U–Pb zircon chronostratigraphy of early-Pliocene ignimbrites from La Pacana, north Chile: implications for the formation of stratified magma chambers

High spatial resolution U–Pb dates of zircons from two consanguineous ignimbrites of contrasting composition, the high-silica rhyolitic Toconao and the overlying dacitic Atana ignimbrites, erupted from La Pacana caldera, north Chile, are presented in this study. Zircons from Atana and Toconao pumice clasts yield apparent ²³⁸U/²⁰⁶Pb ages of 4.11±0.20 Ma and 4.65±0.13 Ma (2σ), respectively. These data combined with previously published geochemical and stratigraphic data, reveal that the two ignimbrites were erupted from a stratified magma chamber. The Atana zircon U–Pb ages closely agree with the eruption age of Atana previously determined by K–Ar dating (4.0±0.1 Ma) and do not support long (>1 Ma) residence times. Xenocrystic zircons were found only in the Toconao bulk ignimbrite, which were probably entrained during eruption and transport. Apparent ²³⁸U/²⁰⁶Pb zircon ages of 13 Ma in these xenocrysts provide the first evidence that the onset of felsic magmatism within the Altiplano–Puna ignimbrite province occurred approximately 3 Myr earlier than previously documented.     

Brønsted reactions on oxide mineral surfaces and the temperature-dependence of their dissolution rates

The pH-dependence of oxide dissolution rates is controlled by Brønsted acid-base reactions at the mineral surface. These reactions are rapid but depend explicitly on temperature, as do the subsequent slow rates of bond hydrolysis. The net result is that dissolution rates vary in a complicated fashion with temperature and solution pH. The enthalpy changes of acid-base reactions on oxide materials are sufficiently similar, however, that general statements can be made about their contribution. The enthalpy changes from proton adsorption to a hydroxyl functional group (SOH), or to a deprotonated functional group (SO ^–), are generally exothermic. The enthalpy changes become increasingly endothermic, however, as charge accumulates on the mineral surface and the charged species interact electrostatically. The result is that mineral dissolution rates are least sensitive to temperature, as measured with an Arrhenius-like rate law, at pH conditions near the Point of Zero Net Proton Charge.     

Sequential melting and fractional crystallization: Granites from Guarda-Sabugal area, central Portugal

Seven distinct phases of Variscan two-mica granite are recognized in the Guarda-Sabugal area. They intruded the Cambrian schist-metagraywacke complex, crystallized in the middle crust, and are syn- to late-D3 (309.2 ± 1.8 Ma), late-D3 (304–300 Ma) and late- to post-D3 (299 ± 3 Ma; ID-TIMS ages on zircon and monazite). Two of the granites, G2 and G5, are close in age and have similar Sr, Nd and O isotope characteristics but contrasting whole rock and mineral features and formed by sequential increasing degree of partial melting of a common metasedimentary protolith. During sequential melting Ti, total Fe, Mg, Ca, Zr, Zn, Sr, Ba and REE contents and (La/Yb)_N increase and Si and Rb contents decrease, plagioclase becomes richer in anorthite and biotite and muscovite richer in Ti and Mg. Each of these granites evolved subsequently by fractional crystallization of quartz, K-feldspar, plagioclase, biotite and ilmenite, defining separate series G2–G3–G7 and G5–G6 containing late Sn-bearing differentiates. Two other granites G1 and G4 represent distinct pulses of magma with individual fractionation trends for major and trace elements and distinct (⁸⁷Sr/⁸⁶Sr)₃₀₀, ?Nd₃₀₀ and δ¹⁸O values.     

Observations of mine seismicity in the eastern Wasatch Plateau,Utah, U.S.A.: A possible case of implosional failure

In the summer of 1984, a three-dimensional, high-resolution microearthquake network was operated in the vicinity of two coal mines beneath Gentry Mountain in the eastern Wasatch Plateau, Utah. During a six-week period, approximately 3,000 seismic events were observed of which the majority were impulsive, higher frequency (>10 Hz), short duration (<2–3 sec) events probably associated with the caving of the roof from a longwall operation. In contrast, 234 of the largest located events appeared to occur predominantlybeneath the mines to a depth of 2 to 3 km consistent with previous studies. The magnitudes of these events ranged from less thanM _c 0 to 1.6. In addition to the unusual depths of these latter events, an anomalous aspect displayed by the events was an apparent dilatational focal mechanism suggesting a non-double-couple, possibly implosional source. Implosional events have been observed in other studies of mine seismicity; however, the generally inadequate instrumental coverage of the focal sphere has cast some doubt on the validity of such mechanisms. Previously suggested source mechanisms for such implosional events have included tensional failure through strata collapse, and a shear-implosional displacement mechanism. Shear failure must be involved in the failure process of the Gentry Mountain implosional events as evidenced by well-defined shear waves in the observed seismograms. Simultaneous monitoring in the East Mountain coal mining area to the south by the University of Utah revealed typical shear failure events mixed with implosional events. The observed double-couple, reverse focal mechanisms at East Mountain were similar to mechanisms determined in previous studies and a composite focal mechanism determined in this study for a sequence outside the mining areas. This suggested that the shear events within the mining areas are being influenced by the regional tectonic stress field. Thus in addition to the seismic events associated with caving of the roof from the longwall operation, there appear to be at least two other types of mining-induced seismic events occurring in the eastern Wasatch Plateau, both submine in origin: (1) events characterized by apparent non-double-couple possibly implosional focal mechanisms and well-defined shear waves; and (2) shear events, which are indistinguishable from tectonic earthquakes and may be considered mining triggered earthquakes. The small mining-induced stress changes that occur beyond a few hundred meters from the mine workings suggest both types of seismic events are occurring on critically stressed, pre-existing zones of weakness. Topography, overburden, method of mining, and mine configuration also appear to be significant factors influencing the occurrence of the implosional submine events.     

Low Visibility Formation and Forecasting on the Northern Coast of Brazil

Visibility analysis and forecast at the Maceio International Airport in the Brazilian Northeast (NEB) was the principal goal of this investigation. Surface meteorological data of the Maceio International Airport were used for low visibility frequency study. Low visibility in NEB was provoked more frequently by light fog (LF) formation (1,098 or 92 h month^?1 on average). Haze and fog were very rare (81 h and one event per year, respectively on average). Light fog with a visibility less than 2 km usually was detected together with rain or drizzle. Low visibility was observed more frequently at night and during the rainy season. Applications of the Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model for light fog forecast were tested. Thermodynamic processes were studied by vertical profile, elaborated by: (1) National Centers for Environmental Prediction (NCEP) reanalysis data for Maceio (because of some radiosonde absence) and (2) forecast vertical temperature and humidity profiles were produced, using Air Parcels Trajectories of the HYSPLIT model at the pattern levels. The synoptic situations before and during low visibility phenomena were analyzed using different products of NCEP reanalysis, the high resolution (10 km) ETA model and infrared satellite images. Wave disturbance in the trade winds field, localized on the northwest periphery of the South Atlantic subtropical High, usually accompanied the phenomena. A humidity advection, weak ascendant movement and thermal inversion absence at the low levels were created by these waves. The middle level’s descendent movement provoked the humidity accumulation at levels below. Satisfactory results of the HYSPLIT model applications for light fog forecast were obtained with 12 h antecedence. In particular, stable level forecast by the ETA model was forecast satisfactorily with 12 h antecedence; vertical movements were predicted better with up to 48 h antecedence. The PSU/NCAR mesoscale model (MM5) and PAFOG models were tested for analysis and forecast of an intensive fog event. Intensive fog provoked a fatal accident of a small airplane near the Maceio Airport in 2007. These fog formation processes were studied by NCEP reanalysis data, the high resolution regional model MM5, and satellite and radar data. Fog formation was simulated by PAFOG model and satisfactory results were obtained with 10 h antecedence.     

Local disappearance of bivalves in the Azores during the last glaciation

The Pleistocene (Eemian) outcrops of Lagoinhas and Prainha, located at Santa Maria Island (Azores), were investigated and their fossil mollusc content reported. These studies revealed that the last glaciation affected two groups of molluscs: the ‘warm‐guest’ gastropods with West African or Caribbean affinities (e.g. Conus spp., Cantharus variegatus, Bulla amygdala, Trachypollia nodulosa) and shallow bivalve species mainly associated with sandy habitats (Ensis minor, Lucinella divaricata, and probably Laevicardium crassum). In this paper we focus on this group of bivalves, which has since locally disappeared from the Azores. We relate the local disappearance of these bivalves in the Azores with the lack of sand in the shelf. The specific characteristics of the Santa Maria shelf combined with the sea‐level drop during the Weichselian prevented deposition of the lowstand deposits and permitted erosion of the previous ones, leaving the shelf without a sediment cover. Copyright © 2008 John Wiley & Sons, Ltd.     

Lake sedimentary processes and vegetation changes over the last 45k cal a bp in the uplands of south-eastern Amazonia

This study addresses paleoclimate influences in a southern Amazonia ecotone based on multiproxy records from lakes of the Carajás region during the last 45k cal a bp. Wet and cool environmental conditions marked the initial deposition in shallow depressions with detrital sediments and high weathering rates until 40k cal a bp. Concomitantly, forest and C3 canga plants, along with cool-adapted taxa, developed; however, short drier episodes enabled expansion of C4 plants and diagenetic formation of siderite. A massive event of siderite formation occurred approximately 30k cal a bp under strong drier conditions. Afterwards, wet and cool environmental conditions returned and persisted until the Last Glacial Maximum (LGM). The LGM was marked by lake-level lowstands and subaerial exposure. The transition from the LGM to the Holocene is marked by the onset of oscillations in temperature and humidity, with an expansion of forest and canga plants. Cool taxa were present for the last time in the Carajás region ~ 9.5–9k cal a bp. After 10k cal a bp , shallow lakes became upland swamps due to natural infilling processes, but the current vegetation types and structures of the plateaus were acquired only after 3k cal a bp under wetter climatic conditions.     

Formal definition of a user-adaptive and length-optimal routing graph for complex indoor environments

Car routing solutions are omnipresent and solutions for pedestrians also exist.Furthermore,public or commercial buildings are getting bigger and the complexity of their internal structure has increased.Consequently,the need for indoor routing solutions has emerged.Some prototypes are available,but they still lack semantically-enriched modelling (e.g.,access constraints,labels,etc.) and are not suitable for providing user-adaptive length-optimal routing in complex buildings.Previous approaches consider simple rooms,concave rooms,and corridors,but important characteristics such as distinct areas in huge rooms and solid obstacles inside rooms are not considered at all,although such details can increase navigation accuracy.By formally defining a weighted indoor routing graph,it is possible to create a detailed and user-adaptive model for route computation.The defined graph also contains semantic information such as room labels,door accessibility constraints,etc.Furthermore,one-way paths inside buildings are considered,as well as three-dimensional building parts,e.g.,elevators or stairways.A hierarchical structure is also possible with the presented graph model.     

Magnetic susceptibility and its relationship with paleoenvironments, diagenesis and remagnetization: examples from the Devonian carbonates of Belgium

To better understand the origin of the initial magnetic susceptibility (??_in) signal in carbonate sequences, a rock magnetic investigation that includes analysis of acquisition curves of the isothermal remanent magnetization (IRM) and hysteresis parameters, was undertaken on Devonian carbonates from the Villers and Tailfer sections, Belgium. Both sections are divided into a lower unit, dominated by biostromal and external ramp facies (biostromal unit) and an upper unit, only consisting of lagoonal facies (lagoonal unit). The variations in ??_in signal are mainly driven by magnetite variation, mostly pseudo-single-domain (PSD) magnetite. Clay minerals, pyrite, hematite and obviously calcite and dolomite are also present but their contribution to the ??_in pattern is not significant. There is a correlation between detrital proxies (Zr, Rb, Al₂O₃, TiO₂) and ??_in for the Tailfer biostromal unit and the entire Villers section. The pervasive presence of fine-grained magnetite is interpreted as related to remagnetization. In absence of external fluids, the iron released during the smectite to illite transition remains in situ. In those situations ??_in may reflect an inherited primary synsedimentary signal. In the lagoonal unit of the Tailfer section, remagnetization appears to have obscured the original detrital information prompting the need for an evaluation of the composition of the susceptibility signal for individual case studies.