a broadening effect with increase in height from the cloud base at Poona. The broadening effect at Bombay is not as marked as that at Poona.     

Magmatic andalusite from the South Mountain batholith,Nova Scotia

Accessory andalusite has been found in some late-stage granitic differentiates of the South Mountain batholith. The andalusite is petrographically distinct from the andalusite of the thermal aureole, and it occurs in regions of the batholith which show little evidence of contamination by the country rocks. Analyses of biotites from andalusite-bearing and andalusite-free phases suggest that those coexisting with andalusite actually grew in equilibrium with the andalusite. It is concluded that magmatic andalusite must be confined mainly to water-saturated, peraluminous, epizonal granites, and some possible P-T paths for the crystallization of magmatic andalusite are considered.     

The origin of chondrules: experimental investigation of metastable liquids in the system Mg2SiO4-SiO2

Laser-melted magnesium silicate droplets, supercooled 400–750°C below their equilibrium liquidus temperatures before crystallization, were examined to provide a comparison with meteoritic and lunar chondrules and to examine physicochemical parameters that may indicate the conditions of their formation. Internal textures of the spherules strikingly resemble textures observed in some chondrules. Definite trends in crystal morphology, crystal width and texture were established with respect to nucleation temperature and bulk composition. Such trends provide a framework for determining the nucleation temperature of chondrules. The only phase to nucleate from the supercooled forsterite-enstatite normative melts was forsterite, which was present in more-than-normative amounts. Highly siliceous glass (~65wt. % SiO₂) was identified interstitially to the forsterite crystals in seven of the spherules and is thought to be present in all. The presence of enstatite and the large proportion of crystals in some meteoritic chondrules implies that they were maintained at temperatures considerably in excess of 600°C at some point in their history.     

Submergence avoidance behavior in the periwinkleLittorina irrorata is not due to threat of drowning

An attempt to establish an LD₅₀ for submergence onLittorina irrorata casts strong doubt on the hypothesis that submergence avoidance behavior is due to the threat of drowning. Predator avoidance is offered as a more plausable hypothesis. Respiration rates of 2.73×10^?3 ml O₂/g body wt./min. for submerged snails and 2.70×10^?2 ml O₂/g body wt./min. for controls were determined.     

Archaeomagnetic investigations in Bulgaria: Field-intensity determinations

Geomagnetic paleointensity determination have been made by the Thellier method using samples from 27 sites in Bulgaria. The samples include bricks, specimens taken from historic kilns, from prehistoric hearths and the sites of ancient fires. The ages of the samples, which range from about 4500 B.C. to the 19th century A.D., have been determined partly by the ¹⁴C method and partly from archaeological evidence. The (residual NMR)-(induced TRM) diagrams tend to be less linear for the prehistoric samples either due to weathering or because the NRM is not a total TRM.     

An Acoustic-Instrumented Mine for Studying Subsequent Burial

The U.S. Navy is supporting the research to develop and validate stochastic, time-dependent, mine burial prediction models to aid the tactical decision making process. This research requires continuous monitoring of both mine behavior during burial, and the near-field processes responsible for burial. A new instrumented mine has been developed that far exceeds the capabilities of the earlier optically instrumented mine in terms of the burial processes that can be measured. The acoustic-instrumented mine (AIM) utilizes acoustic transducers to measure burial and scour, localized flow rates, and sediment size and concentration in the water column. The AIM also includes sensors for measuring mine orientation and movement, as well as oceanographic information such as significant waveheights, wave period, and water temperature. Four AIMs were constructed and deployed during the Indian Rocks Beach (IRB, FL) and Martha's Vineyard Coastal Observatory (MVCO, Edgartown, MA) mine burial experiments. The results from the field experiments have proven that the sensor suite is viable in providing a wealth of data that are critical in understanding and modeling the complex subsequent burial process.     

Mine Burial Prediction: A Short History and Introduction

Naval mines have been in use for over 200 years. They are a cheap and effective way to significantly affect naval operations. Bottom mines in shallow water are particularly difficult to find when they are partially or wholly buried. The U.S. Office of Naval Research (Arlington, VA) and the Naval Research Laboratory (Stennis Space Center, MS) sponsored a six-year-long program to upgrade the capability to predict mine burial. The program consisted of laboratory studies, computer modeling, and field observation programs. Results of the studies have been combined into stochastic predictive programs that utilize state of the art process models and incorporate uncertainty in model capability and in our ability to know the correct values of model inputs.