Transport of U in the Opalinus Clay on centimetre to decimetre scales

The Opalinus Clay formation in North Switzerland is a potential host rock for a deep underground radioactive waste repository. The distribution of ²³⁸U, ²³⁴U and ²³⁰Th was studied in rock samples of the Opalinus Clay from an exploratory borehole at Benken (Canton of Zurich) using MC-ICP-MS. The aim was to assess the in situ, long-term migration behaviour of ²³⁴U in this rock. Very low hydraulic conductivities of the Opalinus Clay, reducing potential of the pore water and its chemical equilibrium with the host rock are expected to render both ²³⁸U and ²³⁰Th immobile. If U is heterogeneously distributed in the Opalinus Clay, gradients in the supply of ²³⁴U from the rock matrix to the pore water by the decay of ²³⁸U will be established. Diffusive redistribution separates ²³⁴U from its immobile parent ²³⁸U resulting in bulk rock ²³⁴U/²³⁸U activity disequilibria. These may provide a means of estimating the mobility of ²³⁴U in the rock if the diffusion rate of ²³⁴U is significant compared to its decay rate. Sampling was carried out on two scales. Drilling of cm-spaced samples from the drill-core was done to study mobility over short distances and elucidate possible small-scale lithological control. Homogenized 25-cm-long portions of a 2-m-long drill-core section were prepared to provide information on transport over a longer distance. Variations in U and/or Th content on the cm-scale between clays and carbonate-sandy layers are revealed by β-scanning, which shows that the (dominant) clay is richer in both elements.     

Holocene and Pleistocene pluvial periods in Yemen,southern Arabia

Arabia is an important potential pathway for the dispersal of Homo sapiens (“out of Africa”). Yet, because of its arid to hyper-arid climate humans could only migrate across southern Arabia during pluvial periods when environmental conditions were favorable. However, knowledge on the timing of Arabian pluvial periods prior to the Holocene is mainly based on a single and possibly incomplete speleothem record from Hoti Cave in Northern Oman. Additional terrestrial records from the Arabian Peninsula are needed to confirm the Hoti Cave record. Here we present a new speleothem record from Mukalla Cave in southern Yemen. The Mukalla Cave and Hoti Cave records clearly reveal that speleothems growth occurred solely during peak interglacial periods, corresponding to Marine Isotope Stages (MIS) 1 (early to mid-Holocene), 5.1, 5.3, 5.5 (Eemian), 7.1, 7.5 and 9. Of these humid periods, highest precipitation occurred during MIS 5.5 and lowest during early to middle Holocene.     

Solving the kriging problem by using the Gram-Schmidt orthogonalization

This paper presents an approach to solve the kriging problem, defined in terms of projections, by using Gram-Schmidt orthogonalization. The Gram-Schmidt orthogonalization allows us to find an optimal approximationY* in then-dimensional subspaceH _n of any vectorY element of a Hilbert spaceH. This approach requiresO(n ³) multiplication operations to obtain an orthogonal basis, andO(n ²) multiplications needed to calculate kriging solution for a given point.     

A palaeomagnetic study of fracture fills in the Holy Cross Mountains of Central Poland and its application in dating tectonic processes

Calcite and sedimentary fills in fractures cutting the Upper Devonian carbonates in the Holy Cross Mountains (HCM) were dated palaeomagnetically by comparison with the apparent polar wander path (APWP). Haematite-bearing calcite possessed well-defined components of natural remanent magnetization (NRM), which were preserved under thermal demagnetization to temperatures of approximately 500 °C, when specimens disintegrated. Although not completely demagnetized, some specimens revealed a stable NRM component before destruction, thus making a component analysis possible. Five components were determined using density point distribution and cluster analysis. One has a mean that is similar to the present-day local geomagnetic vector. The remaining four components yielded palaeomagnetic poles located at: A (70.3°S, 5.5°E), B (71.3°S, 31.2°E), C (48.7°S, 351.0°E, virtual geomagnetic pole), and D (11.6°S, 312.3°E). Antipodal polarities found in the fracture fills, together with dissimilarities in magnetization found in calcite and hosting carbonates, indicate the lack of simultaneous remagnetization, and different times of remanence acquisition for the rocks under comparison. Taking both palaeomagnetically inferred palaeolatitudes and regional tectonics into consideration, a Mesozoic (Cretaceous?) age is estimated for palaeopoles A and B, a Permian age for pole C, and a Carboniferous age for pole D. These age determinations are in line with the calcite ages estimated from isotopic studies. A comparative palaeomagnetic study performed on a well-dated Upper Devonian neptunian dyke of limestone and a Lower Triassic clastic vein yielded virtual geomagnetic poles (VGPs) close to the APWP for Baltica. Generally, the remanence from fracture fills may be useful for dating related tectonics, karst phenomena and mineralization processes.     

Reflected-diffracted waves in fracture zone models

Summary. The paper presents the results of modelling of diffracted and reflected-diffracted waves in fracture zones. The Berryhill method was used and the calculations were made for a profile perpendicular to the diffracting edge. Several homogeneous models of the Earth's crust, characterized by different values of crustal thickness, velocity and horizontal distance between shot point and diffracting edge were considered. A dependence of the relative amplitude of diffracted waves on the location of the diffracting edge is given. The pattern of the seismic wavefield depends upon the dimensions of the fracture zone. Amplitude curves of reflected-diffracted waves are presented for a series of models of fracture zones. The possibility of applying the amplitudes of reflected-diffracted wave trains to the interpretation of the structure of fracture zones in the Earth's crust is andysed for different types of fracture zones.