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101.
Hydrologists have long recognized that changes in barometric pressure can produce changes in water levels in wells. The barometric response function (BRF) has proven to be an effective means to characterize this relationship; we show here how it can also be utilized to glean valuable insights into semi‐confined aquifer systems. The form of the BRF indicates the degree of aquifer confinement, while a comparison of BRFs between wells sheds light on hydrostratigraphic continuity. A new approach for estimating hydraulic properties of aquitards from BRFs has been developed and verified. The BRF is not an invariant characteristic of a well; in unconfined or semi‐confined aquifers, it can change with conditions in the vadose zone. Field data from a long‐term research site demonstrate the hydrostratigraphic insights that can be gained from monitoring water levels and barometric pressure. Such insights should be of value for a wide range of practical applications. 相似文献
102.
D. A. Holwell I. McDonald I. B. Butler 《Contributions to Mineralogy and Petrology》2011,161(6):1011-1026
Magmatic sulfide deposits are the most significant source of platinum-group elements (PGE) in the world. Key to understanding
their genesis is determining the processes and timing of sulfide saturation, metal enrichment and crustal contamination. In
this study, we have identified droplets of magmatic sulfide from the Platreef, South Africa, where droplets of sulfide have
been trapped in the earliest crystallising phase, chromite. Due to their early entrapment at high temperatures, metal concentrations
and ratios that they display are indicative of a very early-stage sulfide liquid in the system, as they will have cooled and
fractionated within an essentially closed system, unlike interstitial blebs that crystallise in an open system as the magma
cools. Analysis of these droplets in an opaque mineral like chromite by LA-ICP-MS is problematic as some of the fractionated
inclusion is necessarily lost during cutting and polishing to initially identify the inclusion. This particularly affects
the ability to representatively sample the most fractionated phases such as gold and platinum minerals. Here, using a novel
technique whereby the inclusions are homogenized and quickly quenched, so that any cutting, polishing and subsequent LA-ICP-MS
analysis samples a truly representative portion of the droplet. This has been used to show that early sulfide liquids in the
Platreef were highly PGE-rich and had Pt/Pd ratios of close to unity that supports genetic models invoking sulfide saturation
and metal enrichment prior to intrusion, with pre-enriched sulfides entrained within the Platreef magma. 相似文献
103.
Daniel Cossa Lars-Eric Heimbürger Stephen R. Rintoul Edward C.V. Butler Andrew R. Bowie Roslyn J. Watson 《Geochimica et cosmochimica acta》2011,75(14):4037-4052
We present here the first mercury speciation study in the water column of the Southern Ocean, using a high-resolution south-to-north section (27 stations from 65.50°S to 44.00°S) with up to 15 depths (0-4440 m) between Antarctica and Tasmania (Australia) along the 140°E meridian. In addition, in order to explore the role of sea ice in Hg cycling, a study of mercury speciation in the “snow-sea ice-seawater” continuum was conducted at a coastal site, near the Australian Casey station (66.40°S; 101.14°E). In the open ocean waters, total Hg (HgT) concentrations varied from 0.63 to 2.76 pmol L−1 with “transient-type” vertical profiles and a latitudinal distribution suggesting an atmospheric mercury source south of the Southern Polar Front (SPF) and a surface removal north of the Subantartic Front (SAF). Slightly higher mean HgT concentrations (1.35 ± 0.39 pmol L−1) were measured in Antarctic Bottom Water (AABW) compared to Antarctic Intermediate water (AAIW) (1.15 ± 0.22 pmol L−1). Labile Hg (HgR) concentrations varied from 0.01 to 2.28 pmol L−1, with a distribution showing that the HgT enrichment south of the SPF consisted mainly of HgR (67 ± 23%), whereas, in contrast, the percentage was half that in surface waters north of PFZ (33 ± 23%). Methylated mercury species (MeHgT) concentrations ranged from 0.02 to 0.86 pmol L−1. All vertical MeHgT profiles exhibited roughly the same pattern, with low concentrations observed in the surface layer and increasing concentrations with depth up to an intermediate depth maximum. As for HgT, low mean MeHgT concentrations were associated with AAIW, and higher ones with AABW. The maximum of MeHgT concentration at each station was systematically observed within the oxygen minimum zone, with a statistically significant MeHgTvs Apparent Oxygen Utilization (AOU) relationship (p < 0.001). The proportion of HgT as methylated species was lower than 5% in the surface waters, around 50% in deep waters below 1000 m, reaching a maximum of 78% south of the SPF. At Casey coastal station HgT and HgR concentrations found in the “snow-sea ice-seawater” continuum were one order of magnitude higher than those measured in open ocean waters. The distribution of HgT there suggests an atmospheric Hg deposition with snow and a fractionation process during sea ice formation, which excludes Hg from the ice with a parallel Hg enrichment of brine, probably concurring with the Hg enrichment of AABW observed in the open ocean waters. Contrastingly, MeHgT concentrations in the sea ice environment were in the same range as in the open ocean waters, remaining below 0.45 pmol L−1. The MeHgT vertical profile through the continuum suggests different sources, including atmosphere, seawater and methylation in basal ice. Whereas HgT concentrations in the water samples collected between the Antarctic continent and Tasmania are comparable to recent measurements made in the other parts of the World Ocean (e.g., Soerensen et al., 2010), the Hg species distribution suggests distinct features in the Southern Ocean Hg cycle: (i) a net atmospheric Hg deposition on surface water near the ice edge, (ii) the Hg enrichment in brine during sea ice formation, and (iii) a net methylation of Hg south of the SPF. 相似文献
104.
Emily E. Riddle Amy H. Butler Jason C. Furtado Judah L. Cohen Arun Kumar 《Climate Dynamics》2013,41(3-4):1099-1116
Lagged ensembles from the operational Climate Forecast System version 2 (CFSv2) seasonal hindcast dataset are used to assess skill in forecasting interannual variability of the December–February Arctic Oscillation (AO). We find that a small but statistically significant portion of the interannual variance (>20 %) of the wintertime AO can be predicted at leads up to 2 months using lagged ensemble averages. As far as we are aware, this is the first study to demonstrate that an operational model has discernible skill in predicting AO variability on seasonal timescales. We find that the CFS forecast skill is slightly higher when a weighted ensemble is used that rewards forecast runs with the most accurate representations of October Eurasian snow cover extent (SCE), hinting that a stratospheric pathway linking October Eurasian SCE with the AO may be responsible for the model skill. However, further analysis reveals that the CFS is unable to capture many important aspects of this stratospheric mechanism. Model deficiencies identified include: (1) the CFS significantly underestimates the observed variance in October Eurasian SCE, (2) the CFS fails to translate surface pressure anomalies associated with SCE anomalies into vertically propagating waves, and (3) stratospheric AO patterns in the CFS fail to propagate downward through the tropopause to the surface. Thus, alternate boundary forcings are likely contributing to model skill. Improving model deficiencies identified in this study may lead to even more skillful predictions of wintertime AO variability in future versions of the CFS. 相似文献
105.
Alejandro Carrillo Pablo Huq Mari C. Pérez José M. Redondo 《Estuarine, Coastal and Shelf Science》2008
Spatial and temporal variations in the distribution of the marine picoplanktic cyanobacteria population and mixing conditions were found in the Ebro River estuary outflow to the Mediterranean Sea in Spain. Six sampling surveys were undertaken between July 1999 and February 2000 for distances up to 15 km from the river mouth. Measurements were taken of flow velocity, salinity, temperature, depth and picocyanobacteria (PCB) abundances. Gradient Richardson (Rig) and Reynolds (Re) numbers were determined to evaluate hydrodynamics. In summer, large values of Rig arise from the small flow rates, and small values of velocity shear between the surface fresh water layer and the bottom saline layer; conversely, in winter the large flow rates and attendant large velocity shears between the layers give rise to small values of Rig. Flow conditions in the fall are an intermediate case between the summer and winter cases. Vertical abundance distributions were resolved through the river water, interfacial region, and the bottom salt wedge; longitudinal gradients of PCB abundances were also resolved. Seasonal differences in the PCB abundance values were observed. Analysis of cell numbers (C) showed that the variable dC/dS, the dependence of cell number upon salinity gradient (dS) was critical. A non-dimensional number; the cellular gradient number (Cg) is introduced. Cg has useful biological interpretations that can potentially be included in ecological modeling. For example, Cg = 1 pertains to perfect adaptability of the organism to adjust to changing environmental conditions, whereas Cg = 0 describes total mortality. For a system with strong advection there is insufficient time for cells to adapt to the changing environment, and so those cell counts are unchanged. This is the case for the Ebro estuary in winter as advection of salinity (and hence PCB abundance) dominates the other loss processes for large flow rates. 相似文献
106.
Tree-ring dating is employed to reconstruct chronologies of occurrence for a variety of natural hazards. The number of trees sampled varies greatly as does the minimum number of tree-ring responses. The number of trees to be sampled and an acceptable tree-ring response index should be dictated by the nature and geographical extent of the specific hazard under study. Repetitive sampling of different numbers of 30 avalanche-damaged trees showed significant differences in number of tree-ring responses over a 55-year-period. More sampling and use of a higher minimum response index allowed greater confidence in the chronology constructed from tree-rings and compared to historical records. Three geographic scales of analysis that can confound tree-ring responses are identified, and three guidelines for choosing sample size, given variations in processes, are suggested. 相似文献
107.
108.
Acquisition by the upper atmosphere of some 1014 gm of cometary dust would have major implications on the Earth's climate. Pluvial activity would increase dramatically as temperature differences between sea and land widened. Global distribution of precipitation would be controlled by the density of the dust in the atmosphere; for a partially reflective blanket, a fraction of solar energy would still reach ground level creating new climatic zones. The totally undecomposed state of the interiors of Siberian Mammoths and the curious distribution, often uphill, of erratic boulders point to unbelievably sudden and severe conditions at the onset and possibly end of a glacial period. We suggest that a reflective blanket of particles could produce such conditions. 相似文献
109.
110.
Abstract The type of remotely sensed imagery best suited for natural hazards analysis is largely dependent on the geographic size and discreteness of the hazard in question. Some forms of imagery that are appropriate for analyses of spatially fixed, relatively fine‐scale hazards are inappropriate for use with geographically widespread and transient hazards, and vice versa. In this paper we utilize one study area, Waterton‐Glacier International Peace Park (Canada and USA), and two natural hazard types (snow avalanches and forest fires), to illustrate how these remote sensing principles can be presented to students of natural hazards. We also address the issue of familiarity, or lack thereof, that students have with different images from a variety of platforms. 相似文献