Petrogenesis of Quebrada de la Mina and Altar North porphyries (Cordillera of San Juan,Argentina): Crustal assimilation and metallogenic implications

We investigate the geology of Altar North (Cu–Au) and Quebrada de la Mina (Au) porphyry deposits located in San Juan Province (Argentina), close to the large Altar porphyry copper deposit (995 Mt, 0.35% Cu, 0.083 g/t Au), to present constraints on the magmatic processes that occurred in the parental magma chambers of these magmatic-hydrothermal systems. Altar North deposit comprises a plagioclase-amphibole-phyric dacite intrusion (Altar North barren porphyry) and a plagioclase-amphibole-biotite-phyric dacite stock (Altar North mineralized porphyry, 11.98 ± 0.19 Ma). In Quebrada de la Mina, a plagioclase-amphibole-biotite-quartz-phyric dacite stock (QDM porphyry, 11.91 ± 0.33 Ma) crops out. High Sr/Y ratios (92–142) and amphibole compositions of Altar North barren and QDM porphyries reflect high magmatic oxidation states (fO₂ = NNO +1.1 to +1.6) and high fH₂O conditions in their magmas. Zones and rims enriched in anorthite (An_37–48), SrO (0.22–0.33 wt.%) and FeO (0.21–0.37 wt.%) in plagioclase phenocrysts are evidences of magmatic recharge processes in the magma chambers. Altar North and Quebrada de la Mina intrusions have relatively homogeneous isotopic compositions (⁸⁷Sr/⁸⁶Sr_(t) = 0.70450–0.70466, ε_Nd(t) = +0.2 to +1.2) consistent with mixed mantle and crust contributions in their magmas. Higher Pb isotopes ratios (²⁰⁷Pb/²⁰⁴Pb = 15.6276–15.6294) of these intrusions compared to other porphyries of the district, reflect an increase in the assimilation of high radiogenic Pb components in the magmas. Ages of zircon xenocrysts (297, 210, 204, 69 Ma) revealed that the magmas have experienced assimilation of Miocene, Cretaceous, Triassic and Carboniferous crustal rocks.Fluids that precipitated sulfides in the Altar deposit may have remobilized Pb from the host rocks, as indicated by the ore minerals being more radiogenic (²⁰⁷Pb/²⁰⁴Pb = 15.6243–15.6269) than their host intrusions. Au/Cu ratio in Altar porphyries (average Au/Cu ratio of 0.14 × 10^?4 by weight in Altar Central) is higher than in the giant Miocene porphyry deposits located to the south: Los Pelambres, Río Blanco and Los Bronces (Chile) and Pachón (Argentina). We suggest that the increase in Au content in the porphyries of this region could be linked to the assimilation of high radiogenic Pb components in the magmas within these long-lived maturation systems.     

Using an Enhanced Dataset for Reassessing the Source Region of the 2003 Armer��a, Mexico Earthquake

We present a fresh look at the source region of the 22 January 2003 M _w 7.4 Armería earthquake, which occurred off the Pacific coast of the state of Colima, Mexico, near the town of Armería. The effects of this earthquake in the neighboring states of Colima and Jalisco were different and stronger than those of previous recent major earthquakes in the region. This earthquake and its aftershocks were recorded by two local telemetered seismograph networks (RESCO and RESJAL). From 22 January to 24 January 2003, no important seismicity was located on the plates interface, or within the Rivera Plate, and most epicenters were located west of the Armería River, which is the western border of the Colima Graben, and is located outside of the Colima Gap region. From 24 January to 31 January, the seismicity recorded by both networks showed a migration in depth, with an almost vertical offshore distribution between 4 and 24?km in depth. For this period, a seven-station portable digital seismograph network, equipped with three-component seismometers, was deployed in the epicentral area to study the aftershock sequence in detail. With this denser network more than 200 M _L?>?2.0 aftershocks were recorded. The aftershock foci were deeper than those recorded during the early period and most of them locate on a hypothetical 12° dipping interface between the Rivera and North American Plates. Composite focal mechanism solutions for the aftershocks located during both periods indicate a reverse fault character that changes with time. Analysis of the new dataset still indicates that the earthquake was a shallow intraplate event.     

Amphibole and phlogopite in “hybrid” metasomatic bands monitor trace element transfer at the interface between felsic and ultramafic rocks (Eastern Alps,Italy)

Ultramafic rocks in contact to gneisses in the Mt. Hochwart HP mélange (Eastern Italian Alps) preserve a series of metasomatic mineral zones. A phlogopitite with minor tremolite and accessory zircon and apatite forms close to the gneiss (Zone 1). Zone 2 consists of tremolite, phlogopite and anthophyllite followed by Zone 3 with anthophyllite plus minor chlorite and talc. Zone 3 grades into an amphibole–garnet peridotite lens. This reaction zone has been generated by infiltration of hydrous fluids at T of 660–700 °C and P < 1.2 GPa, which occurred during exhumation of coupled continental crust and mantle peridotites.The reaction zone between a trace element-rich (gneiss) and a trace element depleted reservoir (peridotite) allows assessment of local trace element mobility in aqueous fluids. We present the results of in situ LA-ICP-MS trace element analysis of minerals from the reaction zone. Phlogopite is the main host for Large Ion Lithophile Elements (LILE) and contributes significantly to the Li, Ti, Nb, Ta, Pb and Sc budget. Anthophyllite is the main host for Li whereas all other trace elements including Rare Earth Elements (REE) are preferentially incorporated into tremolite. Combined with the abundance of these minerals over the contact zone, the mineral trace element data suggests that the LILE and REE were mobile on a small scale of a few centimetres only. Limited mobility of Ta, which is generally regarded as barely mobile in fluids, is documented in elevated contents of Ta in anthophyllite coupled with low Nb/Ta. The high Li content in minerals throughout the reaction zone suggests that Li was the most mobile element.The studied metasomatic zones mirror geochemical processes occurring in subduction zones at the slab–mantle interface. Phlogopite crystallization at the slab–mantle interface is an efficient mechanism to filter LILE from the aqueous fluid. Thus, such reaction zones, forming at temperatures < 660–700 °C, likely prevents that the typical slab signature with enriched LILE is transported by aqueous fluids over long distances in the mantle wedge. However, if coupled to the downgoing slab, phlogopite- and tremolite-rich rocks from such reaction zones might be able to act as carriers of trace elements and water into deeper parts of the subduction zone.     

Evolution of the Galicia Interior Basin over the last 60 ka: sedimentary processes and palaeoceanographic implications

The Galicia Interior Basin (GIB; NW Iberian Peninsula) is located near a critical transition between the subtropical (temperate) and subpolar (cold) gyres of the North Atlantic. It therefore witnesses oceanographic changes driven by global climatic events. This study reports on the recent (latest Pleistocene) sedimentary, palaeoceanographic and palaeoclimatic history of the basin. We integrated analysis of deep‐sea sediment cores retrieved from an E–W transect across the GIB. The analysis indicated three types of sedimentary processes recording glacial (Marine Isotope Stage 2–4) and deglacial events: along‐slope bottom currents (forming contourite deposits), pelagic and hemipelagic sedimentation, and gravitational dislocation. Variation in depositional patterns and sedimentation rates indicate distinctive transport (along‐slope and down‐slope) and depositional processes. These in turn reflect climatic and oceanographic drivers. We interpret changes in sea level from core evidence showing changes in sediment supply. The cores exhibited conspicuous sedimentary evidence of Heinrich events (HEs). The stratigraphic intervals associated with HEs showed significant lateral variation. We suggest that the lateral variation may result from the development of an oceanographic boundary between surface water masses with different temperature and salinity parameters or changes in surface currents which may have introduced relatively warmer water into the GIB during the last glacial period.     

Phytoplankton pigments and epifluorescence microscopy as tools for ecological status assessment in coastal and estuarine waters, within the Water Framework Directive

Inverted microscopy is widespread employed for the analysis of phytoplankton composition within water quality monitoring networks. However, the analysis at the lowest taxonomical level is not always required for ecological status assessment. In addition, inverted microscopy can underestimate the small phytoplankton, and not always distinguish photoautotrophic from heterotrophic cells. In this study, as alternative tools, epifluorescence microscopy and High Performance Liquid Chromatography (HPLC) were employed to characterize phytoplankton communities within waters of different trophic condition. Epifluorescence microscopy confirmed its effectiveness to count the small phytoplankton. Furthermore, significant correlations between nutrients of anthropogenic origin and nanoplankton abundances were found. However, this technique resulted very time-consuming. HPLC together with the CHEMTAX program was more appropriate than inverted microscopy, in terms of cost-effectiveness. Also, the main variability patterns observed in the phytoplankton community structure by HPLC coincided with previous findings in the study area. Nevertheless, a rapid screening at the inverted microscope is recommended.     

Rapid characterisation of the extremely large landslide threatening the Rules Reservoir (Southern Spain)

Landslides - When an active landslide is first identified in an artificial reservoir, a comprehensive study has to be quickly conducted to analyse the possible hazard that it may represent to such...     

Impact of the brine from a desalination plant on a shallow seagrass (Posidonia oceanica) meadow

Although seawater desalination has increased significantly over recent decades, little attention has been paid to the impact of the main by-product (hypersaline water: brine) on ecosystems. In the Mediterranean, potentially the most affected ecosystems are meadows of the endemic seagrass Posidonia oceanica. We studied the effect of brine on a shallow P. oceanica meadow exposed to reverse osmosis brine discharge for more than 6 years. P. oceanica proved to be very sensitive to both eutrophication and high salinities derived from the brine discharge. Affected plants showed high epiphyte load and nitrogen content in the leaves, high frequencies of necrosis marks, low total non-structural carbohydrates and low glutamine synthetase activity, compared to control plants. However, there was no indication of extensive decline of the affected meadow. This is probably due to its very shallow situation, which results in high incident radiation as well as fast dilution and dispersion of the brine plume.     

Development of a User-Centred Web-Mapping Application for Ocean Modellers

Abstract

This paper reports on the User-Centred Design and development of a web-mapping application from the Ocean Mapping Group (OMG) at the University of New Brunswick (UNB), to deliver ocean mapping data to ocean modellers. First, a work domain analysis was conducted to determine the required application functionality and content, consisting of an ocean modeller informal interview, a competitive analysis, and an online survey. Taking insight from the work domain analysis, a requirements document was prepared to support the development of the first application prototype. This prototype was then evaluated by eight target users, using a cognitive walkthrough and an online survey. The results from this evaluation led to a series of revisions to the functionality, content, and interface of the web-mapping application, establishing the revised prototype. The results showed a useful tool, end-user satisfaction, and stated a wide range of recommendations to enhance functionality for the next steps of the development.     

Quaternary landscape evolution and erosion rates for an intramontane Neogene basin (Guadix–Baza basin, SE Spain)

The landscape evolution in Neogene intramontane basins is a result of the interaction of climatic, lithologic, and tectonic factors. When sedimentation ceases and a basin enters an erosional stage, estimating erosion rates across the entire basin can offer a good view of landscape evolution. In this work, the erosion rates in the Guadix–Baza basin have been calculated based on a volumetric estimate of sediment loss by river erosion since the Late Pleistocene. To do so, the distribution of a glacis surface at ca. 43 kyr, characterised by a calcrete layer that caps the basin infilling, has been reconstructed. To support this age, new radiometric data of the glacis are presented. The volume of sediment loss by water erosion has been calculated for the entire basin by comparing the reconstructed geomorphic surface and the present-day topography. The resulting erosion rates vary between 4.28 and 6.57 m³ ha^− 1 yr^− 1, and are the consequence of the interaction of climatic, lithologic, topographic, and tectonic factors. Individual erosion rates for the Guadix and Baza sub-basins (11.80 m³ ha^− 1 yr^− 1 and 1.77 m³ ha^− 1 yr^− 1 respectively) suggest different stages of drainage pattern evolution in the two sub-basins. We attribute the lower values obtained in the Baza sub-basin to the down-throw of this sub-basin caused by very recent activity along the Baza fault.