The multiple chronological techniques applied to the Lake Suigetsu SG06 sediment core,central Japan

The varved sediment of Lake Suigetsu (central Japan) provides a valuable opportunity to obtain high‐resolution, multi‐proxy palaeoenvironmental data across the last glacial/interglacial cycle. In order to maximize the potential of this archive, a well‐constrained chronology is required. This paper outlines the multiple geochronological techniques being applied – namely varve counting, radiocarbon dating, tephrochronology (including argon–argon dating) and optically stimulated luminescence (OSL) – and the approaches by which these techniques are being integrated to form a single, coherent, robust chronology. Importantly, we also describe here the linkage of the floating Lake Suigetsu (SG06) varve chronology and the absolute (IntCal09 tree‐ring) time scale, as derived using radiocarbon data from the uppermost (non‐varved) portion of the core. This tie‐point, defined as a distinct (flood) marker horizon in SG06 (event layer B‐07–08 at 1397.4 cm composite depth), is thus derived to be 11 255 to 11 222 IntCal09 cal. years BP (68.2% probability range).     

Identification of rural land management signals in runoff response

Rural land management signals in catchment‐scale runoff have proven difficult to identify in general. The Pontbren experimental catchment in upland Wales, UK, provides a new data set with which to address this challenge. This data set includes more than 4 years of data from six tipping bucket rainfall gauges and eight stream flow gauges representing different land management regimes at different scales. Data‐based mechanistic rainfall–runoff models were fitted to this data set using the CAPTAIN toolbox. The spatial and temporal variabilities of model parameters were identified and interpreted where possible. The analysis highlighted a dependency between the modelled residence time and the presence of agriculturally improved grassland, which produced a flashier response than grassland in a more natural condition. Another factor found to strongly affect the spatial variability of runoff response was the presence of lakes, while catchment area had a less pronounced effect, and the influence of trees, steepness and soil type could not be identified. Some time variability of response was observed but this was not consistent across the catchment and could not easily be interpreted. Copyright © 2010 John Wiley & Sons, Ltd.     

Investigating controls on the thermal sensitivity of Pennsylvania streams

Stream temperature, an important measure of ecosystem health, is expected to be altered by future changes in climate and land use, potentially leading to shifts in habitat distribution for aquatic organisms dependent on particular temperature regimes. To assess the sensitivity of stream temperature to change in a region where such a shift has the potential to occur, we examine the variability of and controls on the direct relationship between air and water temperature across the state of Pennsylvania. We characterized the relationship between air and stream temperature via linear and nonlinear regression for 57 sites across Pennsylvania at daily and weekly timescales. Model fit (r²) improved for 92% (daily) and 65% (weekly) of sites for nonlinear versus linear relationships. Fit for weekly versus daily regression analysis improved by 0·08 for linear and 0·06 for nonlinear regression relationships. To investigate the mechanisms controlling stream temperature sensitivity to environmental change, we define ‘thermal sensitivity’ as the sensitivity of stream temperature of a given site to change in air temperature, quantified as the slope of the regression line between air and stream temperature. Air temperature accounted for 60–95% of the daily variation in stream temperature for sites at or above a Strahler stream order (SO) of 3, with thermal sensitivities ranging from low (0·02) to high (0·93). The sensitivity of stream temperature to air temperature is primarily controlled by stream size (SO) and baseflow contribution. Together, SO and baseflow index explained 43% of the variance in thermal sensitivity across the state, and 59% within the Susquehanna River Basin. In small streams, baseflow contribution was the major determinant of thermal sensitivity, with increasing baseflow contributions resulting in decreasing sensitivity values. In large streams, thermal sensitivity increased with stream size, as a function of accumulated heat throughout the stream network. Copyright © 2011 John Wiley & Sons, Ltd.     

The Late Devensian (<22,000 BP) Irish Sea Basin: The sedimentary record of a collapsed ice sheet margin

The Late Devensian (<20 ka BP) glacial geology of the Irish Sea Basin (4000 km²) is an event stratigraphy recording the entry of marine waters into a glacio-isostatically-depressed basin, and the rapid retreat of the Irish Sea Glacier as a tidewater ice margin. Marine limits occur up to 140 m O.D. Across much of the central basin, the ice margin was uncoupled from its bed exposing a subglacially-scoured topography to glaciomarine processes. The Irish Sea Glacier was a major drainage conduit of the last British Ice Sheet; calving of the marine ice margin resulted in fast flow (surging) of ice streams recorded by drumlin fields around the northern basin margin and tunnel valleys. Rapid evacuation of the basin may have stranded large areas of dead ice in peripheral zones (e.g. Cheshire/Shropshire Lowlands) and initiated the collapse of the ice sheet.Thick wedges of ice-contact glaciomarine sediments were deposited during ice retreat as morainal bank complexes by successive tidewater ice margins stabilized at pinning points around the Irish Sea coast. Where morainal banks occur on the seaward side of drumlin swarms there is a clear sequential relationship between rapid ice loss from calving ice margins, the development of fast flowing ice streams, drumlinization and the pumping of subglacial sediment to tidewater. Raised delta complexes are locally associated with marine limits along the high relief coastal margins of Wales, east central Ireland, and the Lake District. Associated valley infill complexes record downslope resedimentation of heterogenous sediments into the marine environment during ice retreat. Co-eval offshore deposits are represented by well-stratified glaciomarine complexes that infill a subglacially-scoured topography that shows networks of tunnel valleys. Glaciomarine mud drapes occur well to the south of the maximum limit of grounded ice in the basin (e.g. North Devon, Scilly Islands, Southern Ireland). The age of these distal sediments, previously mapped as pre-Devensian tills, is constrained by amino acid ratios.Basin rebound following deglaciation was rapid, with over 100 m recovery in 3 ka, and was followed by a low marine still stand. Peat, accumulating in offshore areas now as much as 55 m below sea level has been drowned by the postglacial eustatic rise in sea level.The glacio-sedimentary model identified in this paper, involving rapid ice retreat and related sedimentation triggered by rising relative sea level, suggests that isotatic downwarping is an important mechanism for deglaciating continental shelves.     

Characteristics and origins of lee-side stratification sequences in late pleistocene drumlins,northern Ireland

Spindle- and parabolic-shaped drumlins examined at fifty-five localities in northern Ireland possess stratification sequences on their lee-side flanks. These forms lack the distinctive steep stoss- and tapering lee-ends of classical drumlins and tend to occur in linear zones transverse to late Pleistocene ice-flow. In most cases (90 per cent) the stratified deposits infill embayments excavated in the lee-side of barkhanoid forms and, in the remainder (10 per cent), they are superimposed on the lee-side of whaleback forms. The stratification sequences developed as a result of sedimentation in interconnected subglacial water-filled cavities and are unlike remanie proglacial sediments moulded by ice into drumlin form. Stratigraphic evidence indicates that the lee-side sequences developed during drumlin streamlining, which supports the view that subglacial hydraulic processes played an important role in drumlin formation.     

Trace element distribution in the soils above deeply weathered pegmatites, Virginia, U.S.A.: implications for exploration

Chemical partitioning data are of fundamental interest to exploration geochemists. This paper is one of the few studies which has investigated the relative proportions of the rare elements in various soil extracts. The dispersion of trace elements from weathering pegmatites in Powhatan Country, Virginia, was found to be restricted to the immediate vicinity of the pegmatites. A sequential extraction procedure was used to measure the distribution of Be, La, Nb, Sn, U, Li, and Ni,among the following fractions of the B soil horizons: exchangeable, Fe and Mn oxyhydroxide, residual, and aqua regia digestion. The elements Sn, Be, Li, and U were found to be associated with soils over the complex Herbb No. 2 pegmatite, whereas La and Ni were generally associated with the background soils.A geochemical exploration model was developed using stepwise discriminant function analysis to determine the combination of elements and soil extracts that best differentiates between complex pegmatitic, simple pegmatitic, and background soils. Log-transformed aqua regia extract concentrations of Sn, La, U, and Li were the most effective variables when used to separate complex pegmatitic from simple pegmatitic soils.     

Worldwide variations in the attenuative properties of the upper mantle as determined from spectral studies of short-period body waves

A worldwide study of short-period teleseismic body wave spectra shows that the high frequency falloff rates of spectra are correlated with the tectonic type of the source and receiver regions and with source depth. The data indicate, in a consistent manner, that the main cause for such variations is the lateral variation of Q in the upper mantle as well as change of Q with depth. Using the internal consistency checks provided by redundancies in the data set other effects such as crustal, site dependent distortion of the spectra, source effects and instrument non-linearity can be ruled out as significant factors influencing the $\text{t1}$ estimates obtained. The results indicate high attenuation in the upper mantle under tectonic regions and new oceans. Long-period regional attenuation studies indicate similar variations in mantle Q among the types of regions mentioned but yield significantly lower Q estimates in all areas. The short- and long-period attenuation results can be reconciled only by assuming a frequency dependent Q that increases with frequency along all types of paths, such that the relative differences in Q along various types of paths retain the same sign over the short- and long-period bands.     

Stepwise fluorination—a useful approach for the isotopic analysis of hydrous minerals

Analytical uncertainties in oxygen isotopic studies of hydrous silica have been investigated using a partial fluorination procedure in which fractional oxygen yields are achieved by reducing the amount of fluorine. Stepwise reaction of opaline silica results in a set of sequential oxygen fractions which show a wide range of δ¹⁸O values due to variable amounts of water, organic matter, and other impurities, δ-values for successive fractions in non-biogenic opal systematically increase as water is reacted away and then remain constant to within ±0.2%. as the remaining silica reacts, δ-values in biogenic silica increase similarly but then decrease when low ¹⁸O oxide(?) impurities begin to react.The troublesome water component in opal is readily removed by Stepwise fluorination. This technique allows more precise oxygen isotope analysis of non-biogenic opal-A, and may improve the analytical precision for biogenic silica and any silicate mineral containing a significant water component.