Structural control of the distribution of trace elements between silicates and hydrothermal solutions

Over several years many partition coefficients have been measured between framework silicates, sheet silicates and hydrothermal solutions. Only trace alkaline cations are considered in the present work. It is well known that the difference between ionic radii of the trace cation and the major cation is replaces is not satisfactory for a good correlation with the partition coefficients P_X. A structural parameter δ_c is therefore defined, taking into consideration the adaptation of the trace cation to the cavity in which it occurs. This cavity may be the entire site of the major element, or a part of this site in the case of small cations, or a structural cavity located out of the alkali-ion site. The adaptation parameter δ_c is the difference between the ionic radius of the trace cation and the radius of that cavity. This paper shows that the partition coefficient P_X of the trace alkali-ion from the hydrothermal solution is an exponential function of the adaptation parameter δ_c, whatever the silicate may be.     

Brèches sédimentaires marines à la frontière entre les domaines briançonnais et piémontais dans les Alpes occidentales

Different types of jurassic and cretaceous submarine breccias, deposited on the internal part of the Briançonnais shoal, and on the external part of the Piemont trough, are described, especially breccias of the Acceglio zone, which show a cement looking like a “sedimentary micaschist”. Genetic problems are discussed: rock breaking and disintegration, and transportation of rock fragments.     

Assessment of Cyto‐ and Genotoxic Effects of a Variety of Chemicals Using Saccharomyces cerevisiae

Saccharomyces cerevisiae as the most simple eukaryotic organism is broadly accepted as a laboratory model organism. For the detection of potential toxic effects of pure compounds and complex composed samples like wastewater a miniaturised short‐term in vitro cyto‐ and genotoxicity screening assay was developed. The assay based on genetically modified S. cerevisiae cells deleted in the prominent drug efflux transporters Pdr5, Snq2, and Yor1 that facilitate pleiotropic drug resistance. The yeast strain devoid of these proteins that mediate the efflux of structurally diverse hydrophobic compounds exhibited an increased sensitivity to a variety of organic compounds. The DNA damage inducible RAD54 promoter fused to a yeast optimized derivative of the GFP (green fluorescent protein) gene from the jelly fish Aequorea victoria served as an indicator of DNA damage in this strain. Various pure compounds including the direct‐acting genotoxins methyl‐N‐nitro‐N‐nitrosoguanidine (MNNG), 4‐nitroquinoline‐N‐oxide (4‐NQO), methyl methanesulfonate (MMS) and hydroxyurea as well as the heavy metals cadmium and chromium(VI), the insecticide lindane and the central nervous system stimulant caffeine were tested exhibiting dose dependent induction of green fluorescence. All compounds were in parallel examined for chronic toxicity. A bioassay detecting simultaneously geno‐ and cytotoxic effects of potential toxicants in a single assay can be an important tool with a variety of applications in environmental monitoring and aquatic ecotoxicology. By partial automation and miniaturisation to microtitration scale this bioassay enables sensitive and fast biomonitoring for a multitude of samples.     

Découverte de structures périglaciaires (sand-wedges et composite-wedges) sur le site de stockage de déchets radioactifs de l'Aube (France)

Since 1990, a dense network of subvertical cracks has been observed at the upper part of the Albian sands of the site of radioactive waste storage operated by ANDRA. New studies carried out in 1999 during enlargement of the site of Soulaines and in 2003 on the nearby TFA site highlighted an especially well-developed network of periglacial features that are mainly of the sand-wedge type (subvertical stratified infill). These observations demonstrate the periglacial origin of these cracks, which are mainly superimposed on a dense network of former tectonic extension joints, and that rapidly disappear at the top of the underlying clays. In addition, these observations currently represent the only example of a large sand-wedge network developed during the Last Glacial in northern France. To cite this article: P. Antoine et al., C. R. Geoscience 337 (2005).     

Isolation and characterization of Aeromonas species from an eutrophic tropical estuary

Isolation and characterization of Aeromonas species were undertaken in the Ebrié lagoon (Abidjan, Côte d’Ivoire) over a one year period. Overall 63% of 501 water samples were identified as positive for Aeromonas spp. A. sobria, A. hydrophila and A. caviae represent respectively 49.20%, 20.63% and 30.15% of the positive samples. Thirty nine of the positive samples were recovered from surface water samples; while 24 bottom water samples were positive for Aeromonas. Aeromonas species are most frequently (82.53) present in the Ebrié lagoon urban area during the rainy and flood seasons when the salinity is low and below 10‰. A lower isolation frequency is noticed during the dry season when water salinity is over 10‰. Finally, a higher isolation frequency occurred in samples with highest counts of Escherichia coli.     

Landscape Roughness Parameters for Sherwood Forest – Experimental Results

The aim of this work is to present experimentally evaluated effective roughnesses (zoe) of a partly forested landscape. Although the ratio of boundary-layer height to obstacle size was only of the order of 50, there still seemed to exist a height range of 75–200 m where surface-layer similarity was approximately valid. Attempts were made to use conventional wind profile analysis to evaluate zoe, but the small height range and the large number of variables initially led to unacceptable uncertainties. Fixing the displacement height zd, rather than fitting it, reduced the data scatter to an acceptable level. The profile-derived roughness lengths zop obtained in this way were in good agreement with previous work, and with an alternative roughness length estimate zof for which flux-derived profile parameters u* and * were used. This implies that the profile-derived roughnesses were consistent with the measured surface-layer momentum flux. Comparison of both roughness estimates also yielded an improved estimate of the displacement height. Besides this, the authors tested a landscape roughness evaluation method which makes use of the gustiness parameter Tu = u/U in the surface layer. The results obtained by this method were in fair agreement with the profile-derived data. In previous work, the gustiness method was advocated because it could be used at relatively low levels, perhaps even within the roughness sub-layer. At the present measuring site, this was not the case as the gustiness method was only valid in an approximate way, and for a limited height range.     

Modelling Spatial Patterns of Overbank Sedimentation on Embanked Floodplains

This paper presents a GIS-based mathematical model for the simulation of floodplain sedimentation. The model comprises two components: (1) the existing hydrodynamic WAQUA model that calculates two-dimensional water flow patterns; and (2) the SEDIFLUX model that calculates deposition of sediment based on a simple mass balance concept with a limited number of model parameters. The models were applied to simulate floodplain sediment deposition over river reaches of several kilometres in length. The SEDIFLUX model has been calibrated and validated using interpolated raster maps of sediment deposition observed after the large magnitude December 1993 flood on the embanked floodplain of the lower river Rhine in the Netherlands. The model appeared to be an adequate tool to predict patterns of sediment deposition as the product of the complex interaction among river discharge and sediment concentration, floodplain topography, and the resulting water flow patterns during various discharge levels. In the investigated areas, the resulting annual average sedimentation rates varied between 0.5 mm/year and 4.0 mm/year. The role of the most important mechanisms governing the spatial patterns of overbank deposition, i.e. inundation frequency, sediment load, floodplain topography and its influence on the flow patterns over the floodplain, are discussed.