The growth of “black crusts” on calcareous building stones in Palermo (Sicily): a first appraisal of anthropogenic and natural sulphur sources

Chemical, mineralogical and isotopic composition (³⁴S/³²S) analyses were carried out on “black crusts” developed on the old buildings of Palermo (Sicily) with the aim to distinguish between natural and anthropogenic sulphur sources. Furthermore individual samples of total suspended particulate (TSP) were collected and analysed in order to estimate the influence of air pollution on the decay process of calcareous stones in a typical southern Mediterranean coastal environment. SEM/EDS analysis, X-ray diffractometry, IR spectroscopy and liquid chromatography led to the compositional characterization of “black crusts” and airborne particulate matter in the city. Sulphur isotopic compositions of gypsum-bearing crusts showed a prevailing contribution of anthropogenic sources (vehicle exhaust and other combustion processes). Natural sulphur and/or sulphate sources (biogenic and/or sea-spray) were shown to play a secondary role. These data can be considered a starting point for the determination of the rate of growth of “black crusts” in a coastal Mediterranean urban environment like Palermo. In the future, they might be useful to local authorities for planning more efficient maintenance action in order to slow as much as possible the rate of decay of the monumental heritage of the city.     

On the tectonics of the Neocomian Rio do Peixe Rift Basin, NE Brazil: Lessons from gravity, magnetics, and radiometric data

A geophysical perspective based on well-acquired gravity, magnetic, and radiometric data provides good insights into the basin architectural elements and tectonic evolution of the Rio do Peixe Basin (RPB), an Early Cretaceous intracontinental basin in the northeast Brazilian rift system, which developed during the opening of the South Atlantic. NW–SE-trending extensional forces acting over an intensively deformed Precambrian basement yielded a composite basin architecture strongly controlled by preexisting, mechanically weak fault zones in the upper crust. Reactivated NE–SW and E–W ductile shear zones of Brasiliano age (0.6 Ga) divided the RPB into three asymmetrical half-grabens (Brejo das Freiras, Sousa, and Pombal subbasins), separated by basement highs of granite bodies that seem to anchor and distinguish the mechanical subsidence of the subbasins. Radiometric and geopotential field data highlight the relationship between the tectonic stress field and the role of a preexisting structural framework inserted in the final rift geometry. The up-to-2000 m thick half-grabens are sequentially located at the inflexion of sigmoidal-shaped shear zones and acquire a typical NE–SW-oriented elliptic shape. The Sousa Subbasin is the single exception. Because of its uncommon E–W elongated form, three-dimensional gravity modeling reveals an E–W axis of depocenters within the Sousa Subbasin framework, in which the eastern shoulders are controlled by NE–SW-trending faults. These faults belong to the Precambrian structural fabric, as is well illustrated by the gamma ray and magnetic signatures of the basement grain. Release faults were identified nearly perpendicular or oblique to master faults, forming marginal strike ramps and horst structures in all subbasins. The emplacement mechanism of Brasiliano granites around the RPB was partially oriented by the same structural framework, as is indicated by the gravity signature of the granitic bodies after removal of the gravity effect of the basin-filling deposits. The RPB major-fault occurrence along the releasing bend of a strong discontinuity – the so-called Portalegre Shear Zone – in addition to the configuration of a gentle crustal thinning, according to gravity field studies, suggests that a crustal discontinuity governs the nucleation of the RPB, followed probably by small displacement in deep crustal levels accommodating low-rate stretching during basin subsidence.     

High T/P evolution and metamorphic ages of the migmatitic basement of northern Sierras Pampeanas,Argentina: Characterization of a mid-crustal segment of the Famatinian belt

New petrologic, thermobarometric and U-Pb monazite geochronologic information allowed to resolve the metamorphic evolution of a high temperature mid-crustal segment of an ancient subduction-related orogen. The El Portezuelo Metamorphic-Igneous Complex, in the northern Sierras Pampeanas, is mainly composed of migmatites that evolved from amphibolite to granulite metamorphic facies, reaching thermal peak conditions of 670–820 °C and 4.5–5.3 kbar. The petrographic study combined with conventional and pseudosection thermobarometry led to deducing a short prograde metamorphic evolution within migmatite blocks. The garnet-absent migmatites represent amphibolite-facies rocks, whereas the cordierite-garnet-K-feldspar-sillimanite migmatites represent higher metamorphic grade rocks. U-Pb geochronology on monazite grains within leucosome record the time of migmatization between ≈477 and 470 Ma. Thus, the El Portezuelo Metamorphic-Igneous Complex is an example of exhumed Early Ordovician anatectic middle crust of the Famatinian mobile belt. Homogeneous exposure of similar paleo-depths throughout the Famatinian back-arc and isobaric cooling paths suggest slow exhumation and consequent longstanding crustal residence at high temperatures. High thermal gradients uniformly distributed in the Famatinian back-arc can be explained by shallow convection of a low-viscosity asthenosphere promoted by subducting-slab dehydration.     

Sandy beach ecosystems: key features, sampling issues, management challenges and climate change impacts

Escalating pressures caused by the combined effects of population growth, demographic shifts, economic development and global climate change pose unprecedented threats to sandy beach ecosystems worldwide. Conservation of beaches as functional ecosystems and protection of their unique biodiversity requires management interventions that not only mitigate threats to physical properties of sandy shores, but also include ecological dimensions. Yet, beach management remains overwhelmingly focused on engineering interventions. Here we summarise the key outcomes of several workshops, held during the 2006 Sandy Beach Ecology Symposium in Vigo, Spain, that addressed issues of climate change, beach management and sampling methodology. Because efficient communication between managers and ecologists is critical, we summarise the salient features of sandy beaches as functional ecosystems in 50 'key statements'; these provide a succinct synopsis of the main structural and functional characteristics of these highly dynamic systems. Key outcomes of the workshops include a set of recommendations on designs and methods for sampling the benthic infaunal communities of beaches, the identification of the main ecological effects caused by direct and indirect human interventions, the predicted consequence of climate change for beach ecosystems, and priority areas for future research.     

Effects of morphodynamic state on macrofauna community of exposed sandy beaches on Galician coast (NW Spain)

It is known that the fauna of the exposed sandy beaches are primarily controlled by physical variables; but how these variables operate along and across the beach still remains fairly under discussion. In our study, we sampled a range of exposed sandy beaches along the Northwest coast of Spain to determine the relationship between the principal physical variables of the beaches (including beach morphodynamic state), and the macrofaunal community. The fauna of these beaches comprise truly marine species along the intertidal zone as well as semi-terrestrial species in the upper and supratidal environments. These two groups respond in a different manner to the physical environment. The first group is directly controlled by the morphodynamic state of the beach, and variations in the physical environment; the second group is not clearly affected by these physical conditions. In this case, other variables such as food availability and the human uses of the upper limits of the beach seem to be more relevant in explaining the patterns observed in the macrofaunal community.     

Ecological niches and areas of overlap of the squat lobster ‘munida’ (Pleuroncodes monodon) and anchoveta (Engraulis ringens) off Peru

The world’s largest mono-specific fishery, the Peruvian anchovy or anchoveta (Engraulis ringens) fishery, has been the subject of many studies since the 1960s. Details of its relationship with other species have mainly focused on alternations with sardine, Sardinops sagax, and little effort has so far been paid to interactions with other species sharing the same ecosystem. This is the case for Pleuroncodes monodon, the crustacean squat lobster or ’munida’, which has become highly abundant along the Peruvian coast since the mid-1990s. Munida is now an important prey for seabirds, mammals and coastal predatory fish. Knowledge of patterns of distribution and ecological niche of munida is scarce however off Peru. Here we describe and compare spatial patterns of distribution of anchoveta and munida and their ecological niches based on data from 26 acoustic surveys performed along the Peruvian coast between 1998 and 2006. The results indicate that munida and anchoveta share ecological niches but that munida is restricted to the coldest part of the productive cold coastal waters whereas anchoveta do not present any temperature preference over a large range (14–23 °C). The recent increase in munida abundance off Peru is concomitant with colder conditions; with their onset munida extended its range from central Chile northwards. Off Peru the very shallow oxycline keeps munida from its usual bottom habitat and has forced it to adopt pelagic behaviour.     

Genetic heterogeneity in populations of the Mediterranean shore crab, Carcinus aestuarii (Decapoda,Portunidae), from the Venice Lagoon

Heterogeneity in genetic composition among recruits, mostly due to a large variance in reproductive success mediated by oceanographic processes, has been reported for marine species but is less understood in coastal lagoons' organisms. Temporal genetic variation in natural populations of the Mediterranean shore crab Carcinus aestuarii was quantified over a multi-year sample. A total of 486 adult crabs were collected at eight different sites of the Venice Lagoon during the period 2005–2007 and screened for genetic variation using 11 microsatellite loci. Two additional samples (N = 115) from neighbouring sites, located approximately 100 km North and South to the Venice Lagoon, were included for the sake of comparison. Our results show significant differences in allelic frequencies at the micro-geographic scale of the Venice Lagoon, observed between sites of collection, typologies of habitat, and areas with different class of ecological risk or pattern of hemocyanin expression. However, this pattern was not constant between years, with significant differences observed mainly in 2005 and 2006, but not in 2007. Our results indicate significant temporal differences suggesting the existence of dynamic processes that act on the genetic pool of this species. Although natural selection and gene flow might play a role, we suggest that genetic drift linked to large variation in the reproductive success of individuals is the most probable scenario to explain the local genetic patterns of differentiation in the Mediterranean shore crab. Our study, by providing the first evidence for the existence of genetic differences in this species at the micro-geographic scale, suggests that a better comprehension of the link between reproduction, recruitment and oceanography is critical to understand how colonization and maintenance of genetic variation is achieved in ephemeral and vulnerable environments such as coastal lagoons.     

The effects of post-orogenic extension on different scales: an example from the Apennine–Maghrebide fold-and-thrust belt, SW Sicily

ABSTRACT Many structures produced under one single deformation regime, namely extensional, contractional or strike-slip, exhibit remarkable geometrical analogies when analysed at different scales. By contrast, field examples that illustrate the scale effects on structures resulting from superimposed deformations, which were produced under different tectonic regimes, are rare. Yet the change from contraction to extension is known to occur often in the most thickened portions of the continental crust. The Apennine–Maghrebide fold-and-thrust belt of Sicily shows many examples of post-orogenic extensional deformations. Composite structures, resulting from late normal faults that offset folds and thrusts, are observed at four different scales, from regional to mesoscopic, in the south-western portion of Sicily and in the adjacent Isle of Favignana. The recognized analogies in the geometry of these composite structures may provide a key for the interpretation of the features of regional structures, whose deep geometry is often poorly constrained. Moreover, comparison of normalized displacements accommodated by contractional and extensional faults of different scales indicates that self-similarity is not unique to structures produced under single tectonic regimes.     

Fault‐controlled dolomite bodies as palaeotectonic indicators and geofluid reservoirs: New insights from Gargano Promontory outcrops

The Upper Jurassic to Lower Cretaceous platform‐slope to basinal carbonate strata cropping out in Gargano Promontory (southern Italy) are partly dolomitized. Fieldwork and laboratory analyses (petrographic, petrophysical and geochemical) allowed the characterization of the dolomite bodies with respect to their distribution within the carbonate succession, their dimensions, geometries, textural variability, chemical stability, age, porosity, genetic mechanisms and relation with tectonics. The dolomite bodies range from metres to kilometres in size, are fault‐related and fracture‐related, and probably formed during the Early Cretaceous at <500 m burial depths and temperatures <50°C. The proposed dolomitization model relies on mobilization of Early Cretaceous seawater that flowed, downward and then upward, along faults and fractures and was modified in its isotopic composition moving through Triassic and Jurassic strata that underlie the studied dolomitized succession. Despite the numerous cases reported in literature, this study demonstrates that hydrothermal and/or high‐temperature fluids are not necessarily required for fault‐controlled dolomitization. Distribution and geometries of dolomite bodies can be used for palaeotectonic reconstructions, as they partly record the characteristics (size, attitude and kinematics) of the palaeo‐faults, even if not preserved, that controlled dolomitization. In Gargano Promontory, dolomites record Early Cretaceous palaeo‐faults from metres to kilometres long, striking north‐west/south‐east to east/west and characterized by normal to strike‐slip kinematics. Dolomitization increases the matrix porosity by up to 7% and, therefore, can improve the geofluid storage capacity of tight, platform‐slope to basinal limestones. The results have a great significance for characterization of geofluid (for example, hydrocarbons) reservoirs hosted in similar dolomitized carbonate successions. Distribution, size and shapes of reservoir rocks (i.e. dolomite bodies) could be broadly predictable if the characteristics of the palaeo‐fault system present at the time of dolomitization are known.