Sources and composition of organic matter for bacterial growth in a large European river floodplain system (Danube, Austria)

Dissolved and particulate organic matter (DOM and POM) distribution, lignin phenol signatures, bulk elemental compositions, fluorescence indices and microbial plankton (algae, bacteria, viruses) in a temperate river floodplain system were monitored from January to November 2003. We aimed to elucidate the sources and compositions of allochthonous and autochthonous organic matter (OM) in the main channel and a representative backwater in relation to the hydrological regime. Additionally, bacterial secondary production was measured to evaluate the impact of organic carbon source on heterotrophic prokaryotic productivity. OM properties in the backwater tended to diverge from those in the main channel during phases without surface water connectivity; this was likely enhanced due to the exceptionally low river discharge in 2003. The terrestrial OM in this river floodplain system was largely derived from angiosperm leaves and grasses, as indicated by the lignin phenol composition. The lignin signatures exhibited significant seasonal changes, comparable to the seasonality of plankton-derived material. Microbially-derived material contributed significantly to POM and DOM, especially during periods of low discharge. High rates of bacterial secondary production (up to 135 μg C L(-1) d(-1)) followed algal blooms and suggested that autochthonous OM significantly supported heterotrophic microbial productivity.     

The haze and methane distributions on Neptune from HST-STIS spectroscopy

We analyzed a data cube of Neptune acquired with the Hubble STIS spectrograph on August 3, 2003. The data covered the full afternoon hemisphere at 0.1 arcsec spatial resolution between 300 and 1000 nm wavelength at 1 nm resolution. Navigation was accurate to 0.004 arcsec and 0.05 nm. We constrained the vertical aerosol structure with radiative transfer calculations. Ultraviolet data confirmed the presence of a stratospheric haze of optical depth 0.04 at 370 nm wavelength. Bright, discrete clouds, most abundant near latitudes −40° and 30°, had their top near the tropopause. They covered 1.7% of the observed disk if they were optically thick. The methane abundance above the cloud tops was 0.0026 and 0.0017 km-am for southern and northern clouds, respectively, identical to earlier observations by Sromovsky et al. (Sromovsky, L.A., Fry, P.M., Dowling, T.E., Baines, K.H., Limaye, S.S., [2001b]. Icarus 149, 459-488). Aside from these clouds, the upper troposphere was essentially clear. Below the 1.4-bar layer, a vertically uniform haze extended at least down to 10 bars with optical depth of 0.10-0.16/bar, depending on the latitude. Haze particles were bright at wavelengths above 600 nm, but darkened toward the ultraviolet, at the equator more so than at mid and high latitudes. A dark band near −60° latitude was caused by a 0.01 decrease of the single scattering albedo in the visible, which was close to unity. A comparison of methane and hydrogen absorptions contradicted the current view that methane is uniformly mixed in latitude and altitude below the ∼1.5-bar layer. The 0.04 ± 0.01 methane mixing ratio is only uniform at low latitudes. At high southern latitudes, it is depressed roughly between the 1.2 and 3.3-bar layers compared to low-latitude values. The maximum depression factor is ∼2.7 at 1.8 bars. We present models with 2° latitude sampling across the full sunlit globe that fit the observed reflectivities to 2.8% rms.     

Quantification of contemporary storm-induced boulder transport on an intertidal shore platform using radio frequency identification technology

Extreme storm events are known to produce, entrain, transport and deposit sizable boulders along rocky coastlines. However, the extent to which these processes occur under moderate, fetch-limited wave conditions is seldom considered. In this study we quantify boulder transport at a relatively sheltered location subject to high-frequency, low-magnitude storm activity. This was achieved by deploying radio frequency identification (RFID) tags within 104 intertidal limestone boulders ranging in size from fine to very coarse (intermediate axis: 0.27–2.85 m). The study was conducted over 3 years (July 2015–July 2018) and encompassed numerous storm events. Tagged boulders were relocated during 17 field surveys and their positions recorded using a differential global positioning navigation satellite system (DGNSS). On completion, we identified boulder displacement in 69% of the tagged array. The accrued boulder transport distance amounted to 233.0 m from 195 incidents of displacement, including the movement of a boulder weighing an estimated 11.9 t. Transport was not confined to autumn and winter storms alone, as displacement was also recorded during summer months (April–September), despite the seasonally reduced wave magnitude. Boulder production by wave quarrying was documented in three tagged clasts, confirming observations that the shore platform is actively eroding. Incidents of overturning during transport were also recorded, including multiple overturning of clasts weighing up to 5 t. We further identify a statistically significant difference (maximum p-value ≤ 0.03) between the transport distances attributed to constrained and unconstrained boulders, suggesting that the pre-transport morphological setting exerts considerable control over boulder transport potential. The findings establish low to moderate storm waves as a key component in the evolution of the study site. More broadly, we claim that high-frequency, low-magnitude storms regularly modify these overlooked rocky coastal locations, suggesting that the hydrodynamic capability at such sites may previously have been underestimated. © 2020 John Wiley & Sons, Ltd.     

Rapid spread of the wasp spider Argiope bruennichi across Europe: a consequence of climate change?

Numerous species are expanding their ranges towards the North Pole, a pattern that is usually explained with climate change. However, few studies have actually tested the potential role of climate in such range expansions. Here, we studied the wasp spider Argiope bruennichi, which has multiplied its range in Central and Northern Europe during the 20th century and is still spreading. Using current and historical climate data, we analysed whether this spread can be explained by climate warming, increasing cold tolerance or if it is unrelated to temperature. Spatial partial regression showed that the spread of A. bruennichi into formerly cooler areas is independent of spatial autocorrelation, indicating that it is driven by temperature. Some aspects of the spread, as e.g. the patchy distribution at the beginning of the century are likely to be relicts of climate fluctuations before our study period. From the middle of the 20th century until the 1980s, A. bruennichi was recorded from gradually cooler climates, while temperature was relatively constant. This indicates that A. bruennichi either increased its cold tolerance or that the spread continued with a time lag following an earlier warming event, due to dispersal limitation. In the last two decades, temperature rose sharply. The temperatures at which A. bruennichi was newly recorded increased as well, indicating that the spider is dispersal limited and that the spread will continue even in the absence of further climate warming.     

A New Digestion and Chemical Separation Technique for Rapid and Highly Reproducible Determination of Lu/Hf and Hf Isotope Ratios in Geological Materials by MC-ICP-MS

A new digestion procedure and chemical separation technique has been developed for measurement of Lu/Hf and Hf isotope ratios that does not require high‐pressure bombs or use of HF or HClO₄ acids. Samples are digested in dilute HCl or HNO₃ after flux‐fusion at 110 0 °C in the presence of lithium metaborate. High field strength elements (HFSE) and rare earth elements (REE) are separated from this solution by co‐precipitation with iron hydroxide. The dissolved precipitate (in 2 mol l^?1 HCl) is loaded directly onto a standard cation exchange column which separates remaining sample matrix from the heavy REE (Lu+Yb), and the middle‐light REE and HFSE (Hf). The middle‐light REE and individual HFSE are then separated (10.5, 9 and 6 mol l^?1 HCl) using a miniaturized column containing TEVA spec resin which provides a REE‐, Ti‐ and Zr‐free Hf cut. This chemical separation scheme can also be readily adapted for isotopic analysis of the Sm‐Nd system and/or the other HFSE (Ti, Zr). Total procedural blanks for this technique are < 10 0 pg and < 2 pg for Hf and Lu, respectively, even when digesting large (0.5 g) samples. We present data from replicate digestions of international rock reference materials which demonstrate this technique routinely reproduces Lu/Hf ratios to < 0.2% (2s) and ¹⁷⁶ Hf/¹⁷⁷ Hf isotope ratios to < 30 ppm (2s). Moreover, the technique is matrix‐independent and has been successfully applied to analysis of diverse materials including basalts, meteorites, komatiites, kimberlites and carbonatites. The relative simplicity of this technique, coupled with the ease of digestion (and sample‐spike equilibration) of large difficult‐to‐dissolve samples, and the speed (2 days) with which samples can be digested and processed through the chemical separation scheme makes it an attractive new method for preparing samples for Lu‐Hf isotopic investigation.     

8. Beitrag Die Temperaturen der pazifischen Küstengewässer Nordamerikas von 1920 bis 1955

Zusammenfassung Es werden neue Jahrfünftmittel der Oberflächentemperatur für die pazifische Küste Nordamerikas mitgeteilt, die den Zeitraum von mindestens dreißig Jahren (bis einschließlich 1955) umfassen. Die fortschreitenden Jahrfünftmittel lassen Fluktuationen, aber keinen säkularen Trend erkennen. Die seit dem Maximum von 1941 allgemein aufgetretene Abkühlung machte die letzten zehn Jahre 1946–55 zu den durchschnittlich kältesten seit Beginn der zwanziger Jahre. Der Tiefpunkt scheint jedoch bei den meisten Stationen überschritten zu sein. Einzelne besonders ausgeprägte Warmwasser- (und Kaltwasser-) Jahre erstrecken sich offensichtlich über die gesamte Küste von Kalifornien bis Alaska. An dem Beispiel von 1926 wird gezeigt, daß hier eine globale atmosphärische Zirkulationsanomalie ursächlich war, die in ganz ähnlicher Weise auch eine starke Wassererwärmung im östlichen subtropischen Nordatlantik gezeitigt hatte.

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Temperatures of surface waters on the Pacific coast of North America, 1920–1955

Summary This paper presents recent five-year mean values of sea-surface temperatures from the Pacific coast of North America for a period of at least thirty years (including the year 1955). The five-year running means reveal the occurrence of fluctuations rather than the existence of a secular trend. Decreasing temperatures which have been generally observed since the maximum of sea temperature in 1941 made the last ten years from 1946 to 1955 the coldest years since the beginning of the twenties of this century. It seems, however, that at most stations, temperatures already exceeded the minimum. Throughout separate years, a pronounced warming (or a pronounced cooling) of sea-surface water obviously extended over the whole length of the Pacific coast from California to Alaska. The example of 1926 shows that in this case the high temperatures are caused by a worldwide atmospheric circulation anomaly which, in a similar way, accounts for the high values of sea-surface temperatures in the eastern subtropical part of the North Atlantic Ocean.

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Les températures superficielles des eaux côtières pacifiques de l'Amérique du Nord de 1920 à 1955

Résumé Pour une période de trente années (y compris l'anné de 1955) le travail actuel présente de récentes valeurs moyennes de cinq années des températures de surface mesurées sur la côte Pacifique de l'Amérique du Nord. Les moyennes progressives de cinq années montrent la présence des variations plutôt que l'existence d'un trend séculaire. Causé par le refroidissement des eaux de surface qui s'est produit partout depuis le maximum de la température en 1941, les derniers dix ans de 1946 à 1955 ont été au moyen les plus froids dès le début de la décade de 1920 à 1930. Il semble, cependant, qu'auprès de la plupart des stations, les températures aient déjà dépassé le minimum. Pendant plusieurs années isolées, un échauffement prononcé (ou un refroidissement prononcé) des eaux de surface s'étend tout le long de la côte Pacifique de la Californie jusqu'à l'Alaska. L'exemple de 1926 montre que dans ce cas les températures élevées furent causées par une anomalie universelle de la circulation atmosphérique qui, d'une manière analogue, provoqua également un échauffement des eaux de surface dans la région orientale subtropicale de l'Atlantique du Nord.

     

Trace element mapping by LA-ICP-MS: assessing geochemical mobility in garnet

A persistent problem in the study of garnet geochemistry is that the consideration of major elements alone excludes a wealth of information preserved by trace elements, particularly the rare-earth elements (REEs). This is despite the fact that trace elements are generally less vulnerable to diffusive resetting, and are sensitive to a broader spectrum of geochemical interactions involving the entire mineral assemblage, including the growth and/or dissolution of accessory minerals. We outline a technique for the routine acquisition of high-resolution 2D trace element maps by LA-ICP-MS, and introduce an extension of the software package XMapTools for rapid processing of LA-ICP-MS data to visualise and interpret compositional zoning patterns. These methods form the basis for investigating the mechanisms controlling geochemical mobility in garnet, which are argued to be largely dependent on the interplay between element fractionation, mineral reactions and partitioning, and the length scales of intergranular transport. Samples from the Peaked Hill shear zone, Reynolds Range, central Australia, exhibit contrasting trace element distributions that can be linked to a detailed sequence of growth and dissolution events. Trace element mapping is thus employed to place garnet evolution in a specific paragenetic context and derive absolute age information by integration with existing U–Pb monazite and Sm–Nd garnet geochronology. Ultimately, the remarkable preservation of original growth zoning and its subtle modification by subsequent re-equilibration is used to ‘see through’ multiple superimposed events, thereby revealing a previously obscure petrological and temporal record of metamorphism, metasomatism, and deformation.     

Self-diffusion of water and its dependence on temperature and ionic strength in highly compacted montmorillonite, illite and kaolinite

The effect of temperature and ionic strength on the diffusion of HTO parallel to the direction of compaction through 5 highly compacted clay minerals (bulk dry density, ρ_b,d = 1.90 ± 0.05 Mg/m³), namely montmorillonite (Na- and Ca-form), illite (Na- and Ca-form), and kaolinite, was studied. The diffusion experiments were carried out at temperatures between 0 °C and 60 °C and at ionic strengths of 0.01 M and 1 M NaCl for the Na-form clays and kaolinite, and of 0.005 M and 0.5 M CaCl₂ for the Ca-form. The ionic strength had an insignificant influence on the values of the effective diffusion coefficient (variation by less than 10%) for the clays under study at this degree of compaction. The effective diffusion coefficients followed the order Na-montmorillonite < Ca-montmorillonite < Ca-illite < Na-illite  kaolinite. It is thought that the differences between Na- and Ca-montmorillonite originate from the larger size particles, and thus the lower tortuosity of the latter; whereas the differences between Na- and Ca-illite are related to the different degree of solvation of the Na and Ca cations. The activation energies were successfully calculated using the Arrhenius law. Swelling clays (Na- and Ca-montmorillonite) had slightly larger activation energy values (20 kJ/mol) compared to bulk water (17 kJ/mol); Ca-illite (16 kJ/mol), Na-illite (13 kJ/mol) and kaolinite (14.4 kJ/mol) lower values than that of bulk water. The low activation energies of the last three clays may be related to weaker H-bonds between water and the clay surfaces compared to those in bulk water.