Elliptical structure of the lunar South Pole-Aitken basin

The South Pole-Aitken basin (SP-A) is the largest and oldest basin on the Moon. The basin has usually been interpreted to exhibit a degraded circular structure, but here we demonstrate that the topography, iron and thorium signatures of the basin are well described by ellipses with axes measuring 2400 by 2050 km and centered at −53°, 191°E. Topography, abundances of iron, thorium, and the distribution of mare basalts are all elevated in the northern halves of the ellipses. We also identify an outer topographic ellipse whose semiminor axis scales with the main topographic ellipse by approximately . Taken together, these data imply that the basin was created by an oblique impact along an azimuth of approximately 19°, measured counterclockwise from longitude 191°E. The geometry of the elevated central farside topography surrounding SP-A suggests that it predates the impact. The elliptical ring structures of SP-A and their scaling relationships will help to understand the formation of large and elliptical basins elsewhere in the Solar System. This refined basin shape will also inform local geology, geochemistry, and geophysics of the region.     

The role of massive AGB stars in the early solar system composition

Abstract— We demonstrate that a massive asymptotic giant branch (AGB) star is a good candidate as the main source of short‐lived radionuclides in the early solar system. Recent identification of massive (4–8 M⊙) AGB stars in the galaxy, which are both lithium‐ and rubidium‐rich, demonstrates that these stars experience proton captures at the base of the convective envelope (hot bottom burning), together with high‐neutron density nucleosynthesis with ²²Ne as a neutron source in the He shell and efficient dredge‐up of the processed material. A model of a 6.5 M⊙ star of solar metallicity can simultaneously match the abundances of ²⁶Al, ⁴¹Ca, ⁶⁰Fe, and ¹⁰⁷Pd inferred to have been present in the solar nebula by using a dilution factor of 1 part of AGB material per 300 parts of original solar nebula material, and taking into account a time interval between injection of the short‐lived nuclides and consolidation of the first meteorites equal to 0.53 Myr. Such a polluting source does not overproduce ⁵³Mn, as supernova models do, and only marginally affects isotopic ratios of stable elements. It is usually argued that it is unlikely that the short‐lived radionuclides in the early solar system came from an AGB star because these stars are rarely found in star forming regions, however, we think that further interdisciplinary studies are needed to address the fundamental problem of the birth of our solar system.     

A Comparison Between Modelled and Measured Mixing-Layer Height Over Munich

An attempt is made to correlate the mixing heights, derived from ceilometer and Sodar measurements, to those simulated by different atmospheric boundary-layer parameterization schemes. The comparison is performed at two sites (one suburban and one rural) close to Munich, Germany for two spring and two winter days. It is found that, under convective conditions, the mixing height determined, by both Sodar and ceilometer, corresponds to the middle or the top of the entrainment zone, respectively, as calculated from the eddy-viscosity profiles. Under stable conditions, the measured mixing height is related to the height where eddy viscosities attain their minimum values (Sodar) or to the height of residual mechanical turbulence (ceilometer). During a foehn case with weak turbulence, the measured mixing height from both Sodar and ceilometer is better inferred by considering the eddy-viscosity profiles during daytime and the height of the low-level jet during nighttime.     

Exploring earth system governance: A case study of floodplain management along the Tisza river in Hungary

This paper discusses a recently proposed conceptualisation of ‘earth system governance’ by applying it to floodplain management in the Hungarian Tisza river basin. By doing so it aims to improve our understanding of governance systems facilitating adaptation to a changing world. The conceptualisation of earth system governance consists of three elements: problem structure, principles and research challenges. These three elements are assessed using results from actor interviews and policy review. A regional example of natural resources management is found to be a valid case for earth system governance research. The proposed conceptualisation of earth system governance explains well the main problems, barriers and opportunities for adapting floodplain management to climate change in the Tisza region. Problem structure analysis highlights how previous socio-economic and political orders continue to shape expectations and patterns of conduct. Current barriers can be attributed to a lack of the key governance principles credibility, stability, inclusiveness and adaptiveness. Interviewees perceived the lack of credibility and effective cooperation between organisations as the largest barrier. The research challenges proposed for earth system governance agree well with opportunities identified for adapting Tisza floodplain management, calling for inclusion of actors beyond governments and state agencies, and equitable resource allocation in particular. The analysis suggests that an additional challenge for earth system governance is the prioritisation of actions to support an existing governance system and its actors in adapting.     

Characterization of particulate matter in the Apulia Region (South of Italy): features and critical episodes

The chemical composition of PM₁₀ and PM_2.5 samples collected during two seasonal monitoring campaigns at residential, urban and industrial Apulia Region- sites was investigated. Ionic fraction, carbonaceous compounds and Polycyclic Aromatic Hydrocarbons were determined for all samples. High correlations among PM data collected in the investigated sites suggested the regional character of particulate matter. It was also confirmed by five days back trajectories analysis. Moreover, no significant seasonal trend in PM mass concentration was observed in the investigated sites. These results, relevant for the area under investigations, were not observed in the North of Italy and Europe and allow to conclude that PM₁₀ and PM_2.5 cannot be considered ‘good’ indicators for the evaluation of local anthropic contributions to air quality. On the contrary, the high levels of Polycyclic Aromatic Hydrocarbons found in Taranto sampling sites suggested that PAHs can be a better indicator for this purpose. This result is also relevant in order to weigh the importance of industrial area and to suggest right policy control to decision makers.     

Stability analysis of historic underground quarries

This work, carried out at the Department of Civil, Environmental and Territory Engineering and Architecture (DICATeA) of the University of Parma, analyzes the stability conditions of the ancient underground quarries of Viggiù (Varese, Italy). The objective of the study is to verify the actual structural predisposition to instability phenomena of the old Viggiù quarries, within the context of a historical and cultural valorization and recovery of the ancient ornamental stone quarries. These quarries, that are now completely abandoned, could be used as a tourist attraction and/or as a teaching environment. They are a wonderful example of industrial architecture by presenting an audacious composition of filled in trenches and room and pillar techniques. An experimental campaign based on in situ measurements and laboratory measurements has been carried out to characterize the rock mass and to determine rock mass mechanical features. A numerical model of the entire rock mass has been developed in order to analyze the stability of the entire underground openings. A preliminary monitoring phase has been realized, aimed at controlling abandoned rock structure movements at the most significant discontinuities. Some measurements of the vertical stress in the pillars and in the walls have been performed, as well, and used for the model calibration. Once the model has been calibrated, the analysis of the actual stress and deformation conditions has been evaluated, the stability condition of the entire structure computed and a forecasting analysis of any intervention that could be realized to guarantee the underground public access has been performed.     

Crystal chemistry, surface morphology and X-ray photoelectron spectroscopy of Fe-rich osumilite from Mt. Arci, Sardinia (Italy)

Microprobe analysis, single crystal X-ray diffraction, X-ray photoelectron spectroscopy, atomic force microscopy, and X-ray absorption spectroscopy were applied on Fe-rich osumilite from the volcanic massif of Mt. Arci, Sardinia, Italy. Osumilite belongs to the space group P6/mcc with unit cell parameters a = 10.1550(6), c = 14.306(1) Å and chemical formula (K_0.729)_C (Na_0.029)_B (Si_10.498 Al_1.502)_T1 (Al_2.706 Fe _0.294 ²⁺ )_T2 (Mg_0.735 Mn_0.091 Fe _1.184 ²⁺ )_AO₃₀. Structure refinement converged at R = 0.0201. Unit cell parameter a is related to octahedral edge length as well as to Fe²⁺ content, unlike the c parameter which does not seem to be affected by chemical composition. The determination of the amount of each element on the mineral surface, obtained through X-ray photoelectron spectroscopy high-resolution spectra in the region of the Si_2p, Al_2p, Mg_1s and Fe_2p core levels, suggests that Fe presents Fe²⁺ oxidation state and octahedral coordination. Two peaks at 103.1 and 100.6 eV can be related to Si⁴⁺ and Si¹⁺ components, respectively, both in tetrahedral coordination. The binding energy of Al_2p, at 74.5 eV, indicates that Al is mostly present in the distorted T2 site, whereas the Mg peak at 1,305.2 eV suggests that this cation is located at the octahedral site. X-ray absorption at the Fe L_2,3-edges confirms that iron is present in the mineral structure, prevalently in the divalent state and at the A octahedral site.     

Spatial Variations in Particle Size and Magnetite Concentration on Cedar Beach: Implications for Grain-Sorting Processes, Western Lake Erie, Canada

<正>This study examined spatial variations in the concentration,grain size and heavy mineral assemblages on Cedar Beach(Lake Erie,Canada).Magnetic studies of heavy mineral-enriched,dark-reddish sands present on the beach showed that magnetite(～150μm) is the dominant magnetic mineral.Surficial magnetic susceptibility values defined three zones:a lakeward region close to the water line(Zone 1),the upper swash zone(Zone 2) and the region landwards of the upper swash zone (Zone 3).Zone 2 showed the highest bulk and mass susceptibility(κ,χ) and the highest mass percentage of smaller grain-size(250μm) fractions in the bulk sand sample.Susceptibility(i.e.κandχ) values decreased and grain size coarsened from Zone 2 lakewards(into Zone 1) and landwards (into Zone 3),and correlated with the distribution of the heavy mineral assemblage,most probably reflecting preferential separation of large,less dense particles by waves and currents both along and across the beach.The eroded western section of Cedar Beach showed much higher concentrations of heavy minerals including magnetite,and finer sand grain sizes than the accreting eastern section, suggesting that magnetic techniques could be used as a rapid,cost-effective way of examining erosion along sensitive coastline areas.     

Intrinsic and specific vulnerability of groundwater in central Spain: the risk of nitrate pollution

The intrinsic vulnerability of groundwater in the Comunidad de Madrid (central Spain) was evaluated using the DRASTIC and GOD indexes. Groundwater vulnerability to nitrate pollution was also assessed using the composite DRASTIC (CD) and nitrate vulnerability (NV) indexes. The utility of these methods was tested by analyzing the spatial distribution of nitrate concentrations in the different aquifers located in the study area: the Tertiary Detrital Aquifer, the Moor Limestone Aquifer, the Cretaceous Limestone Aquifer and the Quaternary Aquifer. Vulnerability maps based on these four indexes showed very similar results, identifying the Quaternary Aquifer and the lower sub-unit of the Moor Limestone Aquifer as deposits subjected to a high risk of nitrate pollution due to intensive agriculture. As far as the spatial distribution of groundwater nitrate concentrations is concerned, the NV index showed the greatest statistical significance (p?<?0.01). This new type of multiplicative model offers greater accuracy in estimations of specific vulnerability with respect to the real impact of each type of land use. The results of this study provide a basis on which to guide the designation of nitrate vulnerable zones in the Comunidad de Madrid, in line with European Union Directive 91/676/EEC.