Coulometric total carbon dioxide analysis for marine studies: maximizing the performance of an automated gas extraction system and coulometric detector

A global survey of the distribution of dissolved CO₂ taking advantage of sampling opportunities provided by the World Ocean Circulation Experiment: World Hydrographic Program (WOCE-WHP) is being carried out through 1995. Goals include the measurement of oceanic inorganic carbon transport and the development of a data base from which future fossil-fuel CO₂ build-up can be monitored. The analytical method selected for total carbon dioxide (C_T) is gas extraction of acidified seawater with coulometric titration of the acid formed by the resultant carbon dioxide and monoethanolamine. To combine high accuracy and precision (± 1.5 μmol/kg for C_T ≥ 2000 μmol/kg) with a high rate of analysis, we have modified an automated single-parameter system. Following prototype development between 1987 and 1990, an instrument emerged with the acronym Somma standing for single-operator multiparameter metabolic analyzer. Improved functional and operating procedures have integrated electronic calibration, CO₂ gas calibration, and sample analysis with automated pressure, temperature, and conductivity (salinity) sensing into a single convenient transportable package.     

Characterization of the Structure of River-Bed Gravels Using Two-Dimensional Fractal Analysis

This paper is concerned with the application of fractal analysis to understand the structure of water-worked gravel-bed river surfaces. High resolution digital elevation models, acquired using digital photogrammetric methods, allowed the application of two-dimensional fractal methods. Previous gravel-bed river studies have been based upon sampled profiles and hence one-dimensional fractal characterisation. After basic testing that bed elevation increments are Gaussian, the paper uses two-dimensional variogram surfaces to derive directionally dependent estimates of fractal dimension. The results identify mixed fractal behavior with two characteristic fractal bands, one associated with the subgrain scale and one associated with the grain scale. The subgrain scale characteristics were isotropic and sensitive to decisions made during the data collection process. Thus, it was difficult to differentiate whether these characteristics were real facets of the surfaces studied. The second band was anisotropic and not sensitive to data collection issues. Fractal dimensions were greater in the downstream direction than in other directions suggesting that the effects of water working are to alter the level of surface organisation, by increasing surface irregularity and hence roughness. This is an important observation as it means that water-worked surfaces may have a distinct anisotropic signal, revealed when using a fractal type analysis.     

Prediction of the abiotic degradability of organic compounds in the troposphere

A statistically relevant correlation between the reaction rate coefficient, k _OH, for the OH radical reaction with 161 organic compounds in the gas phase at 300 K, and the corresponding vertical ionisation energies E _i,v, reveals two classes of compounds: aromatics where –log(k _OH/cm³s^-1)3/2E _i,v(eV)–2 and aliphatics where –log(k _OH/cm³s^-1)4/5E _i,v(eV)+3. The prediction of the rate coefficient, k _OH, for the reaction of OH with organic molecules from the above equations has a probability of about 90%. Assuming a global diurnal mean of the OH radical concentration of 5×10⁵ cm³, the upper limit of the tropospheric half-life of organic compounds and their persistence can be estimated.     

Possible climate change/variability and human impacts,vulnerability of drought-prone regions,water resources and capacity building for Africa

ABSTRACT

This review article discusses the climate, water resources and historical droughts of Africa, drought indices, vulnerability, impact of global warming and land use for drought-prone regions in West, southern and the Greater Horn of Africa, which have suffered recurrent severe droughts in the past. Recent studies detected warming and drying trends in Africa since the mid 20th century. Based on the Fourth Assessment Report of the Intergovernmental Panel on Climate Change and the Coupled Model Intercomparison Project Phase 5 (CMIP5), both northern and southern Africa are projected to experience drying, such as decreasing precipitation, runoff and soil moisture in the 21st century and could become more vulnerable to the impact of droughts. The daily maximum temperature is projected to increase by up to 8°C (RCP8.5 of CMIP5), precipitation indices such as total wet day precipitation (PRCPTOT) and heavy precipitation days (R10 mm) could decrease, while warm spell duration (WSDI) and consecutive dry days (CDD) could increase. Uncertainties of the above long-term projections, teleconnections to climate anomalies such as ENSO and the Madden-Julian Oscillation, which could also affect the water resources of Africa, and capacity building in terms of physical infrastructure and non-structural solutions are also discussed. Given that traditional climate and hydrological data observed in Africa are generally limited, satellite data should also be exploited to fill the data gap for Africa in the future.

Editor D. Koutsoyiannis; Associate editor N. Ilich     

The Rocky Mountains And The Southwest: Using Feature Names To Study Two Iconic Subregions In The American West

Geographic regions can be defined in many ways, including via physiography, historical development patterns, language, and culture. After broadly surveying different methods of regionalization and their influences on studies of the American West, this article uses a vernacular‐mapping approach to: first, propose distinctive toponyms that are relatively unique to cultures situated in the American Rocky Mountains and Southwest areas; second, map the spatial distributions of these toponyms across the western American landscape; and, third, compare the resulting distributions to the geographies of western businesses that incorporate regional terms into their corporate names. Notably, while the Rocky Mountains and the Southwest are iconic American regions that have captured the imagination for centuries, their cultural geographies are relatively underexplored in the literature. This article makes a modest contribution to this research gap by using geographic information systems (GIS) to map high concentrations of culturally distinctive feature names. The results reveal that the boundaries of vernacular Southwest and Rocky Mountain regions correspond relatively well with boundaries delineated with physiographic characteristics     

Potential of mosques to serve as evacuation shelters for foreign Muslims during disasters: a case study in Gunma,Japan

Natural Hazards - Foreigners tend to be vulnerable to disasters due to religious and cultural differences. In Japan, Muslim foreign residents, who are minorities, likely face difficulties in terms...     

Water Well Hydrographs: An Underutilized Resource for Characterizing Subsurface Conditions

Many of the world's major aquifers are under severe stress as a result of intensive pumping to support irrigated agriculture and provide drinking water supplies for millions. The question of what the future holds for these aquifers is one of global importance. Without better information about subsurface conditions, it will be difficult to reliably assess an aquifer's response to management actions and climatic stresses. One important but underutilized source of information is the data from monitoring well networks that provide near-continuous records of water levels through time. Most organizations running these networks are, by necessity, primarily focused on network maintenance. The result is that relatively little attention is given to interpretation of the acquired hydrographs. However, embedded in those hydrographs is valuable information about subsurface conditions and aquifer responses to natural and anthropogenic stresses. We demonstrate the range of insights that can be gleaned from such hydrographs using data from the High Plains aquifer index well network of the Kansas Geological Survey. We show how information about an aquifer's hydraulic state and lateral extent, the nature of recharge, the hydraulic connection to the aquifer and nearby pumping wells, and the expected response to conservation-based pumping reductions can be extracted from these hydrographs. The value of this information is dependent on accurate water-level measurements; errors in those measurements can make it difficult to fully exploit the insights that water-well hydrographs can provide. We therefore conclude by presenting measures that can help reduce the potential for such errors.