Cretaceous sedimentary blanketing and tectonic rejuvenation in the Western Klamath moutains: Insights from thermochronology

We present new thermochronometric analyses of 4 samples from the Western Klamath mountains in California and Oregon, together with a re-evaluation of available geological constraint from a thermo-tectonic perspective. Early Cretaceous cooling of basement samples is seen to reflect significant exhumation by normal faulting, linked to the Separation Episode during which the Klamah region was rifted away from the formerly contiguous Sierra Nevada block. Syn-faulting sedimentation and subsequent Early Cretaceous re-heating of samples establishes the former continuity of scattered Hornbrook Formation remnants as a significant sedimentary basin spanning the Klamath region, with local maximum thickness of at least 5 km. This basin experienced significant inversion during early Cordilleran development around 110–120 Ma, with further unrooting and almost complete eversion in the Late Cretaceous, associated with Laramide uplift of the region.     

Climatic change: communication changes over this journal’s first ‘century’

Over the century of ‘Climatic Change’ volumes and the 33 years that they span the climate has changed. Here I consider the challenge of interdisciplinary communication to which the first 99 volumes of this journal are dedicated. Have we succeeded and have climatic change researchers shared findings with a broader audience? If this journal has been successful, should the editorial board and publishers now consider new modes of communicating research to a still wider public, say by hiring a communication cartoonist or with an interactive blog?     

Trends of seasonal maximum and minimum temperatures and precipitation in Southern Brazil for the 1913–2006 period

Long-term variations of monthly average maximum and minimum temperature (TMAX and TMIN) and precipitation records in southern Brazil are investigated for the 1913–2006 period. These variations are carefully analyzed for seasonal and annual indices, taken as regional averages. For this purpose, the serial correlation and trend of the indices are investigated using the run and Mann–Kendall tests. The significant trends are obtained from linear least-square fits. The annual and seasonal TMIN indices show significant warming trends with magnitudes (1.7°C per 100 years for annual index) comparable to those reported by the Intergovernmental Panel on Climate Change, but lower than those found for the southern Brazil in another previous work. Regarding the two other variables, the indices show significant trends only for summer, being a cooling trend of 0.6°C per 100 years for the TMAX and an increasing trend of 93 mm per 100 years over an average summer precipitation of 367 mm. Concerning the decadal analysis, the 1920s present the lowest annual, autumn, and spring TMIN and the 1990s, the highest ones. The 1970s is the decade with the lowest summer TMAX, and the 1940s the decade with the highest one. The driest decade is the 1940s and the wettest, the 1980s.     

Monitored Natural Attenuation of Contaminants in the Subsurface: Applications

In recent years there has been increasing interest in the application of passive technologies to reduce or remove contaminants from the subsurface environment including soil and ground water. In most cases, the impetus for this interest lies in a perceived savings compared with more traditional remedial alternatives. In a few cases, the infrastructure at contaminated sites, such as buildings, paved areas, and utilities, makes the use of conventional remedial measures difficult and expensive.
To demonstrate that natural processes are effective in reaching established goals, it is necessary to determine that transformation processes are taking place at a rate that is protective of human health and the environment and that these processes will continue for an acceptable period of time. The basic conditions that must be present to confirm natural attenuation processes arc taking place are discussed along with the behavior of contaminated plumes, monitoring requirements, data analysis, rates of degradation, and mathematical modeling.     

Field Measurement of Dissolved Oxygen: A Comparison of Methods

The ability to confidently measure the concentration of dissolved oxygen (D.O.) in ground water is a key aspect of remedy selection and assessment. Presented here is a comparison of the commonly practiced methods for determining D.O. concentrations in ground water, including colorimetric, membrane-covered electrode, and modified Winkler techniques. The Winkler titration (azide and permanganate modifications) is the most accurate and precise technique for determining D.O. and is appropriate for applications with stringent data quality objectives. In addition, excellent correlation over a wide range of D.O. concentrations was found between Winkler titrations and colorimetric tests using the rhodazine D (below 1 part per million [ppm]) and indigo carmine reagents (above 1 ppm). Electrode measurements represent the simplest method for determining D.O. concentrations on a continuous basis and electrode determinations positively correlate with Winkler results above 1 ppm. Below 1 ppm, electrodes provide only a qualitative measure of low D.O. level, apparently due to slow electrode response.     

Acid-base status of soils in groundwater discharge zones — relation to surface water acidification

Critical load calculations have suggested that groundwater at depth of 2 m in Sweden is very sensitive to acid load. As environmental isotope studies have shown that most of the runoff in streams has passed through the soil, there is a risk in the near future of accelerated acidification of surface waters.

To assess the importance of the last soil horizon of contact before discharge, the upper 0–0.2m of soils in seven discharge zones were analysed for pools of base cations, acidity and base saturation. The sites were about 3–4 m² in size and selected from two catchments exposed to different levels of acid deposition.

The soils in the seven sites had high concentrations of exchangeable base cations and consequently high base saturation. The high correlation (r² = 0.74) between base saturation in the soils of the discharge zones and mean pH of the runoff waters suggested that the discharge zone is important for surface water acidification. The high pool of exchangeable base cations will buffer initially against the acid load. As the cation exchange capacity (meq dm⁻³) and base saturation were lower in the sites from the catchment receiving lower deposition, these streams may be more vulnerable to acidification in the near future. The high concentration of base cations in non-exchangeable fractions may also buffer against acidification as it is likely that some of these pools will become exchangeable with time.     

The diurnal and semidiurnal barometric oscillations global distribution and annual variation

Summary The global distributions of the annual and seasonal means of the diurnal (S ₁) and semidiurnal (S ₂) surface pressure oscillations are investigated by spherical harmonic analysis. The main waves are,S ₁ ¹ (with wave number 1) forS ₁ andS ₂ ² forS ₂.S ₁ ¹ is much less predominant among the waves ofS ₁ thanS ₂ ² among those ofS ₂. As in the case of the lunar semidiurnal barometric tideL ₂ the pressure maxima occur earlier in the Southern than in the Northern Hemisphere. In the case ofS ₂ the standing waveS ₂ ⁰ and the waveS ₂ ³ are also of interest besidesS ₂ ². Although the present analysis extends only from 60°N to 60°S, whileS ₂ ⁰ is largest at polar latitudes, its results show thatS ₂ ⁰ should be smaller at high southerly than at high northerly latitudes, as has been observed. Thus this observed asymmetrical distribution ofS ₂ ⁰ may be due to causes outside the polar regions rather than to their geographical differences. The best approximation to the observed distribution ofS ₂ ⁰ is obtained by including a mode representing an oscillation independent of longitude and latitude indicating a small semidiurnal variation of the mean global surface presure, which is an unlikely result on physical grounds.The seasonal variation ofS ₁ ¹ expressed in percent of the annual mean is smaller than that ofS ₂ ², and both are less than the unexplained seasonal variation ofL ₂ ².The main wavesS ₁ ¹ andS ₂ ² are expressed not only by associated Legendre functions, but also by Hough functions.National Center for Atmospheric Research, Boulder, Colorado, U.S.A., sponsored by the National Science Foundation.     

Studying Regions by Studying Firms*

This paper presents a method for inferring regional economic structure and prospects from key informant interviews. It describes assumptions which must be made and steps to be taken in moving from individuals to establishment, firm, and industry aggregations. A technique is offered for mapping core relationships among firms and other regional and external actors, and for aggregating firm-centered maps into industrial and regional maps. The mapping technique can be expanded to incorporate historicity and dynamic change.     

A close-interval sampler for collection of sediment pore waters for nutrient analyses

An in situ sediment pore water sampler is described. It can simultaneously and continuously sample at four discrete 1 cm levels at one location without disturbing the sediment or the sample. The sampler can maintain an anaerobic environment, and can be used over extended periods of time. Laboratory tests indicate 98 to 100 percent recoveries for ammonium, silicate, reactive phosphate, nitrate and nitrite. Vertical profiles for ammonium, reactive phosphate and silicate are shown from field studies.