Assessment of Submarine Groundwater Discharge (SGD) as a Source of Dissolved Radium and Nutrients to Moorea (French Polynesia) Coastal Waters

Previous work has documented large fluxes of freshwater and nutrients from submarine groundwater discharge (SGD) into the coastal waters of a few volcanic oceanic islands. However, on the majority of such islands, including Moorea (French Polynesia), SGD has not been studied. In this study, we used radium (Ra) isotopes and salinity to investigate SGD and associated nutrient inputs at five coastal sites and Paopao Bay on the north shore of Moorea. Ra activities were highest in coastal groundwater, intermediate in coastal ocean surface water, and lowest in offshore surface water, indicating that high-Ra groundwater was discharging into the coastal ocean. On average, groundwater nitrate and nitrite (N + N), phosphate, ammonium, and silica concentrations were 12, 21, 29, and 33 times greater, respectively, than those in coastal ocean surface water, suggesting that groundwater discharge could be an important source of nutrients to the coastal ocean. Ra and salinity mass balances indicated that most or all SGD at these sites was saline and likely originated from a deeper, unsampled layer of Ra-enriched recirculated seawater. This high-salinity SGD may be less affected by terrestrial nutrient sources, such as fertilizer, sewage, and animal waste, compared to meteoric groundwater; however, nutrient-salinity trends indicate it may still have much higher concentrations of nitrate and phosphate than coastal receiving waters. Coastal ocean nutrient concentrations were virtually identical to those measured offshore, suggesting that nutrient subsidies from SGD are efficiently utilized.     

Forecasting the water inflow into the Krasnoyarsk and Sayano-Shushenskoe reservoirs in the second quarter of the year

We consider the various methods of constructing models intended to forecast the average water inflow, in the second quarter of the year, into two reservoirs on the Yenisei river. To solve modeling problems used a new computer technology implemented in the specialized “Stochastic Modeling” software package. Independent data were employed to verify the variants of the models for the formation of variability in quarterly inflow as generated based on different algorithms. A more sophisticated and robust model for forecasting the inflow was constructed as an ensemble of partial models. Based on aggregate results of modeling, we suggest the method of constructing a forecast of the average (for the second quarter) lateral inflow into the Krasnoyarsk reservoir and the inflow into the Sayano-Shushenskoe reservoir by use of observational data accumulated by Srednesibirskoe UGMS (Weather Control and Environmental Monitoring Service), based on an ensemble of partial models. It is established that such an operation reduces the probability of forecasting errors implying an arbitrary selection of models. We constructed forecasts of the aforementioned characteristics using real-time data for 2015. It is stated that the solution of the forecasting problem can be facilitated by using additional information.     

Influence of melioration in natural ecological processes of a small river valley (Poland)

On the basis of the topographic maps from 1933, 1951 and 1962 (sc 1:10 000, 1:25 000 and 1:100 000, respectively) and the satellite image from 2014 (sc 1:10 000), we determined changes in the channel of the small Brynica river (Southern Poland) as well as in the land-use pattern along this river valley after its melioration. Terrain regulation and drainage brought about an intensification of the overland runoff, and a decrease in irrigation of the territory. Due to soil overdrying, some tracts of the valley are experiencing a moisture deficiency. Peat drying can lead to negative consequences, because shallow peats mostly occur on the study territory. Disappearance of peaty soils acts to decrease the degree of suitability of the riverside territories for economic purposes as well as their capacity for recovery. The schematic map of vegetation distribution along the river valley prior to and after melioration as compiled from results of field observations displays differences between mosaic quasi-natural vegetation and areas of typical agrocenoses. The preservation of the natural values along the Brynica valley is possible through balanced economic management, while the differentiation of topography contributes to creating favorable conditions for the formation of biodiversity.     

Petrophysical features of the tectonic structures of the Okhotsk continent–ocean transition zone

Petrophysical characteristics are determined for the rock complexes of the Okhotsk margin within the continent–ocean transition zone. Petrophysical maps showing the major inhomogeneities of the main tectonic elements of the studied area are constructed. Petrophysical inhomogeneities and the corresponding geophysical field anomalies are compared. A relationship between the magnetic field anomalies and subsurface rock complexes is revealed. The gravity field anomalies are related to deep inhomogeneities and are almost independent of the subsurface rock complexes of relatively low thickness.     

Mechanistic evaluation and reaction pathway of UV photo-assisted Fenton-like degradation of progesterone in water and wastewater

The mechanisms and reaction pathway of UV photo-assisted Fenton-like degradation of progesterone in water and wastewater were investigated. The reaction followed the pseudo-first-order kinetics for both the dark Fenton-like and UV photo-Fenton-like processes. The reaction kinetics of the UV photo-assisted process improved with the presence of humic acid (HA) in wastewater, due to the formation of Fe(III)-HA complexes which enhanced Fe(II) production by a ligand-to-metal charge transfer. The UV photo-assisted process reduced the amount of ferric required to completely degrade progesterone by 60 % and lowered the activation energy to 42 kJ/mol compared to 104 kJ/mol for the dark Fenton-like process. Complete degradation of progesterone was achieved through a multi-step process involving several intermediate compounds.     

Long-Term Geochemical Monitoring of the Source of the Angara River (Runoff from Lake Baikal)

The long-term data (1950–2017) on the chemical composition of the water from the source of the Angara River, which is the only run-off from Lake Baikal, a large and clean fresh water reservoir, are presented. The absence of water contamination despite the anthropogenic influence is shown. The similarity and constancy of the current composition of the waters in the lake and the Angara River are recorded. It is recommended to continue geochemical studies of this unique world heritage site.