Validation of high-resolution TRMM-3B43 precipitation product using rain gauge measurements over Kyrgyzstan

This paper presents the validation of monthly precipitation using Tropical Rainfall Measuring Mission Multisatellite Precipitation Analysis (TMPA)—3B43 product with conventional rain gauge observations for the period 1998–2007 over Kyrgyzstan. This study is carried out to quantify the accuracy of TMPA-3B43 product over the high latitude and complex orographic region. The present work is quite important because it is highly desirable to compare the TMPA precipitation product with the ground truth data at a regional scale, so that the satellite product can be fine-tuned at that scale. For the validation, four different types of spatial collocation have been used: station wise, climatic zone wise, topographically and seasonal. The analysis has been done at the same spatial and temporal scales in order to eliminate the sampling biases in the comparisons. The results show that TMPA-3B43 product has statistically significant correlation (r?=?0.36–0.88) with rain gauge data over the most parts of the country. The minimum linear correlation is observed around the large continental water bodies (e.g., Issyk-Kul lake; r?=?0.17–0.19). The overall result suggests that the precipitation estimated using TMPA-3B43 product performs reasonably well over the plain regions and even over the orographic regions except near the big lake regions. Also, the negative bias suggests the systematic underestimation of high precipitation by TMPA-3B43 product. The analyses suggest the need of a better algorithm for precipitation estimation over this region separately to capture the different types of rain events more reliably.     

Comparison of instrumental and GDGT-based estimates of sea surface and air temperatures from the Skagerrak

Sea surface temperatures (SSTs) and annual mean air temperatures (MATs) are estimated for the last 200 years from glycerol dialkyl glycerol tetraethers (GDGTs) proxies in a marine sediment core from the Skagerrak, off southern Norway. The reconstructed values compare well with annual SSTs and summer air temperatures obtained from composite regional instrumental records. The results provide further confidence in the application of proxies based on GDGTs to estimate past temperatures.     

Index test for the degradation potential of carbonate sands during hydraulic transportation

Carbonate sands undergo degradation when transported hydraulically from a dredging vessel to the reclamation site. Risks involved in the production of fines during hydraulic transport are a deterioration of the mechanical properties of the fill in certain areas of the reclamation area where these fines concentrate. In order to assess sand degradation in the concrete and road construction industry, the Micro-Deval test for fine aggregates was developed in France and Canada. During Micro-Deval testing, aggregates degrade when tumbled in a rotating steel drum with water and steel balls. In the Canadian standard, the steel charge is lower than in the French standard and balls have the diameter of the smallest balls used in the French test. During testing, the quantity of fines produced is measured. This makes the Micro-Deval test an option for assessing the degradation of sand during hydraulic transportation of slurries in the dredging industry. Three sands are tested: two shelly carbonate sands and one quartzic river sand for comparison. The carbonate sands were sampled on reclaimed land and had been subjected to hydraulic transportation in pipeline before artificial deposition. Due to differences in particle shape, the carbonate sands and the quartz sand have a different number of contacts with the steel charge in the drum of the Micro-Deval and are not exposed to the same degradation forces during testing. It was found that the quartzic sand suffers relatively much degradation as compared to the carbonate sands, despite its greater hardness and resistance to crushability. The French test appears to create turbulence that promotes floatation of the curved shells of the carbonate sands instead of shell grinding at the bottom of the drum by contact with the steel balls. Microscopic observations of sand samples before and after testing showed that the French Micro-Deval test is too destructive. The test leads to the fragmentation by impact of the quartz sands and the destruction of certain particle types that had survived hydraulic transportation. With respect to the Canadian test, microscopic examination of sand grains before and after testing shows there is still much fragmentation of quartz grains. A lower rotational speed combined with a limited steel charge made of uniform balls of a smaller diameter, reduces turbulence, shell floatability and last but not the least, impact forces. It produces the desired result: a high Micro-Deval loss for the carbonate sands in comparison to that for the quartz sands and a very limited fragmentation of the quartz grains. Once the slurry reaches its destination, the grain size distribution of the fines fraction will influence the mechanical behaviour of mixed sands. A procedure is proposed to measure the particle size distribution of the fines fraction produced during Micro-Deval testing.Field validation is needed to validate preliminary laboratory results.     

Radar observations and a physical model of contact binary Asteroid 4486 Mithra

Arecibo (2380 MHz, 12.6 cm) and Goldstone (8560 MHz, 3.5 cm) delay-Doppler radar images obtained in July and August of 2000 reveal that 4486 Mithra is an irregular, significantly bifurcated object, with a central valley ∼380 m deep and a long axis potentially exceeding 2 km. With its bimodal appearance, Mithra is a strong candidate for a contact binary asteroid. Sequences of Goldstone images spanning up to 3 h per day show very little rotation and establish that Mithra is an unusually slow rotator. We used Goldstone and Arecibo data to estimate Mithra’s 3D shape and spin state. We obtain prograde (λ = 337°, β = 19°) and retrograde (λ = 154°, β = −19°) models that give comparable fits, have very similar shapes roughly resembling an hourglass, and have a rotation period of 67.5 ± 6.0 h. The dimensions of these two models are very similar; for the prograde solution the maximum dimensions are X = 2.35 ± 0.15 km, Y = 1.65 ± 0.10 km, Z = 1.44 ± 0.10 km. Dynamical analysis of our models suggests that in the past, Mithra most likely went through a period of even slower rotation with its obliquity close to 90°. The spin rate is predicted to be increasing due to thermal torque (YORP), while the obliquity, which is currently +68° and +106° for the prograde and retrograde models, respectively, is predicted to move away from 90°.     

Simulation of the interactions between gravity processes and contour currents on the Algarve Margin (South Portugal) using the stratigraphic forward model Sedsim

The margin of the Gulf of Cadiz is swept by an intermediate current the Mediterranean Outflow Water (MOW) flowing from the Mediterranean to the Atlantic. On the northern margin of the Gulf (Algarve Margin, South Portugal) the MOW intensity is low, and fine-grained contourite drifts are built up with an alongslope alignment. Recent sedimentological studies emphasize the presence of complex process interactions resulting in the formation of a unique depositional architecture. Alongslope processes related to contour currents generate contourite drift, while downslope processes form canyons and channels aligned on deep faults. This paper uses a combined oceanographic and geological dataset to simulate the different types of interactions between gravity processes and contour currents, which were evidenced on this margin. An extrapolation of the contour current intensity has been used based on the present day velocity field and sea-level fluctuations over the simulated geological time-scale. According to our model results, the construction of the contourite drift is closely linked to contour current velocities and directions, the types of sediments transported and the existing topography. Using modern sedimentological understanding of the area, we have correlated gravity flow's strongest activity to sea level lowstand periods mainly due to a closer connection between canyon's mouth and river or deltaic systems. The simulated gravity flows are initialized at different locations and times on the margin depending on the preserved lobes retrieved from seismic analysis. Their resulting morphological features are identified as perched-lobes with volumes and forms close to the ones observed on Portimão and Lagos Drifts. This study provides a process-based understanding of the construction of contourite system and a physical evaluation of the interactions between gravity flows perpendicular to the slope, and alongslope processes. In addition, it shows the influence of autocyclic factors in the construction of contourite sedimentation, which is important to consider in future sedimentary paleo-reconstruction interpretations.     

High-resolution analysis of submarine lobes deposits: Seismic-scale outcrops of the Lauzanier area (SE Alps, France)

The Lauzanier area represents the northernmost extension of the Annot Sandstone series and contains deposits between 650 and 900 m-thick. This basin was active from upper Bartonian or lower Priabonian to early Rupelian. It is composed of two superposed units separated by a major unconformity. The sediment supply is due to channelled flows coming from the south. Flow processes include mass flow to turbidity currents. The size of the particles and the absence of fine-grained sediment suggest a transport over a short distance. The Lower Unit is made of coarse-grained tabular beds interpreted as non-channelled lobe deposits. The Upper Unit is made of massive conglomerates interpreted as the channelled part of lobes. These lobe deposits settle in a tectonically confined basin according to topographic compensation that occurs from bed scale to unit scale. The abrupt progradation between the lower and the upper unit seems related to a major tectonic uplift in the area. This uplift is also suggested by a change in the petrographic nature of the source and an abrupt coarsening of the transported clasts.This field example allows providing high resolution analysis for depositional sedimentary sequences of terminal lobe deposits in a coarse-grained turbidite system. The outcrop analysis shows the lateral evolution of deposits and the system progradation allows a longitudinal analysis of facies evolution by superposing on the same outcrops the channelled lobe system and the non-channelled lobe system. These results of high-resolution outcrop analysis can be extrapolated to results obtained on sedimentary lobes in recent deep-sea turbidite system that are either restricted to cores, or with a lesser resolution (seismic).     

Prediction of the thermodynamic properties of metal–chromate aqueous complexes to high temperatures and pressures and implications for the speciation of hexavalent chromium in some natural waters

Log–log correlation plots between the dissociation constants of known metal–chromate complexes and those of corresponding metal–sulfate complexes at 25 °C, 1 bar were used to derive the standard partial molal Gibbs free energies of formation of unknown metal–chromate complexes involving either (i) monovalent cations, divalent cations, and trivalent lanthanides or (ii) trivalent cations (excluding those of rare earth elements, REE) and tetravalent cations. For each of these two classes of ionic associations, empirical relationships between the standard partial molal volumes, isobaric heat capacities and entropies of known metal–chromate complexes and the corresponding thermodynamic properties of metal ions have been found. These data were utilized to evaluate the solute-characteristic parameters of the revised Helgeson–Kirkham–Flowers equation of state and to compute the thermodynamic properties of the dissociation reactions of metal–chromate complexes at high temperatures and pressures.     

A two‐step process for the reflooding of the Mediterranean after the Messinian Salinity Crisis

The Messinian Salinity Crisis is well known to have resulted from a significant drop of the Mediterranean sea level. Considering both onshore and offshore observations, the subsequent reflooding is generally thought to have been very sudden. We present here offshore seismic evidence from the Gulf of Lions and re‐visited onshore data from Italy and Turkey that lead to a new concept of a two‐step reflooding of the Mediterranean Basin after the Messinian Salinity Crisis. The refilling was first moderate and relatively slow accompanied by transgressive ravinement, and later on very rapid, preserving the subaerial Messinian Erosional Surface. The amplitude of these two successive rises of sea level has been estimated at ≤500 m for the first rise and 600–900 m for the second rise. Evaporites from the central Mediterranean basins appear to have been deposited principally at the beginning of the first step of reflooding. After the second step, which preceeded the Zanclean Global Stratotype Section and Point, successive connections with the Paratethyan Dacic Basin, then the Adriatic foredeep, and finally the Euxinian Basin occurred, as a consequence of the continued global rise in sea level. A complex morphology with sills and sub‐basins led to diachronous events such as the so‐called ‘Lago Mare’.This study helps to distinguish events that were synchronous over the entire Mediterranean realm, such as the two‐step reflooding, from those that were more local and diachronous. In addition, the shoreline that marks the transition between these two steps of reflooding in the Provence Basin provides a remarkable palaeogeographical marker for subsidence studies.     

Relating land surface,water table,and weathering fronts with a conceptual valve model for headwater catchments

Knowing little about how porosity and permeability are distributed at depth, we commonly develop models of groundwater by treating the subsurface as a homogeneous black box even though porosity and permeability vary with depth. One reason for this depth variation is that infiltrating meteoric water reacts with minerals to affect porosity in localized zones called reaction fronts. We are beginning to learn to map and model these fronts beneath headwater catchments and show how they are distributed. The subsurface landscapes defined by these fronts lie subparallel to the soil-air interface but with lower relief. They can be situated above, below, or at the water table. These subsurface landscapes of reaction are important because porosity developed from weathering can control subsurface water storage. In addition, porosity often changes at the weathering fronts, and when this affects permeability significantly, the front can act like a valve that re-orients water flowing through the subsurface. We explore controls on the positions of reaction fronts under headwater landscapes by accounting for the timescales of erosion, chemical equilibration, and solute transport. One strong control on the landscape of subsurface reaction is the land surface geometry, which is in turn a function of the erosion rate. In addition, the reaction fronts, like the water table, are strongly affected by the lithology and water infiltration rate. We hypothesize that relationships among the land surface, reaction fronts, and the water table are controlled by feedbacks that can push landscapes towards an ‘ideal hill’. In this steady state, reaction-front valves partition water volumes into shallow and deep flowpaths. These flows dissolve low- and high-solubility minerals, respectively, allowing their reaction fronts to advance at the erosion rate. This conceptualization could inform better models of subsurface porosity and permeability, replacing the black box.     

The distribution and utility of sea‐level indicators in Eurasian sub‐Arctic salt marshes (White Sea,Russia)

In support of efforts to reconstruct relative sea level (RSL), we investigated the utility of foraminifera, diatoms and bulk‐sediment geochemistry (δ¹³C, C:N and parameters measured by Rock‐Eval pyrolysis) as sea‐level indicators in Eurasian sub‐Arctic salt marshes. At three salt marshes (<15 km apart) in Dvina Bay (White Sea, Russia), we collected surface sediment samples along transects from subtidal to Taiga forest environments. Foraminifera at all sites formed bipartite assemblages, where elevations below mean high higher water (MHHW) were dominated by Miliammina spp. and elevations between MHHW and the highest occurrence of foraminifera were dominated by Jadammina macrescens and Balticammina pseudomacrescens. Five high‐diversity groups of diatoms were identified and they displayed pronounced variability amongst the study sites. Bulk‐sediment geochemistry recognized two groups (clastic‐dominated environments below MHHW and organic‐rich environments above MHHW). As one group included subtidal elevations and the other included supratidal elevations, we conclude that the measured geochemical parameters are not stand‐alone sea‐level indicators. Core JT2012 captured a regressive sediment succession of clastic, tidal‐flat sediment overlain by salt‐marsh organic silt and freshwater peat. The salt‐marsh sediment accumulated at 2804±52 years before present and preserved foraminifera (Jadammina macrescens and Balticammina pseudomacrescens) with good analogy to modern assemblages indicating that RSL was +2.60±0.47 m at this time. Diatoms confirm that marine influence decreased through time, but the lack of analogy between modern and core assemblages limited their utility as sea‐level indicators. Geochemical parameters also indicate a reduction in marine influence through time. We conclude that RSL reconstructions derived from salt‐marsh sediment preserved beneath Eurasian sub‐Arctic peatlands can provide valuable insight into the spatio‐temporal evolution of the Fennoscandian and Eurasian ice sheets.