两种盐度参数化方案在海冰模式中的应用比较

本文详细介绍了SIS海冰模式中引进两种盐度参数化方案即等盐度方案和盐度廓线方案对海冰模拟所存在的差异。利用盐度廓线方案导出的表征盐度与海冰温度间关系的方程比等盐度方案多出一项,将定义为盐度差异项。盐度差异项对海冰厚度的热力作用表现为：在海冰厚度增长季节（11月到次年5月）,盐度差异项通过升高海冰内部温度,抑制海冰增长;在消融的第一阶段（6．8月）,盐度差异项通过升高海冰内部温度加快海冰消融;在消融的第二阶段（9．10月）,盐度差异项通过降低海冰内部的温度抑制海冰消融。但尺度分析表明,盐度差异项要比方程中队海冰温度作用最大项小1．2个量级,如果采用一级近似,可以略去盐度差异项,因此盐度差异项对海冰增长和消融影响很小。同时利用冰洋耦合模式（ModularOceanModel,MOM4）,分别采用两种盐度参数化方案模拟北极海冰厚度和海冰密集度的季节性变化,模拟结果也表明两种方案模拟得到的海冰厚度和海冰密集度的季节性变化相差甚小。     

风对中国东部海域海平面季节变化的影响

应用ROMS数值模式配置基本实验模拟了2004年到2006年中国东部海域海平面的季节变化。模拟结果与TOPEX／Poseidon（T／P）卫星高度计观测结果基本一致,海平面年较差从中国沿岸到黑潮路径逐渐变小。将数值模式的风应力项去掉,配置对比实验。与基本实验结果对比发现,对比实验海平面仍然具有季节变化,但是闽浙沿岸和苏北沿岸海平面春夏季异常偏低、秋冬季异常偏高现象消失,中国沿岸向太平洋的海平面变化减弱。春季和秋季,渤、黄海和黑潮附近海平面异于东海的现象减弱。对比实验海平面的年较差的数值明显减小,从近岸向黑潮海平面年较差渐变的过程消失。整个渤黄海的海平面年较差近似。对比实验海平面年较差占基本实验海平面年较差比率从近岸向黑潮路径逐渐增大。     

Index test for the degradation potential of carbonate sands during hydraulic transportation

Carbonate sands undergo degradation when transported hydraulically from a dredging vessel to the reclamation site. Risks involved in the production of fines during hydraulic transport are a deterioration of the mechanical properties of the fill in certain areas of the reclamation area where these fines concentrate. In order to assess sand degradation in the concrete and road construction industry, the Micro-Deval test for fine aggregates was developed in France and Canada. During Micro-Deval testing, aggregates degrade when tumbled in a rotating steel drum with water and steel balls. In the Canadian standard, the steel charge is lower than in the French standard and balls have the diameter of the smallest balls used in the French test. During testing, the quantity of fines produced is measured. This makes the Micro-Deval test an option for assessing the degradation of sand during hydraulic transportation of slurries in the dredging industry. Three sands are tested: two shelly carbonate sands and one quartzic river sand for comparison. The carbonate sands were sampled on reclaimed land and had been subjected to hydraulic transportation in pipeline before artificial deposition. Due to differences in particle shape, the carbonate sands and the quartz sand have a different number of contacts with the steel charge in the drum of the Micro-Deval and are not exposed to the same degradation forces during testing. It was found that the quartzic sand suffers relatively much degradation as compared to the carbonate sands, despite its greater hardness and resistance to crushability. The French test appears to create turbulence that promotes floatation of the curved shells of the carbonate sands instead of shell grinding at the bottom of the drum by contact with the steel balls. Microscopic observations of sand samples before and after testing showed that the French Micro-Deval test is too destructive. The test leads to the fragmentation by impact of the quartz sands and the destruction of certain particle types that had survived hydraulic transportation. With respect to the Canadian test, microscopic examination of sand grains before and after testing shows there is still much fragmentation of quartz grains. A lower rotational speed combined with a limited steel charge made of uniform balls of a smaller diameter, reduces turbulence, shell floatability and last but not the least, impact forces. It produces the desired result: a high Micro-Deval loss for the carbonate sands in comparison to that for the quartz sands and a very limited fragmentation of the quartz grains. Once the slurry reaches its destination, the grain size distribution of the fines fraction will influence the mechanical behaviour of mixed sands. A procedure is proposed to measure the particle size distribution of the fines fraction produced during Micro-Deval testing.Field validation is needed to validate preliminary laboratory results.     

Comparison of instrumental and GDGT-based estimates of sea surface and air temperatures from the Skagerrak

Sea surface temperatures (SSTs) and annual mean air temperatures (MATs) are estimated for the last 200 years from glycerol dialkyl glycerol tetraethers (GDGTs) proxies in a marine sediment core from the Skagerrak, off southern Norway. The reconstructed values compare well with annual SSTs and summer air temperatures obtained from composite regional instrumental records. The results provide further confidence in the application of proxies based on GDGTs to estimate past temperatures.     

Validation of high-resolution TRMM-3B43 precipitation product using rain gauge measurements over Kyrgyzstan

This paper presents the validation of monthly precipitation using Tropical Rainfall Measuring Mission Multisatellite Precipitation Analysis (TMPA)—3B43 product with conventional rain gauge observations for the period 1998–2007 over Kyrgyzstan. This study is carried out to quantify the accuracy of TMPA-3B43 product over the high latitude and complex orographic region. The present work is quite important because it is highly desirable to compare the TMPA precipitation product with the ground truth data at a regional scale, so that the satellite product can be fine-tuned at that scale. For the validation, four different types of spatial collocation have been used: station wise, climatic zone wise, topographically and seasonal. The analysis has been done at the same spatial and temporal scales in order to eliminate the sampling biases in the comparisons. The results show that TMPA-3B43 product has statistically significant correlation (r?=?0.36–0.88) with rain gauge data over the most parts of the country. The minimum linear correlation is observed around the large continental water bodies (e.g., Issyk-Kul lake; r?=?0.17–0.19). The overall result suggests that the precipitation estimated using TMPA-3B43 product performs reasonably well over the plain regions and even over the orographic regions except near the big lake regions. Also, the negative bias suggests the systematic underestimation of high precipitation by TMPA-3B43 product. The analyses suggest the need of a better algorithm for precipitation estimation over this region separately to capture the different types of rain events more reliably.     

Simulation of the interactions between gravity processes and contour currents on the Algarve Margin (South Portugal) using the stratigraphic forward model Sedsim

The margin of the Gulf of Cadiz is swept by an intermediate current the Mediterranean Outflow Water (MOW) flowing from the Mediterranean to the Atlantic. On the northern margin of the Gulf (Algarve Margin, South Portugal) the MOW intensity is low, and fine-grained contourite drifts are built up with an alongslope alignment. Recent sedimentological studies emphasize the presence of complex process interactions resulting in the formation of a unique depositional architecture. Alongslope processes related to contour currents generate contourite drift, while downslope processes form canyons and channels aligned on deep faults. This paper uses a combined oceanographic and geological dataset to simulate the different types of interactions between gravity processes and contour currents, which were evidenced on this margin. An extrapolation of the contour current intensity has been used based on the present day velocity field and sea-level fluctuations over the simulated geological time-scale. According to our model results, the construction of the contourite drift is closely linked to contour current velocities and directions, the types of sediments transported and the existing topography. Using modern sedimentological understanding of the area, we have correlated gravity flow's strongest activity to sea level lowstand periods mainly due to a closer connection between canyon's mouth and river or deltaic systems. The simulated gravity flows are initialized at different locations and times on the margin depending on the preserved lobes retrieved from seismic analysis. Their resulting morphological features are identified as perched-lobes with volumes and forms close to the ones observed on Portimão and Lagos Drifts. This study provides a process-based understanding of the construction of contourite system and a physical evaluation of the interactions between gravity flows perpendicular to the slope, and alongslope processes. In addition, it shows the influence of autocyclic factors in the construction of contourite sedimentation, which is important to consider in future sedimentary paleo-reconstruction interpretations.     

High-resolution analysis of submarine lobes deposits: Seismic-scale outcrops of the Lauzanier area (SE Alps, France)

The Lauzanier area represents the northernmost extension of the Annot Sandstone series and contains deposits between 650 and 900 m-thick. This basin was active from upper Bartonian or lower Priabonian to early Rupelian. It is composed of two superposed units separated by a major unconformity. The sediment supply is due to channelled flows coming from the south. Flow processes include mass flow to turbidity currents. The size of the particles and the absence of fine-grained sediment suggest a transport over a short distance. The Lower Unit is made of coarse-grained tabular beds interpreted as non-channelled lobe deposits. The Upper Unit is made of massive conglomerates interpreted as the channelled part of lobes. These lobe deposits settle in a tectonically confined basin according to topographic compensation that occurs from bed scale to unit scale. The abrupt progradation between the lower and the upper unit seems related to a major tectonic uplift in the area. This uplift is also suggested by a change in the petrographic nature of the source and an abrupt coarsening of the transported clasts.This field example allows providing high resolution analysis for depositional sedimentary sequences of terminal lobe deposits in a coarse-grained turbidite system. The outcrop analysis shows the lateral evolution of deposits and the system progradation allows a longitudinal analysis of facies evolution by superposing on the same outcrops the channelled lobe system and the non-channelled lobe system. These results of high-resolution outcrop analysis can be extrapolated to results obtained on sedimentary lobes in recent deep-sea turbidite system that are either restricted to cores, or with a lesser resolution (seismic).     

Prediction of the thermodynamic properties of metal–chromate aqueous complexes to high temperatures and pressures and implications for the speciation of hexavalent chromium in some natural waters

Log–log correlation plots between the dissociation constants of known metal–chromate complexes and those of corresponding metal–sulfate complexes at 25 °C, 1 bar were used to derive the standard partial molal Gibbs free energies of formation of unknown metal–chromate complexes involving either (i) monovalent cations, divalent cations, and trivalent lanthanides or (ii) trivalent cations (excluding those of rare earth elements, REE) and tetravalent cations. For each of these two classes of ionic associations, empirical relationships between the standard partial molal volumes, isobaric heat capacities and entropies of known metal–chromate complexes and the corresponding thermodynamic properties of metal ions have been found. These data were utilized to evaluate the solute-characteristic parameters of the revised Helgeson–Kirkham–Flowers equation of state and to compute the thermodynamic properties of the dissociation reactions of metal–chromate complexes at high temperatures and pressures.     

A two‐step process for the reflooding of the Mediterranean after the Messinian Salinity Crisis

The Messinian Salinity Crisis is well known to have resulted from a significant drop of the Mediterranean sea level. Considering both onshore and offshore observations, the subsequent reflooding is generally thought to have been very sudden. We present here offshore seismic evidence from the Gulf of Lions and re‐visited onshore data from Italy and Turkey that lead to a new concept of a two‐step reflooding of the Mediterranean Basin after the Messinian Salinity Crisis. The refilling was first moderate and relatively slow accompanied by transgressive ravinement, and later on very rapid, preserving the subaerial Messinian Erosional Surface. The amplitude of these two successive rises of sea level has been estimated at ≤500 m for the first rise and 600–900 m for the second rise. Evaporites from the central Mediterranean basins appear to have been deposited principally at the beginning of the first step of reflooding. After the second step, which preceeded the Zanclean Global Stratotype Section and Point, successive connections with the Paratethyan Dacic Basin, then the Adriatic foredeep, and finally the Euxinian Basin occurred, as a consequence of the continued global rise in sea level. A complex morphology with sills and sub‐basins led to diachronous events such as the so‐called ‘Lago Mare’.This study helps to distinguish events that were synchronous over the entire Mediterranean realm, such as the two‐step reflooding, from those that were more local and diachronous. In addition, the shoreline that marks the transition between these two steps of reflooding in the Provence Basin provides a remarkable palaeogeographical marker for subsidence studies.     

Characteristics of the lithospheric mantle beneath East Serbia inferred from ultramafic xenoliths in Palaeogene basanites

Mantle xenoliths from Paleogene basanites of East Serbia were studied using EMP and LA-ICP-MS techniques in order to better understand mantle characteristics in this region. Five different mantle lithologies have been distinguished: a dunite/harzburgite/lherzolite (D/HZ/L) group, clinopyroxene-rich lherzolites (Cpx-L), clinopyroxene megacrysts (Cpx-M), spinel-rich olivine websterites (OWB₁) and spinel-poor olivine websterites (OWB₂). D/HZ/L xenoliths are the most common and represent normal mantle composed of typical anhydrous spinel peridotites with well equilibrated, unzoned silicates characterized by high Mg# s. Negative correlations between Mg# and TiO₂, Al₂O₃ and CaO wt% in clinopyroxenes (cpx) and orthopyroxenes (opx) and the Cr–Al trend in spinel (sp) suggest depletion via extraction of basaltic melts. The modal composition of D/HZ/L xenoliths and unusual low-Al opx suggest that the lithospheric mantle underneath East Serbia is more depleted than normal European lithosphere. D/HZ/L xenoliths contain numerous pockets and veins filled by Cr-rich cpx, Ti-rich spinel, altered glass, apatite and rare ilmenite and phlogopite. Petrographic observations, supported by major element contents in sp and cpx, and modelling using trace element contents in cpx, indicate that the pockets and veins formed from infiltration of alkaline melts and reaction with peridotite wall-rock causing opx and spinel replacement. The same alkaline melt-related metasomatism gave rise to the Cpx-L and OWB₁ mantle xenoliths and Cpx-M xenocrysts. Trace element contents of cpx in these xenoliths show a distinctively concave downwards REE pattern with a HFSE depletion, very similar to cpx megacrysts from the Pannonian Basin and to vein cpx from Eifel. In contrast, the OWB₂ xenoliths show evidence of precipitation from subduction-related mafic to ultramafic melts, as inferred from their opx-rich lithology and unusual Cr-rich spinels. They are probably related to subduction magmatism during the Late Cretaceous.Milivoje Jovanovi: deceased in April 2004