Chlorinated hydrocarbons in the seawater and surface sediments of Blanca Bay,Argentina

In order to characterize our study area and to provide reference values to be used in the future to measure the changes produced by an increase in contamination, the concentrations of chlorinated hydrocarbons have been investigated in fifty-one samples of seawater, taken at four different depths: air-sea interface, surface, one metre and bottom waters, and in twenty-three samples of surface sediments from Blanca Bay, Argentina. Of eleven organochlorine compounds we were looking for (α BHC, lindane, heptachlor, δ BHC. aldrin, heptachlor epoxide, dieldrin, o-p′DDD, p-p′DDD, o-p′DDT and p-p′DDT), seven could be detected in seawater and three in surface sediments with the following mean concentrations: α-BHC=48·2 ng l^?1; lindane=54·2 ng l^?1; heptachlor=45·0 ng l^?1; δ BHC=12·5 ng l^?1; aldrin=61·8 ng l^?1 and ΣDDT=67·0 ng l^?1; and δ BHC=3·2 ng g^?1; lindane=4·2 ng g^?1 and heptachlor=1·0 ng g^?1 for seawater, regarding the surface waters, and sediment samples, respectively.Concentration factors among the different water layers were also studied to see if there was any correlation between chlorinated hydrocarbon contents and the water depths from which the samples were taken. As a mean value, the air-sea interface water contains 18 times more of these compounds than that of the water near the bottom. A comparison of the values corresponding to seawater and surface sediments from our study area with those levels measured in samples from other geographic locations is also presented.With the purpose to detect a relationship between chlorinated hydrocarbon concentrations and the contents of particulate matter (PM) on the one hand, and particulate organic material (POM) on the other hand, four groups of samples containing different amounts of PM and POM, respectively were formed. From a comparison of the results obtained, lindane, heptachlor and δ BHC showed a tendency to lower concentrations in those samples containing little PM whereas α BHC and aldrin remained without important changes. No significant correlation was found between organochlorine levels and contents of POM.     

Far-infrared properties of metallic dust grains

Far-infrared properties of metallic particle are reinvestigated in detail. In the far-infrared region, absorption due to the eddy current generally dominates over that obtained by using the Rayleigh approximation erroneusly. The wavelength dependence of the eddy current term is examined carefully and shown to be less steep than that predicted by the Rayleigh approximation for dust grains larger than 100 nm in radius. It also depends more sensitively on the grain size. A wider temperature distribution is expected corresponding to a given size distribution and hence the emission spectrum becomes less steep than the preductions by the Rayleigh approximation. Iron and graphite particles are investigated as typical interstellar metallic grains. Effects of coating of dielectric materials are also examined. Comparisons with experimental results and with observations are discussed.     

Fast solar electrons,interplanetary plasma and km-wave type-III radio bursts observed from the IMP-6 spacecraft

IMP-6 spacecraft observations of low frequency radio emission, fast electrons, and solar wind plasma are used to examine the dynamics of the fast electron streams which generate solar type-III radio bursts. Of twenty solar electron events observed between April, 1971 and August, 1972, four were found to be amenable to detailed analysis. Observations of the direction of arrival of the radio emission at different frequencies were combined with the solar wind density and velocity measurements at 1 AU to define an Archimedean spiral trajectory for the radio burst exciter. The propagation characteristics of the exciter and of the fast electrons observed at 1 AU were then conpared. We find that: (1) the fast electrons excite the radio emission at the second harmonic; (2) the total distance travelled by the electrons was between 30 and 70% longer than the length of the smooth spiral defined by the radio observations; (3) this additional distance travelled is the result of scattering of the electrons in the interplanetary medium; (4) the observations are consistent with negligible true energy loss by the fast electrons.     

Position and velocity reliability testing in degraded GPS signal environments

Reliability testing, namely receiver autonomous integrity monitoring (RAIM), consists of statistical testing of least-squares residuals of observations, e.g., on an epoch-by-epoch basis aiming towards reliable navigation fault detection and exclusion (FDE). In this paper, classic RAIM and FDE methods are extended with testing of range-rate residuals to find inconsistent velocity solutions in order to contribute to the reliability of the system with special focus on degraded signal environments. Reliability enhancement efforts discussed include a Backward-FDE scheme based on statistical outlier detection and an iteratively reweighted robust estimation technique, a modified Danish method. In addition, measurement weighting assigned to code and Doppler observations is assessed in the paper in order to allow fitting a priori variance models to the estimation processes. The schemes discussed are also suitable in terms of computational convenience for a combined GPS/Galileo system. The objective of this paper is to assess position and velocity reliability testing and enhancement in urban and indoor conditions and to analyze the navigation accuracy conditions with high sensitivity GPS (HSGPS) tests. The results show the necessity of weighted estimation and FDE for reliability enhancement in degraded signal-environment navigation.     

Zinc, Lead and Cadmium Content in Meadow Plants and Mosses Along the M3 Motorway (Hungary)

The heavy metal content was investigated in meadow plants located in a cultivated area and situated along the M3 motorway (Hungary). In addition to the meadow plants used as passive bioindicators, active bioindicators were also exposed to examine the accumulation rate of air pollutants. Tortula ruralis (Hedw.) Geartn. ssp. ruralis was applied to monitor the status of the environment. Meadow plant samples were collected at distances of 5, 10, 25, 50 and 100 m from the motorway and moss samples were exposed at the same distances. The zinc, lead and cadmium content of meadow plants and moss samples were analysed by ICP spectrophotometry. It was found that the zinc, lead and cadmium contents of the meadow plants decreased as the distance increased from the motorway. There was a significant difference even between values measured at the distances of 5 m and 10 m. The heavy metal contents in the moss samples exceeded those of the meadow plants. The heavy metal content in moss samples decreased with distance from the motorway. On comparing the data with Hungarian standards, it was found that measured values did not exceed the maximum allowed concentration levels.     

Water quality and presence of pesticides in a tropical coastal wetland in southern Mexico

The water quality of the Pozuelos-Murillo lagoon system in southern Mexico was evaluated during three periods between March and October 2002, with particular emphasis on the detection of organochlorine and organophosphorous pesticide residues in water and sediments. Physicochemical and microbiological parameters of water were also measured and integrated in a water quality index (WQI). Multivariate analysis was used to regionalise the lagoon system as a function of the behaviour of all measured parameters. Solid phase micro-extraction followed by gas chromatography (SPME-GC) was used for pesticide analysis. The concentration of phosphorous was found to be higher than that of nitrogenous compounds. This, besides a deficiency in dissolved oxygen and a high organic matter concentration (as COD), reflects eutrophication processes in some areas of the system. Measured levels of faecal coliforms and oils and greases were above the limits established by Mexican law and comparable to the concentrations reported for other highly polluted systems in Mexico. Residues of DDD (2.0 microg L(-1)) in water and DDE (247 ng g(-1)) and endosulfan I (814 ng g(-1)) sediments were detected by SPME-GC. The spatial distribution of these contaminants implies major potential risks because the most polluted sites were found to be those with the highest fishing activity. Although in general the WQI is on acceptable levels (65-80%), some contamination problems are evident.     

Abnormal features of Macoma balthica (Bivalvia) in the Baltic Sea: alerting symptoms of environmental adversity?

Recent studies of the Baltic clam Macoma balthica (L.) from the southern Baltic (the Gulf of Gdansk) have revealed striking morphological, histological and cytogenetic features. Strong deformation of the shell, including elongation of the posterior end and the appearance of an easily visible flexure in this part, has been recorded. The population contribution of the deformed blunt shelled ("irregular") clams ranged from 0% to 65% and tended to increase with depth. The morphologically "irregular" clams had higher accumulated tissue concentrations of trace metals (As, Ag, Cd, Pb, Cu and Zn), indicating a different metal handling ability. Adverse conditions in deeper water regions of the Gulf (e.g. hypoxia, hydrogen sulphide, elevated bioavailability of contaminants) have been suggested as inducers of the phenotypical changes (morphological deformation) in part of the population and, in parallel, of the specific physiological adaptations that result in higher metal accumulation in the "irregular" clams. Cytogenetic and histological analyses showed the presence of tumours in gill cells and digestive system of the affected clams, the prevalence of disseminated neoplasia ranging from 0% to 94% depending on the site. The disease was manifested by a modified karyotype (i.e. an abnormal number and morphology of chromosomes), a higher activity of nucleolar organizer regions (AgNORs), and tissue lesions (enlarged cells, actively proliferative with pleomorphic nuclei). Bottom sediments showed acute toxicity and have been proposed as a source of an initialising carcinogenic factor. However, none of the ecotoxicological studies provided was successful in the clear demonstration of a single (or multifactorial) agent that can account for the disseminated neoplasia.     

Converging P-T paths of Mesozoic HP-LT metamorphic units (Diego de Almagro Island, Southern Chile): evidence for juxtaposition during late shortening of an active continental margin

Summary On Diego de Almagro Island in Chilean Patagonia (51°30S), a convergent strike slip zone, the Seno Arcabuz shear zone, separates the Diego de Almagro Metamorphic Complex from very low grade metagreywackes in the east, which were intruded by Jurassic granitoids. The Diego de Almagro Metamorphic Complex is composed of a metapsammopelitic sequence containing blueschist intercalations in the west and (garnet) amphibolite lenses in the east. Peak metamorphic conditions (stage I) at 9.5–13.5kbar, 380–450°C in the blueschist and at 11.2–13.2, 460–565°C in the amphibolite indicate subduction and accretion at different positions within the deepest part of the accretionary wedge. A K–Ar age of 117±28Ma of amphibole approximately dates the peak of metamorphism in the amphibolite. The early retrograde stage of metamorphism occurred under static conditions and resulted in localized equilibration (stage II) at 6.3–9.6kbar, 320–385°C in the blueschist and 6.1–8.4kbar, 310–504°C in the amphibolite. Both P-T paths converge within a midcrustal level.In contrast, an orthogneiss of trondhjemitic composition occurring within the Seno Arcabuz shear zone is associated with a garnet mica-schist containing a high temperature/intermediate pressure assemblage formed at 4.9–6.5kbar, 580–690°C. A muscovite K–Ar age of 122.2±4.6Ma dates cooling after this event which is related to a concomitant magmatic arc. These rocks were overprinted by a mylonitic deformation, which is caused by convergent strike slip shearing and ends during formation of a retrograde phengite-chlorite-stilpnomelane assemblage at a minimum pressure of approximately 5.7kbar (at 300°C).Zircon fission track ages from rocks of the Seno Arcabuz shear zone are 64.9±2.7 and 64.9±2.7Ma; they record the end of shearing in the Seno Arcabuz shear zone that juxtaposed all rocks in the middle crust. Zircon fission track ages ranging from 78 to 105Ma in the South Patagonian batholith to the east indicate earlier cooling through 280°C. The rocks of the Diego de Almagro Metamorphic Complex were initially slowly exhumed and resided at a midcrustal level before being emplaced via shearing in the Seno Arcabuz shear zone. Apatite fission track ages (54±8Ma) from the Seno Arcabuz shear zone show that exhumation and cooling rates increased after this event. The incorporation of continental crust within the subduction system was a late process, which modified the Cretaceous accretionary wedge, resulting in considerable shortening of the convergent margin.     

Effects of iron black varnish on petrophysical properties of building sandstone

In zones washed by rain (façades, pinnacles, pilasters), fine siliceous sandstones are covered by a black varnish, which gives a dirty appearance to monuments. In composition, structure and areas covered by it, it differs from the usual black gypsum crust. Experiments carried out on blocks covered by black varnish show the modifications due to their growth. Results show that despite their low thickness and the coherence of the stone below, the accumulation of hydrophobic matters and the wetting-drying cycles modify the transfer properties of sandstones several centimeters below the surface. Thus, although sandstones seem to be protected by the black varnish, in the long run, a flake detachment process, in the areas covered by it, affects them. Therefore, damage to sandstones by black varnish can be explained by the fact that a wetting and drying cycle modifies the pore network.