Quality Assurance in TFS for Inorganic Compounds

A quality assurance program for the three main field experiments in TFScovering O₃, NO, NO_x, NO_y, CO,O₃ LIDARs and meteorological parameters was designed andexecuted. The results are presented and problems encountered during the execution phase are discussed. The need for and the benefit of independent quality assurance activities is demonstrated and documented in detailed meta data files that are part of the final data set.     

The relevance of preferential flow in catchment scale simulations: Calibrating a 3D dual-permeability model using DREAM

The occurrence of preferential flow in the subsurface has often been shown in field experiments. However, preferential flow is rarely included in models simulating the hydrological response at the catchment scale. If it is considered, preferential flow parameters are typically determined at the plot scale and then transferred to larger-scale simulations. Here, we successfully used the optimization algorithm DiffeRential Evolution Adaptive Metropolis (DREAM) to calibrate a 3D physics-based dual-permeability model directly at the catchment scale. In order to keep computational costs of the optimization routine at a reasonable level, we limited the number of parameters to be calibrated to the ones that had been shown before to be most influential for the simulation of discharge. We also calibrated parameters of the matrix domain and the macropore domain with a fixed parameter ratio between soil layers instead of calibrating every layer separately. These ratios reflected observed depth profiles of soil hydraulic properties at our study site. The dual-permeability parameter sets identified during calibration were able to simulate observed discharge time series satisfactorily but did not outperform a calibrated single-domain reference model scenario. Saturated hydraulic conductivities of the macropore domain were calibrated such that they became very similar to matrix saturated hydraulic conductivities, thereby effectively removing the effect of macropores. This suggests that the incorporation of vertical preferential flow as represented by the dual-permeability approach was not relevant for reproducing the hydrometric response reasonably well in the studied catchment. We also tested the scale-invariance of the calibrated dual-permeability parameter sets by using the parameter sets performing best at catchment scale to simulate plot-scale bromide depth profiles obtained from tracer irrigation experiments. This parameter transfer proved to be not successful, indicating that soil hydraulic parameters are scale-variant, independent of the direction of parameter transfer.     

A Theoretical Framework for Hyperspectral Anomaly Detection Using Spectral and Spatial A Priori Information

This letter presents a new theoretical approach for anomaly detection using a priori information about targets. This a priori knowledge deals with the general spectral behavior and the spatial distribution of targets. In this letter, we consider subpixel and isolated targets that are spectrally anomalous in one region of the spectrum but not in another. This method is totally different from matched filters that suffer from a relative sensitivity to low errors in the target spectral signature. We incorporate the spectral a priori knowledge in a new detection distance, and we propose a Bayesian approach with a Markovian regularization to suppress the potential targets that do not respect the spatial a priori. The interest of the method is illustrated on simulated data consisting in realistic anomalies that are superimposed on a real HyMap hyperspectral image.     

Fate and effects of picric acid and 2,6-DNT in marine environments: toxicity of degradation products

The toxicity of transformation products of 2,6-dinitrotoluene (2,6-DNT) and 2,4,6-trinitrophenol (picric acid) were assessed in spiked sandy and fine-grained marine sediments and in seawater. Toxicity of pore water from sediments spiked with 2,6-DNT decreased for the macro-alga, Ulva fasciata, zoospores as biotransformation proceeded, but increased for the copepod, Schizopera knabeni, nauplii. The primary biotransformation product of 2,6-DNT, 2-amino-6-nitrotoluene, was also more toxic than the parent compound to copepod nauplii, but not to alga zoospores, in spiked seawater tests. Two biotransformation products of picric acid, picramic acid and 2,4-DNP, were more toxic than their parent compound. Porewater toxicity from picric acid-spiked sediments decreased significantly at the end of six-months incubation. Fine-grained sediment spiked with either ordnance compound had lower toxicity than its sandy counterpart after six months, suggesting faster microbial transformation in the former and production of less toxic products. Photo-transformation of 2,6-DNT in seawater resulted in a reduction in toxicity.     

Three-dimensional finite-element modelling of magnetotelluric data with a divergence correction

A finite-element method for computing the electric field in a 3-D conductivity model of the Earth for plane wave sources, thus enabling magnetotelluric responses to be calculated, is presented. The method incorporates in the iterative solution of the electric-field system of equations the divergence correction technique introduced for finite-difference solutions by Smith (1996). The correction technique accelerates the development of the discontinuity of the normal component of the approximate electric field across conductivity discontinuities. The convergence rate of the iterative solution is improved significantly, especially for low frequencies. The correction technique involves computing the divergence of the current density for the approximate electric field, computing the static potential whose source is this divergence of the current density, and ‘correcting’ the approximate electric field by subtracting from it the gradient of the potential. This is repeated at regular intervals during the iterative solution of the electric-field system of equations. For the method presented here, the Earth model is discretised using a rectilinear mesh comprising uniform cells. Edge-element basis functions are used to approximate the electric field and nodal basis functions are used to approximate the correction potential. The Galerkin method is used to derive the systems of equations for the approximate electric field and correction potential from the respective differential equations. A bi-conjugate gradient solver was found to be adequate for the system of equations for the correction potential; a generalised minimum residual solver was found to be better for the electric-field system of equations. The method is illustrated using the COMMEMI 3D-1A and 3D-2A models.     

Deciphering the weathering processes using environmental mineralogy and geochemistry: Towards an integrated model of laterite and podzol genesis in the Upper Amazon Basin

This article reports major results from collaborative research between France and Brazil on soil and water systems, carried out in the Upper Amazon Basin. It reveals the weathering processes acting in the partly inundated, low elevation plateaus of the Basin, mostly covered by evergreen forest. Our findings are based on geochemical data and mineral spectroscopy that probe the crystal chemistry of Fe and Al in mineral phases (mainly kaolinite, Al- and Fe-(hydr)oxides) of tropical soils (laterites). These techniques reveal crystal alterations in mineral populations of different ages and changes of metal speciation associated with mineral or organic phases. These results provide an integrated model of soil formation and changes (from laterites to podzols) in distinct hydrological compartments of the Amazon landscapes and under altered water regimes.     

Impact of the Doha outcome on surplus emission allowances and their effect on developed country emissions

The outcome from the December 2012 climate negotiations in Doha has clarified the rules regarding surplus units for the Kyoto Protocol. We summarize these new rules and estimate the resulting effective emissions during the second commitment period using our unit trade model. Other options to deal with surplus emission allowances are employed as benchmarks to assess the Doha outcome. The effective emissions for developed countries as a group under the Doha outcome could be 10–11 % below 1990 levels or 4–5 % points below business-as-usual levels for the second commitment period if we assume that non-Kyoto Protocol countries domestically achieve their targets. However, if mechanisms exist where non-Kyoto Protocol countries can trade units, their emissions could increase and effective emissions for developed countries could be 7–8 % below 1990 levels. In this low-ambition situation we find the main impact of the Doha surplus rules to be the introduction of the historical cap on emissions allowances. Without the effect of the cap, the Doha outcome allows the Parties to the second commitment period to emit at business-as-usual levels until 2020, while still leaving surplus units at the end of the second commitment period.     

Simulations of VLBI observations of a geodetic satellite providing co-location in space

We performed Monte Carlo simulations of very-long-baseline interferometry (VLBI) observations of Earth-orbiting satellites incorporating co-located space-geodetic instruments in order to study how well the VLBI frame and the spacecraft frame can be tied using such measurements. We simulated observations of spacecraft by VLBI observations, time-of-flight (TOF) measurements using a time-encoded signal in the spacecraft transmission, similar in concept to precise point positioning, and differential VLBI (D-VLBI) observations using angularly nearby quasar calibrators to compare their relative performance. We used the proposed European Geodetic Reference Antenna in Space (E-GRASP) mission as an initial test case for our software. We found that the standard VLBI technique is limited, in part, by the present lack of knowledge of the absolute offset of VLBI time to Coordinated Universal Time at the level of microseconds. TOF measurements are better able to overcome this problem and provide frame ties with uncertainties in translation and scale nearly a factor of three smaller than those yielded from VLBI measurements. If the absolute time offset issue can be resolved by external means, the VLBI results can be significantly improved and can come close to providing 1 mm accuracy in the frame tie parameters. D-VLBI observations with optimum performance assumptions provide roughly a factor of two higher uncertainties for the E-GRASP orbit. We additionally simulated how station and spacecraft position offsets affect the frame tie performance.