Origin of atoll garnet in schists from the Alpuj��rride Complex (Central zone of the Betic Cordillera, Spain): Implications on the P-T evolution

Atoll-shaped and normal garnets from schists of the Betic Cordillera (Spain) were studied by electron microprobe, scanning electron microscopy and microstructural electron backscattered scanning diffraction (EBSD). Medium-grade schists contain a textural variety of atoll garnets, characterized by the presence of muscovite, annite, and quartz as main ??core?? phases. Zoning patterns, EBSD analyses and themobarometric data indicate that the micaceous intergrowths formed in most cases through breakdown of a first garnet generation, with orientation of micas being controlled by garnet (c*_mica//[111]*_Grt and c*_mica//[110]*_Grt as main crystallographic relationships). Rings formed from multiple nucleation and coalescence, with orientation being controlled, in some cases, by the relics of the initial garnet and more generally by mica orientation. P-T estimates indicate that the first stage of garnet growth occurred at relatively high P (9?C12?kbar/500?C550°C) whereas the second metamorphic stage occurred at lower P and slightly higher T conditions (5?C7?kbar/500?C600°C).     

Activity maps of multi-source mudslides from the Daunia Apennines (Apulia,southern Italy)

Natural Hazards - Flooding poses a serious public health hazard throughout the world. Flood modeling is an important tool for emergency preparedness and response, but some common methods require a...     

Soil stabilization with microbially induced desaturation and precipitation (MIDP) by denitrification: a field study

Acta Geotechnica - A field trial was performed to test the feasibility of microbially induced desaturation and precipitation (MIDP) by denitrification for the stabilization of a silty soil....     

Timing of the HT/LP transpression in the Neoproterozoic Seridó Belt (Borborema Province,Brazil): Constraints from UPb (SHRIMP) geochronology and implications for the connections between NE Brazil and West Africa

The Seridó schist belt is a classical domain of the Borborema Province (NE Brazil) recording crustal melting at HT/LP conditions in a tectonic setting dominated by dextral transpressive deformation. A comparable tectonometamorphic setting has been described in the Pan-African Igarra and Ilesha schist belts of south Nigeria (Africa). The HT‐transpression of the Seridó has previously been imprecisely dated by using a range of isotopic methods on a suite of syntectonic granites. We provide new UPb zircon ages of the Acari granite and Santa Luzia migmatite that constrain the HT/LP metamorphism of the Seridó at c. 575 Ma. Anisotropy of magnetic susceptibility of the Santa Luzia migmatite shows that the magnetic fabric records the NE-trending dextral kinematics similar to those previously described in the Acari pluton. On the other hand, the UPb ages of the Totoró pluton provide evidence for an older, mostly mafic to intermediate magmatism intruding the pelitic schist that precedes the HT/LP metamorphism by approximately 15 m.y. In contrast with the Acari pluton and Santa Luzia migmatite, the magnetic fabrics of Totoró show a concentric steep-dipping structure apparently related to magma ascent. Thermobarometric studies in the Seridó, Igarra and Ilesha schist belts indicate that a large domain in the northern Borborema and south of the Nigeria shields was deformed at a high temperature and at relatively shallow depths. Although the tectonic setting for such a post-collision HT event remains an open issue, it allows us nevertheless to refine the across-Atlantic geological correlation between the continents.     

Timing the time of concentration: shedding light on a paradox

From the origins of hydrology, the time of concentration, t_c, has conventionally been tackled as a constant quantity. However, theoretical proof and empirical evidence imply that t_c exhibits significant variability against rainfall, making its definition and estimation a hydrological paradox. Adopting the assumptions of the Rational method and the kinematic approach, an effective procedure in a GIS environment for estimating the travel time across a catchment’s longest flow path is provided. By application in 30 Mediterranean basins, it is illustrated that t_c is a negative power function of excess rainfall intensity. Regional formulas are established to infer its multiplier (unit time of concentration) and exponent from abstract geomorphological information, which are validated against observed data and theoretical literature outcomes. Besides offering a fast and easy solution to the paradox, we highlight the necessity of implementing the varying t_c concept within hydrological modelling, signalling a major shift from current engineering practices.     

Monte Carlo method applied to modeling copper transport in river sediments

Monte Carlo simulation (MCS) methodology has been applied to explain the variability of parameters for pollutant transport and fate modeling. In this study, the MCS method was used to evaluate the transport and fate of copper in the sediment of the Tibagi River sub-basin tributaries, Southern Brazil. The statistical distribution of the variables was described by a dataset obtained for copper concentration using sequential extraction, organic matter (OM) amount, and pH. The proposed stochastic spatial model for the copper transport in the river sediment was discussed and implemented by the MCS technique using the MatLab 7.3? mathematical software tool. In order to test some hypotheses, the sediment and the water column in the river ecosystem were considered as compartments. The proposed stochastic spatial model makes it possible to predict copper mobility and associated risks as a function of the organic matter input into aquatic systems. The metal mobility can increase with the OM posing a rising environmental risk.     

Pre-Observational Evolution of Surface Temperature in Romania as Inferred from Borehole Temperature Measurements

Temperature data from nine boreholes in the Carpathian orogen in Romania were used to obtain information on the ground surface temperature history (GSTH) in the last 250?years. The temperature measurements were taken with a thermistor probe (sensitivity in the 10 mK range) using the stop-and-go technique, at 10 m intervals, in the depth range of 20–580?m. The least squares inverse modelling approach of Tarantola and Valette (J Geophys 50:159–170, 1982) was used to infer the GSTH. Long-term air temperature records available from the Romanian weather station network were used as a comparison term for the first 100–150?years of the GSTH, and as a forcing function in a POM-SAT model that combines borehole temperature profiles (BTPs) and meteorological time series (surface air temperature, SAT) to produce information on the so-called pre-observational mean (POM). Results from a global circulation model for the Romanian area are incorporated in the discussion as well.     

Zero-stress,cylindrical wave functions around a circular underground tunnel in a flat,elastic half-space: Incident P-waves

The zero-stress boundary conditions at the surface of the half-space in the presence of surface and sub-surface cavities for in-plane, incident cylindrical P- and SV-waves have always posed challenging problems. The outgoing cylindrical P- and SV-waves can be represented by Hankel functions of radial distance coupled with the sine and cosine functions of angle. Together, at the half-space surface the P- and SV-wave functions are not orthogonal over the semi-infinite radial distance from 0 to infinity. Thus, to simultaneously satisfy the zero in-plane, normal, and shear stresses, an approximation of the geometry is often made. This paper presents an analytical formulation of the boundary-valued problem, where the Hankel wave functions are expressed in integral form, changing the representation from cylindrical to rectangular coordinates, so that the zero-stress boundary conditions at the half-space surface can be applied in a more straightforward way.     

Overview of Natural Source Zone Depletion: Processes,Controlling Factors,and Composition Change

Natural source zone depletion (NSZD) has emerged as a practical alternative for restoration of light non‐aqueous phase liquid (LNAPL) sites that are in the later stages of their remediation lifecycle. Due to significant research, the NSZD conceptual model has evolved dramatically in recent years, and methanogenesis is now accepted as a dominant attenuation process (e.g., Lundegard and Johnson 2006 ; Ng et al. 2015 ). Most of the methane is generated within the pore space adjacent to LNAPL (Ng et al. 2015 ) from where it migrates through the unsaturated zone (e.g., Amos and Mayer 2006 ), where it is oxidized. While great progress has been made, there are still some important gaps in our understanding of NSZD. NSZD measurements provide little insight on which constituents are actually degrading; it is unclear which rate‐limiting factors that can be manipulated to increase NSZD rates; and how longevity of the bulk LNAPL and its key constituents can be predicted. Various threads of literature were pursued to shed light on some of the questions listed above. Several processes that may influence NSZD or its measurement were identified: temperature, inhibition from acetate buildup, protozoa predation, presence of electron acceptors, inhibition from volatile hydrocarbons, alkalinity/pH, and the availability of nutrients can all affect methanogenesis rates, while factors such as moisture content and soil type can influence its measurement. The methanogenic process appears to have a sequenced utilization of the constituents or chemical classes present in the LNAPL due to varying thermodynamic feasibility, biodegradability, and effects of inhibition, but the bulk NSZD rate appears to remain quasi‐zero order. A simplified version of the reactive transport model presented by Ng et al. 2015 has the potential to be a useful tool for predicting the longevity of key LNAPL constituents or chemical fractions, and of bulk LNAPL, but more work is needed to obtain key input parameters such as chemical classes and their biodegradation rates and any potential inhibitions.     

River temperature forecasting: case study for Little Southwest Miramichi River (New Brunswick,Canada)

River temperature models play an increasingly important role in the management of fisheries and aquatic resources. Among river temperature models, forecasting models remain relatively unused compared to water temperature simulation models. However, water temperature forecasting is extremely important for in-season management of fisheries, especially when short-term forecasts (a few days) are required. In this study, forecast and simulation models were applied to the Little Southwest Miramichi River (New Brunswick, Canada), where water temperatures can regularly exceed 25–29°C during summer, necessitating associated fisheries closures. Second- and third-order autoregressive models (AR2, AR3) were calibrated and validated using air temperature as the exogenous variable to predict minimum, mean and maximum daily water temperatures. These models were then used to predict river temperatures in forecast mode (1-, 2- and 3-day forecasts using real-time data) and in simulation mode (using only air temperature as input). The results showed that the models performed better when used to forecast rather than simulate water temperatures. The AR3 model slightly outperformed the AR2 in the forecasting mode, with root mean square errors (RMSE) generally between 0.87°C and 1.58°C. However, in the simulation mode, the AR2 slightly outperformed the AR3 model (1.25°C < RMSE < 1.90°C). One-day forecast models performed the best (RMSE ~ 1°C) and model performance decreased as time lag increased (RMSE close to 1.5°C after 3 days). The study showed that marked improvement in the modelling can be accomplished using forecasting models compared to water temperature simulations, especially for short-term forecasts.

EDITOR M.C. Acreman ASSOCIATE EDITOR S. Huang