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221.
In ophiolite complexes and Ural/Alaskan-type intrusions the platinum-group element minerals (PGM) occur as laurite (RuS2), erlichmanite (OsS2), irarsite (IrAsS) and alloys (Os-Ir-Ru and Pt-Fe). They are commonly found as small inclusions (normally less than 10 μm, occasionally up to 100 μm) in chromite. The origin of coarse-grained PGM, in the form of 0.5-10 mm nuggets, in placer deposits related with mafic/ultramafic complexes remains still unclear. Literature data on grain size (r) of platinum-group minerals (PGM) and their formation temperature (range of temperatures between 700 and 1100 °C), revealed an Arrhenius temperature dependence. Correlation of the rate of crystal formation that depends on temperature (T) with the size (r) of the grain results in a linear relationship between ln(r) and 1/T. From the slope of the line n × ln(r) = −const. + Eact/RT the activation energy for the formation of IPGM (Ir-platinum-group minerals) was estimated, for the first time in the present study, to be approximately 450 ± 45 kJ mol−1. Applying the Arrhenius equation, the corresponding formation temperature for extremely large IPGM grains (up to 1.3 mm) in chromite ores related to ophiolites was found to be approximately 740 °C. It seems to be consistent with a lower formation temperature than with the typical formation temperature of small PGM grains associated with ophiolitic chromitites. This suggests that coarse-grained PGM in mafic/ultramafic complexes, along the permeable shear zones, may have been re-crystallized during plastic deformation at relatively lower temperatures (700-800 °C), under appropriate pressure, temperature, redox conditions and an increased H2O content. Thus, applying the plot of ln(r) versus 1/T on large Os-Ir-Ru-minerals (sulfides or alloys), characterized by an r value falling into the linear part of the graph and having evidence supporting their formation at relatively high temperatures, then the corresponding formation temperature of those IPGM can be found. 相似文献
222.
Vito Coppola Maria Boni H. Albert Gilg Bozena Strzelska-Smakowska 《Mineralium Deposita》2009,44(5):559-580
The Silesia–Cracow district in Poland has been one of the world’s principal sources of zinc from nonsulfide zinc ore (Polish:
galman). The still remaining nonsulfide ore resources can be estimated at 57 Mt at 5.6% Zn and 1.4% Pb. Nonsulfide mineralization
is mainly hosted by Lower Muschelkalk (Triassic) limestone and is associated with different generations of the hydrothermal
ore-bearing dolomite (OBD I, II, III). A fundamental ore control is believed to have been exerted by the basement faults,
which were repeatedly reactivated during the Alpine tectonic cycle, leading to the formation of horst-and-graben structures: these dislocations may have caused short periods of emersion and the circulation of meteoric waters during the
Cenozoic. Nonsulfide ores show a wide range of morphological characteristics and textures. They occur as earthy masses, crystalline
aggregates, and concretions in cavities. Breccia and replacement textures are also very common. The most important mineral
phases are: smithsonite, Fe–smithsonite, Zn–dolomite, goethite, and Fe–Mn(hydr)oxides. Minor hemimorphite and hydrozincite
have also been detected. Two distinct nonsulfide ore types occur: the predominant red galman and the rare white galman. In the white galman, Fe–smithsonite and Zn–dolomite are particularly abundant. This ore type is commonly considered as a peripheral hydrothermal
alteration product related to the same fluids that precipitated both the OBD II–III and the sulfides. In contrast, a supergene
origin is commonly assumed for the red galman. Evidence of the petrographic and mineralogical difference between white and red galman is also found in stable isotope data. Smithsonite from red galman shows a limited range of δ
13CVPDB values (−10.1 to −11.4‰), and δ
18OVSMOW values (25.3‰ to 28.5‰, mean 26.8 ± 0.3‰). The uniform and low carbon isotope values of red galman smithsonite are unusual for supergene carbonate-hosted deposits and indicate the predominance of a single organic carbon
source. Smithsonite from white galman has a more variable, slightly more positive carbon isotope (−2.9‰ to −7.4‰), but broadly similar oxygen isotope composition
(26.8‰ to 28.9‰). The relationship of the white galman ore with the hydrothermal system responsible for OBD II and sulfide generation is still uncertain. The most important paleoweathering
events took place in both Lower and Upper Silesia during Late Cretaceous up to Paleogene and early Neogene time. During this
period, several short-lasting emersions and intense weathering episodes facilitated the formation of sinkholes in the Triassic
carbonate rocks and the oxidation of sulfide orebodies through percolating meteoric waters. These phenomena may have lasted
until the Middle Miocene. 相似文献
223.
Holocene variations in annual precipitation (Pann) were reconstructed from pollen data from southern Argentinian Patagonia using a transfer function developed based on a weighted-averaging partial least squares (WA-PLS) regression. The pollen–climate calibration model consisted of 112 surface soil samples and 59 pollen types from the main vegetation units, and modern precipitation values obtained from a global climate database. The performance (r2 = 0.517; RMSEP = 126 mm) of the model was comparable or slightly lower than in other comparable pollen–climate models. Fossil pollen data were obtained from a sediment core from Cerro Frias site (50°24'S, 72°42'W) located at the forest-steppe ecotone. Reconstructed Pann values of about 200 mm suggest dry conditions during the Pleistocene–Holocene transition (12,500–10,500 cal yr BP). Pann values were about 300–350 mm from 10,500 to 8000 cal yr BP and increased to 400–500 mm between 8000 and 1000 cal yr BP. An abrupt decrease in Pann at about 1000 cal yr BP was associated with a Nothofagus decline. The reconstructed Pann suggests a weakening and southward shift of the westerlies during the early Holocene and intensification, with no major latitudinal shifts, during the mid-Holocene at high latitudes in southern Patagonia. 相似文献
224.
Jaqueline C. Rodrigues Tania Maria Haas Costa Márcia R. Gallas Celso C. Moro 《Physics and Chemistry of Minerals》2009,36(8):439-446
We investigate the structural evolution of synthetic layered double hydroxides (LDH) samples, processed at room temperature
and high-pressure (up to 7.7 GPa) in a toroidal chamber with two pressure-transmitting media, lead and graphite, using X-ray
diffraction, thermogravimetry and N2-adsorption isotherms techniques. The X-ray patterns of compacted samples show a decrease in the peak intensities. For both
pressure-transmitting media, our samples revealed a reduction of the basal d-spacing for the (003) plane when processed at
7.7 GPa. The expected high-pressure-induced amorphization was not observed. Surprisingly, we find high-pressure processing
to have a strong influence on the memory effect of the LDH, due essentially to the reduction of the surface area and pore
closing. Even when immersed in water, our samples did not recover the LDH structure, when either calcined at 450°C and compacted
at 7.7 GPa, or calcined at 700°C and immediately compacted at 2.5 and 7.7 GPa. 相似文献
225.
Guy Singleton Maria Fay Rola-Rubzen Kado Muir Deeva Muir Murray McGregor 《GeoJournal》2009,74(5):403-413
In spite of a ‘digital divide’, Aboriginal groups in Australia, as internationally, are increasingly using information and
communication technologies (ICTs) to maintain their cultures, communicate, archive knowledge, empower their communities, develop
skills and generate income. Each community uses the technologies differently in accordance with their particular needs and
the opportunities available. The use of ICTs in Aboriginal youth empowerment is illustrated through a case study of an initiative
undertaken by the Walkatjurra Cultural Centre in Leonora, remote Western Australia. A participatory process was used to engage
the Centre’s young people and they were given individual assistance to develop their ICT related capacity. The community conceives
this youth empowerment to be part of a broader youth participation process that will contribute to the Centre’s overall objectives. 相似文献
226.
With the global container population exceeding 25 million TEU (Twenty-foot Equivalent Unit) and the annual production of new
boxes exceeding 3 million TEU it is estimated that around 1.5 million TEU of empty containers are sitting in yards and depots
around the world waiting for use. Although utilization rates have improved since 2004, container utilization depends on the
very dynamic nature of container transportation, and the container building and leasing industries. Owing primarily to the
chronic trend of increasing trade imbalances across the oceans, and despite recent trends along some trade routes, the empty
container management problem has become a major issue for the container shipping industry during the last decade. This paper
examines and analyzes empty container logistics at a global, interregional, regional and local level. Special consideration
is given to key factors affecting the empty container logistics management and strategies implemented by ocean carriers and
other stakeholders to better manage empty containers.
相似文献
Maria BoileEmail: |
227.
Maria D. Kazachenko Richard C. Canfield Dana W. Longcope Jiong Qiu 《Solar physics》2012,277(1):165-183
In order to better understand the solar genesis of interplanetary magnetic clouds (MCs), we model the magnetic and topological
properties of four large eruptive solar flares and relate them to observations. We use the three-dimensional Minimum Current Corona model (Longcope, 1996, Solar Phys.
169, 91) and observations of pre-flare photospheric magnetic field and flare ribbons to derive values of reconnected magnetic
flux, flare energy, flux rope helicity, and orientation of the flux-rope poloidal field. We compare model predictions of those
quantities to flare and MC observations, and within the estimated uncertainties of the methods used find the following: The
predicted model reconnection fluxes are equal to or lower than the reconnection fluxes inferred from the observed ribbon motions.
Both observed and model reconnection fluxes match the MC poloidal fluxes. The predicted flux-rope helicities match the MC
helicities. The predicted free energies lie between the observed energies and the estimated total flare luminosities. The
direction of the leading edge of the MC’s poloidal field is aligned with the poloidal field of the flux rope in the AR rather
than the global dipole field. These findings compel us to believe that magnetic clouds associated with these four solar flares
are formed by low-corona magnetic reconnection during the eruption, rather than eruption of pre-existing structures in the
corona or formation in the upper corona with participation of the global magnetic field. We also note that since all four
flares occurred in active regions without significant pre-flare flux emergence and cancelation, the energy and helicity that
we find are stored by shearing and rotating motions, which are sufficient to account for the observed radiative flare energy
and MC helicity. 相似文献
228.
Guillermo M. MUÑOZ CARO Frans J. M. RIETMEIJER Virginia SOUZA‐EGIPSY Maria Pilar VALLES‐GONZÁLEZ 《Meteoritics & planetary science》2012,47(2):248-261
Abstract– We used a combination of different analytical techniques to study particle W7190‐D12 using microinfrared spectroscopy, micro‐Raman spectroscopy, and field emission scanning electron microscopy (FESEM) energy dispersive X‐ray spectroscopy (EDS). The particle consists mainly of hematite (α‐Fe2O3) with considerable variations in structural disorder. It further contains amorphous (Na,K)‐bearing Ca,Al‐silicate and organic carbon. Iron‐bearing spherules (<150 nm in diameter) cover the surface of this particle. At local sites of structural disorder at the hematite surface, the hematite spheres were reduced to FeO in the presence of organic carbons forming FeO‐spheres. However, metallic Fe spheres cannot be excluded based on the available data. To the best of our knowledge, this particle is the first detection of such spherules at the surface of a stratospheric dust particle. Although there is no definitive evidence for an extraterrestrial origin of particle W7190‐D12, we suggest that it could be an IDP that had moved away from the asteroid‐forming region of the early solar system into the outer solar system of the accreting Kuiper Belt objects. After it was released from a Jupiter family comet, this particle became part of the zodiacal cloud. Atmospheric entry flash‐heating caused (1) the formation of microenvironments of reduced iron oxide when indigenous carbon materials reacted with hematite covering its surface resulting in the formation of FeO‐spheres and (2) Na‐loss from Na,Al‐plagioclase. The particle of this study, and other similar particles on this collector, may represent a potentially new type of nonchondritic IDPs associated with Jupiter family comets, although an origin in the asteroid belt cannot be ignored. 相似文献
229.
Christian Kofler Volkmar Mair Stephan Gruber Maria Cristina Todisco Ian Nettleton Stefan Steger Marc Zebisch Stefan Schneiderbauer Francesco Comiti 《地球表面变化过程与地形》2021,46(7):1311-1327
The fronts of two rock glaciers located in South Tyrol (Italian Alps) failed on 13 August 2014, initiating debris flows in their downslope channels. A multimethod approach including climate, meteorological, and ground temperature data analysis, aerial image correlation, as well as geotechnical testing and modeling, led to the reconstruction of the two events. An integrated investigation of static predisposing factors, slowly changing preparatory factors, and potential triggering events shed light on the most likely reasons for such failures. Our results suggest that the occurrence of front destabilization at the two rock glaciers can only partly be explained by the occurrence of heavy rainfall events. Indeed, antecedent hydrological and thermal ground conditions were characterized by a saturated active layer favored by a snow-rich winter and extensive precipitation in late spring and summer. Also, the rising trend of air temperature during spring and summer months since 1950s might explain the concurrent marked displacement of the two rock glaciers. Indeed, geotechnical investigations have provided strong indications that one of the investigated rock glacier fronts was at a marginally stable state prior to 2014. As rainfall events more intense than the one that occurred in August 2014 were previously recorded in the same area without resulting failures at the studied rock glaciers, we propose that both predisposing and preparatory destabilizing factors have played a key role in the 2014 rock glacier front failures. 相似文献
230.
Parham Ahmadi Massimo Coltorti Takeshi Kuritani Yue Cai Anna Maria Fioretti 《International Geology Review》2019,61(2):150-174
Tertiary volcanic rocks in northwestern Firoozeh, Iran (the Meshkan triangular structural unit), constitute vast outcrops (up to 250 km2) of high-Mg basaltic andesites to dacites that are associated with high-Nb hawaiites and mugearites. Whole-rock 40Ar/39Ar ages show a restricted range of 24.1 ± 0.4–22.9 ± 0.5 Ma for the volcanic rocks. The initial ratios of 87Sr/86Sr and 143Nd/144Nd vary from 0.703800 to 0.704256 and 0.512681 to 0.512877, respectively, in the high-Mg basaltic andesites–dacites. High-Th contents (up to 11 ppm) and Sr/Y values (27–100) and the isotopic composition of the subalkaline high-Mg basaltic andesites–dacites indicate derivation from a mantle modified by slab and sediment partial melts. Evidence such as reverse zoning and resorbed textures and high Ni and Cr contents in the evolved samples indicate that magma mixing with mafic melts and concurrent fractional crystallization lead to the compositional evolution of this series. The high-Nb hawaiites and mugearites, by contrast, have a sodic alkaline affinity and are silica undersaturated; they are also enriched in Nb (up to 47 ppm) and a wide range of incompatible trace elements, including LILE, LREE, and HFSE. Geochemistry and Sr–Nd isotopic compositions of the high-Nb hawaiites and mugearites suggest derivation from a mantle source affected by lower degrees of slab melts. Post-orogenic slab break-off is suggested to have prompted the asthenospheric upwelling that triggered partial melting in mantle metasomatized by slab-derived melts. 相似文献