Mg---NH4 exchange on humic acid: A radiotracer technique for conditional exchange constants in a seawater medium

A radiotracer technique, employing ²⁷Mg, is used to determine the Mg released by ammonium exchange on undis-solved humic acid in a seawater medium. This new method allows for the measurement of exchangeable Mg on the solid phase surface, which eliminates the problem caused by the high-Mg background in the seawater matrix. The precision calculated from the counting statistics is better than ±2%; the reproducibility among repeated counts ranged from ±1% to ±3%. The higher sensitivity of the method allows for monitoring the Mg---NH₄ exchange at concentrations as low as 30 mM NH₄. This is a major improvement relative to the data obtained with the analytical methods used so far, which allow detection of exchangeable Mg only at NH₄ concentrations higher than 1 M. The lower experimental concentrations are more in accordance with the natural ammonium levels found in anoxic marine sediments. For the undissolved humic acid used in this experiment, the amount of exchangeable Mg in apparent equilibrium with an ammonium-free seawater matrix was found to be 96.6 ± 0.4 meq/100g. The Mg---NH₄ exchange on humic acid in seawater comes to a steady-state value in < 18 min. The conditional equilibrium constant obtained for this reaction, K_cond = 0.039 ± 0.001 M⁻¹. The technique can be expanded to other geochemical solid phases in seawater and it can be modified to study the behavior of the major cations by using ²⁴Na, ⁴²K and ⁴⁹Ca.     

Witnessing North Atlantic westerlies variability from ships’ logbooks (1685–2008)

A monthly index based on the persistence of the westerly winds over the English Chanel is constructed for 1685–2008 using daily data from ships’ logbooks and comprehensive marine meteorological datasets. The so-called Westerly Index (WI) provides the longest instrumental record of atmospheric circulation currently available. Anomalous WI values are associated with spatially coherent climatic signals in temperature and precipitation over large areas of Europe, which are stronger for precipitation than for temperature and in winter and summer than in transitional seasons. Overall, the WI series accord with the known European climatic history, and reveal that the frequency of the westerlies in the eastern Atlantic during the twentieth century and the Late Maunder Minimum was not exceptional in the context of the last three centuries. It is shown that the WI provides additional and complementary information to the North Atlantic Oscillation (NAO) indices. The analysis of WI series during the industrial era indicates an overall good agreement with the winter and high-summer NAO, with the exception of several multidecadal periods of weakened correlation. These decoupled periods between the frequency and the intensity of the zonal flow are interpreted on the basis of several sources of non-stationarity affecting the centres of the variability of the North Atlantic and their teleconnections. Comparisons with NAO reconstructions and long instrumental indices extending back to the seventeenth century suggest that similar situations have occurred in the past, which call for caution when reconstructing the past atmospheric circulation from climatic proxies. The robustness and extension of its climatic signal, the length of the series and its instrumental nature make the WI an excellent benchmark for proxy calibration in Europe and Greenland.     

Using NWP to Assess the Influence of the Arctic Atmosphere on Midlatitude Weather and Climate

The influence of the Arctic atmosphere on Northern Hemisphere midlatitude tropospheric weather and climate is explored by comparing the skill of two sets of 14-day weather forecast experiments using the ECMWF model with and without relaxation of the Arctic atmosphere towards ERA-Interim reanalysis data during the integration. Two pathways are identified along which the Arctic influences midlatitude weather: a pronounced one over Asia and Eastern Europe, and a secondary one over North America. In general, linkages are found to be strongest(weakest) during boreal winter(summer) when the amplitude of stationary planetary waves over the Northern Hemisphere is strongest(weakest). No discernible Arctic impact is found over the North Atlantic and North Pacific region, which is consistent with predominantly southwesterly flow. An analysis of the flow-dependence of the linkages shows that anomalous northerly flow conditions increase the Arctic influence on midlatitude weather over the continents. Specifically, an anomalous northerly flow from the Kara Sea towards West Asia leads to cold surface temperature anomalies not only over West Asia but also over Eastern and Central Europe. Finally, the results of this study are discussed in the light of potential midlatitude benefits of improved Arctic prediction capabilities.     

The evaluation of “social risk” due to volcanic eruptions of Vesuvius

A re-evaluation of the demographic risk per number of inhabitants due to volcanic eruptions in the Vesuvius area was made on the basis of the Census data of 2001. We introduced other variables (population density and number of houses) which permit to upgrade the existing models. Using the Geographical Information Systems (GIS) and particularly ArcGIS 9.0 software we have elaborated a land use map, an urbanization map and a series of new risk maps which lead us to obtain a map of what we call “social risk” due to volcanic eruptions, derived from the combination of the data used and the overlay of the maps. We have proposed an integrated model which can be easily updated to follow the evolution of the volcanic risk in the overpopulated Vesuvius area, with the aim of supporting the planning of Civil Protection and Local Authorities, for an evacuation scenarios and the possibility of taking into account the potential infrastructural damages. This methodology can be tested in other volcanic regions.     

Pyroclastic deposits of the November 13, 1985 eruption of Nevado del Ruiz volcano, Colombia

The November 13, 1985 eruption of Nevado del Ruiz produced a series of pyroclastic flows and surges that eroded channels on the surface of the summit glacier and generated lahars which descended down most of the rivers that drain the volcano. The stratigraphy of the proximal pyroclastic deposits indicates that there were at least four episodes to the eruption. Episode I, deposited an unusual surge consisting of small pieces of ice mixed with ash and exhibiting planar stratification. Ballistically emplaced fragments are also intercalated with this unit. During Episode II, at least two pyroclastic flows were erupted. Their deposits contain the most evolved pumice of the entire eruption; SiO₂ content of matrix glass ranges between 74.5 and 74.9%. Episode III is marked by the emplacement of a welded tuff with an average SiO₂ content of about 66% in the matrix glass. The final Episode IV was characterized by the development of a high-altitude eruption column and the emplacement of several nonwelded pyroclastic flows. Banded pumice are common in the pyroclastic flow as well as in the pumice fall deposits. Co-existing dark and light pumice bands differ in SiO₂ content by 3.5% and in general are similar to the composition of the welded pumice from Episode III.The compositional zonation of the pyroclastic deposits from Episode I to IV suggests that a nearsurface compositionally-stratified portion of the magma body was tapped during Episode II. During Episodes III and IV the main body of magma was involved although the coexistence of the compositionally distinct pumice clasts at similar stratigraphic levels argues for mixing of magma from different levels in the chamber during the eruptive process.     

Growth Dynamics, Production, and Nutrient Status of the Seagrass Cymodocea nodosa in a Mediterranean Semi-Estuarine Environment

Abstract. Cymodocea nodosa is a relatively small seagrass species which is common in the Mediterranean. An intensive survey on its growth and production was carried out in a dense, monospecific stand located in a semi-estuarine embayment. Data on leaf appearance and growth, shoot recruitment and death, rhizome growth, above- and belowground biomass, and nutrient content in the different parts of the plant were obtained over 2 years. All these variables showed a clear seasonality. In general, maximum growth and production occurred in early summer (July), and maximum biomass was reached between July and September. Biomass, shoot density, growth and production showed clear minima in winter.     

Isotopic signatures of organic matter in sediments of the continental shelf facing the Orinoco Delta: Possible contribution of organic carbon from savannas

The ⁸⁷Sr, ¹³C, and ¹⁵N isotopic signatures of organic matter in sediments from the continental shelf facing the Orinoco Delta were measured to determine the contribution of sediments transported from the Amazon River by the coastal Guayana current and the sediments transported by the Orinoco River. Box core samples between 60 and 300 m water depth collected along 4 transects located eastwards to the Orinoco Delta were analyzed. Carbon and nitrogen concentrations decreased with depth under water on the shelf, and were strongly correlated indicating homogeneity of organic matter composition. Phosphorus content was also associated to organic matter in most samples, but some of them revealed deposition of P-enriched sediments. The ⁸⁷Sr/⁸⁶Sr ratios showed a strong continental signature averaging 0.7117, therefore, limiting the possible carbon and nitrogen sources associated with these sediments to C3 trees, C4 grasses, or freshwater phytoplankton. The δ¹³C values were relatively high averaging −21‰, above values reported for sediments on the Amapá shelf and the Amazon River in Brazil. Average δ¹³C values did not differ significantly among transects. High δ¹³C values point to the influence of organic matter transported from the C4-plants dominated savannas in the northern fringe of the Orinoco River. δ¹⁵N values were positive and averaged 5‰, being within the range of values measured in the Marajo island (Amazon River) and the estuary of the Pará River. The δ¹⁵N values differed significantly among transects (4.9–5.2‰), lowest values corresponding to the northernmost transect near the coast of Trinidad, and the highest values corresponding to the transect located at the southernmost position.     

Interplay between metamorphic strengthening and structural softening in inclusion‐bearing layered rocks

We employ numerical and analytical methods to investigate the effect of the presence of rigid porphyroblasts such as garnets on layer strengthening and the folding instability. We use a 50% fraction of non‐overlapping, circular‐shaped inclusions with a wide size distribution. These inclusions cause a fourfold effective viscosity increase and can significantly promote the folding instability. This is not only due to the increased viscosity but also due to the layer interface roughness generation driven by relative movement of inclusions. The increase in layer viscosity promotes strengthening of the whole system. However, with progressive fold development, the system undergoes an effective softening that may counteract the strengthening effect of the porphyroblast growth.