Is there a possibility to correct fossil n-alkane data for postsedimentary alteration effects?

The long chain n-alkane composition of plant material can significantly differ between plant groups e.g. trees and grasses. Due to their relative recalcitrance, they have been employed in paleoecological research as molecular proxies for different types of vegetation. Most of those paleoenvironmental studies rely on the assumption that characteristic molecular fingerprints of plant material are preserved in the fossil organic material without significant alteration. However, there exists evidence that n-alkane distributions may change in the course of plant litter degradation. Here, the authors propose and discuss a conceptual approach to the correction of n-alkane patterns in paleosols and terrestrial sediments for postsedimentary alteration effects. This might have potential to improve paleoenvironmental reconstructions derived from these molecular fossils. In soil depth profiles typically a correlation between the OEP (odd over even predominance) and paleoecological valuable long-chain n-alkane ratios (LARs) can be found. Similar relationships have been also obtained from n-alkane records in paleosols. With the OEP serving as a proxy of microbial reworking, the correction procedure applies OEP vs. LAR regression functions to correct fossil LARs for degradation effects. The regression functions have been derived from modern soils. The application of the procedure and its significance for paleoecological interpretations is demonstrated on a case study of a loess-paleosol sequence (∼400–700 ka) in Romania. It is shown that changes in the C27/C31 n-alkane ratio at this site are closely related to degradation effects rather than to changes in the paleovegetation (e.g. tree vs. grass abundance). However, it was found that the C29/C31 ratio is a more suitable paleoenvironmental proxy at the Mircea Voda site. The results indicate that there is a future potential to correct fossil n-alkane ratios via the OEP/LAR relationship, however at the moment a general straight forward application of this approach might be critical due to lack of extended and diverse n-alkane records from modern soils. The need of more systematic n-alkane studies on soil profiles is highlighted to improve knowledge concerning dynamics and actual mechanisms of postsedimentary LAR and OEP changes.     

Use of archaeology to date liquefaction features and seismic events in the New Madrid seismic zone,Central United States

Prehistoric earthquake-induced liquefaction features occur in association with Native American occupation horizons in the New Madrid seismic zone. Age control of these liquefaction features, including sand-blow deposits, sand-blow craters, and sand dikes, can be accomplished by extensive sampling and flotation processing of datable materials as well as archaeobotanical analysis of associated archaeological horizons and pits. This approach increases both the amount of carbon for radiocarbon dating and the precision dating of artifact assemblages. Using this approach, we dated liquefaction features at four sites northwest of Blytheville, Arkansas, and found that at least one significant earthquake occurred in the New Madrid seismic zone between A.D. 1180 and 1400, probably about A.D. 1300 ± 100 yr. In addition, we found three buried sand blows that formed between 3340 B.C. and A.D. 780. In this region where very large to great earthquakes appear to be closely timed, archaeology is helping to develop a paleoearthquake chronology for the New Madrid seismic zone. © 1996 John Wiley & Sons, Inc.     

Identification of Atlantic water inflow on the north Svalbard shelf during the Holocene

Nordaustlandet is located in the northeastern part of the Svalbard archipelago, within the northernmost reach of the West Spitsbergen Current. This current transports Atlantic water to the Arctic Ocean along the western and northern Svalbard margins. This region is well-suited for reconstructing the history of changing Atlantic water inflow to the Arctic Ocean. We studied the marine sediment core HH12-04-GC from Rijpfjorden. Benthic foraminiferal assemblages and sedimentological data are combined to reconstruct the palaeoenvironment of the fjord from the end of the last local deglaciation to the late Holocene. The local deglaciation, between 11.3 and 10.6 cal ka bp , was dominated by active glacier calving processes, associated with a strong inflow of Atlantic water. This led to the establishment of glaciomarine conditions. The Holocene was initially characterised by a relatively stable and warm environment associated with a strong contribution of Atlantic water. Glaciomarine influence progressively decreases after 9.7 cal ka bp and the Atlantic water contribution increases. The late Holocene displayed a similar environment to today, with the influence of glaciomarine conditions and limited Atlantic water inflow. These results confirm that Atlantic water inflows made a continuous contribution to northern Nordaustlandet throughout the postglacial period.