Automated Image Registration for Hydrologic Change Detection in the Lake-Rich Arctic

Multitemporal remote sensing provides a unique tool to track lake dynamics at the pan-Arctic scale but requires precise registration of thousands of satellite images. This is a challenging task owing to a dearth of stable features to be used as tie points [(TPs), i.e., control points] in the dynamic landscapes. This letter develops an automated method to precisely register images in the lake-rich Arctic. The core premise of the method is that the centers of lakes are generally stable even if their shorelines are not. The proposed procedures first extract lakes in multitemporal satellite images, derive lake centroids and match them between images, and then use the centroids of stable lakes as TPs for image registration. The results show that this approach can achieve subpixel registration accuracy, outcompeting the conventional manual methods in both efficiency and accuracy. The proposed method is fully automated and represents a feasible way to register images for lake change detection at the pan-Arctic scale.      

The Khvalynian transgression of the Caspian Sea and the New-Euxinian basin of the Black Sea

The Late Pleistocene history of the Caspian and Black seas is considered. It is suggested that the New-Euxinian basin was to a great degree due to the penetration of the Caspian water through the Manych depression into the Black Sea during the Caspian-Early Khvalynian transgression.     

Using the geologic setting of talc deposits as an indicator of amphibole asbestos content

This study examined commercial talc deposits in the U.S. and their amphibole-asbestos content. The study found that the talc-forming environment directly influenced the amphibole and amphibole-asbestos content of the talc deposit. Large talc districts in the U.S. have mined hydrothermal talcs that replaced dolostone. Hydrothermal talcs, created by siliceous fluids heated by magmas at depth, consistently lack amphiboles as accessory minerals. In contrast, mineable talc deposits that formed by contact or regional metamorphism consistently contain amphiboles, locally as asbestiform varieties. Examples of contact metamorphic deposits occur in Death Valley, California; these talc-tremolite deposits contain accessory amphibole-asbestos. Talc bodies formed by regional metamorphism always contain amphiboles, which display a variety of compositions and habits, including asbestiform. Some industrial mineral deposits are under scrutiny as potential sources of accessory asbestos minerals. Recognizing consistent relations between the talc-forming environment and amphibole-asbestos content may be used in prioritizing remediation or monitoring of abandoned and active talc mines.     

New data on the composition of jordanite–geocronite Pb–Sb–As sulfosalts at the Berezitovoe deposit (Upper Amur Region,Russia)

New data on the composition of jordanite–geocronite Pb–Sb–As sulfosalts in the vein–disseminated gold ore at the Berezitovoe deposit were provided. Within the studied quartz–sulfide sample, some grains of Pb–Sb–As sulfosalts, uniform in composition and azonal, are drastically different from each other in As and Sb contents forming a quasi-continuous range of solid compounds from jordanite to geocronite. Jordanite–geocronite minerals at the Berezitovoe deposit (relative to the Darasun deposit) are characterized by a higher Pb concentration with a low polymetal total. It is assumed that such typomorphic features of the composition of Pb–Sb–As sulfosalts are indicative of specific formation conditions of gold mineralization in polymetallic ores at the Berezitovoe deposit.     

Comparison of transfer functions in statistical downscaling models for daily temperature and precipitation over Canada

This study compares three linear models and one non-linear model, specifically multiple linear regression (MLR) with ordinary least squares (OLS) estimates, robust regression, ridge regression, and artificial neural networks (ANNs), to identify an appropriate transfer function in statistical downscaling (SD) models for the daily maximum and minimum temperatures (T_max and T_min) and daily precipitation occurrence and amounts (P_occ and P_amount). This comparison was made over twenty-five observation sites located in five different Canadian provinces (British Columbia, Saskatchewan, Manitoba, Ontario, and Québec). Reanalysis data were employed as atmospheric predictor variables of SD models. Predictors of linear transfer functions and ANN were selected by linear correlations coefficient and mutual information, respectively. For each downscaled case, annual and monthly models were developed and analysed. The monthly MLR, annual ANN, annual ANN, and annual MLR yielded the best performance for T_max, T_min, P_occ and P_amont according to the modified Akaike information criterion (AICu). A monthly MLR is recommended for the transfer functions of the four predictands because it can provide a better performance for the T_max and as good performance as the annual MLR for the T_min, P_occ, and P_amount. Furthermore, a monthly MLR can provide a slightly better performance than an annual MLR for extreme events. An annual MLR approach is also equivalently recommended for the transfer functions of the four predictands because it showed as good a performance as monthly MLR in spite of its mathematical simplicity. Robust and ridge regressions are not recommended because the data used in this study are not greatly affected by outlier data and multicollinearity problems. An annual ANN is recommended only for the T_min, based on the best performance among the models in terms of both the RMSE and AICu.     

Adsorption of copper, nickel and lead ions from synthetic semiconductor industrial wastewater by palm shell activated carbon

Granular activated carbon produced from palm kernel shell was used as adsorbent to remove copper, nickel and lead ions from a synthesized industrial wastewater.Laboratory experimental investigation was carried out to identify the effect of pH and contact time on adsorption of lead, copper and nickel from the mixed metals solution. Equilibrium adsorption experiments at ambient room temperature were carried out and fitted to Langmuir and Freundlich models. Results showed that pH 5 was the most suitable, while the maximum adsorbent capacity was at a dosage of 1 g/L, recording a sorption capacity of 1.337 mg/g for lead, 1.581 mg/g for copper and 0.130 mg/g for nickel. The percentage metal removal approached equilibrium within 30 min for lead, 75 min for copper and nickel, with lead recording 100 %, copper 97 % and nickel 55 % removal, having a trend of Pb²⁺ > Cu²⁺ > Ni²⁺. Langmuir model had higher R² values of 0.977, 0.817 and 0.978 for copper, nickel and lead respectively, which fitted the equilibrium adsorption process more than Freundlich model for the three metals.     

ISTOK hydrologic probes: development and application

A brief survey of the thirty-year history of creation and development of hydrologic probes at the Marine Hydrophysical Institute of the Ukrainian Academy of Sciences is given. We describe problems arisen before developers and analyze the principles of design of equipment, algorithmic support, software for data processing, and methodological and metrological support. The results of intercalibration and application of probes in expeditions are presented. Translated by Peter V. Malvshev and Dmitry V. Malyshev     

Does upward seepage of river water and storm water runoff determine water quality of urban drainage systems in lowland areas? A case study for the Rhine–Meuse delta

The water quality of urban drainage ditches in lowlands in the Rhine‐Meuse delta was analysed with principal component analysis (PCA) during a dry period and a rain storm, and related to the seepage of polluted river water and effective impervious area (EIA). This was done in order to test the hypothesis that seepage of river water and storm water runoff from impervious areas strongly determine the water quality of urban drainage systems along large lowland rivers. Our analysis revealed that upward seepage of groundwater originating from rivers Rhine and Meuse was positively correlated with nitrate, potassium, sodium and chloride and negatively correlated with alkalinity, calcium, magnesium and iron. EIA was correlated with very few environmental variables (i.e. phosphate, pH and iron in the dry period and iron during the rain storm). Nickel and zinc concentrations generally exceeded the maximum allowable concentrations (MAC), while lead and phosphorus concentrations were just above the nutrient standards and MAC in a few locations during the rain storm. To optimize water quality in urban water systems, attention should be paid to all sources of pollution and not only to EIA. The impact of local groundwater seepage originating from large rivers in lowlands on the chemistry of urban water systems is often underestimated and should be taken into account when assessing water quality and improving water quality status. Copyright © 2009 John Wiley & Sons, Ltd.     

Kinetics of Disproportionation of Inorganic Polysulfides in Undersaturated Aqueous Solutions at Environmentally Relevant Conditions

The rate of the reversible homogeneous disproportionation of polysulfides was studied by following the optical absorbance of polysulfide solutions in a continuous plug flow reactor equipped with an on-line photometric detector. In order to avoid heterogeneous slow reactions involving sulfur colloids or precipitate, the reaction was initiated by an abrupt pH change from an undersaturated solution containing predominantly tetrasulfide species to a pH where pentasulfide is the dominant species. The disproportionation was found to follow first order reversible reaction dynamics. At environmentally relevant conditions the characteristic time of the disproportionation reaction is of the order of 10 s. This characteristic time implies that necessary conditions for speciation of the different polysulfide species by chromatography or another separation and subsequent quantification scheme should be of the order of 1 s.