Etude des Déformations et Inclinaisons du Sous-sol: Développements Instrumentaux et Applications dans la Région Sismique d’Arette,France

We present a modified version of a tilt and strain meter conceived to have great sensibility and good stability. These instruments were deployed in a cave at the seismic Pyrenean region of Arette (France). We set in evidence several types of phenomena, of which deformations brought about by water recharge filling up fissures on the massif are of importance. Owing to the redundance in the data, the study of the co-seismic deformations allows one to separate instrumental displacements and local readjustments from regional motions.     

Field‐based and spectral indicators for soil erosion mapping in semi‐arid mediterranean environments (Coastal Cordillera of central Chile)

The Coastal Cordillera of central Chile is naturally sensitive to soil erosion due to moderate to steep slopes, intense winter rains when the vegetation cover is scarce, and deeply weathered granitic rocks. In 1965, 60 per cent of its surface was moderately to very severely eroded. Today this process is still largely active, but no data are currently available to evaluate the real extent, distribution and severity of soil degradation on a regional scale. This information is vital to support efficient soil conservation plans. A multi‐scale approach was implemented to produce regional land degradation maps based on remote sensing technologies. Fieldwork has shown that the surface colour or ‘redness’ and the density of coarse fragments are pertinent erosion indicators to describe a typical sequence of soil degradation in the context of mediterranean soil developed on granitic materials and micaschists. Field radiometric experiments concluded that both factors influence the reflectance of natural surfaces and can be modelled using radiometric indices accessible from most satellites operating in the optical domain, i.e. redness index and brightness index. Finally the radiometric indices were successfully applied to SPOT images to produce land degradation maps. Only broad classes of erosion status were discriminated and the detection of the degradation processes was only possible when most of the fertile layer had already been removed. This technology provides decision‐making information required to develop regional soil conservation plans and to prioritize actions between catchment areas, especially in vast inter‐tropical regions where spatialized data are not always readily available. Copyright © 2006 John Wiley & Sons, Ltd.     

Petrochemical Investigation of the Antique Ophiolite (Philippines): Implications on Volcanogenic Massive Sulfide and Podiform Chromitite Deposits

Abstract: The Antique ophiolite, located in Panay island (west‐central Philippines), corresponds to several tectonic slices within the suture zone between the Philippine Mobile Belt (PMB) and the North Palawan Block (NPB). It includes dismembered fragments of a basaltic sequence, dominantly pillow‐lavas with minor sheet flows, rare exposures of sheeted dikes, isotropic gabbros, subordinate layered mafic and ultramafic rock sequences and serpentinites. Most of the ophiolite units commonly occur as clasts and blocks within the serpentinites, which intrude the whole ophiolitic body, as well as, the basal conglomerate of the overlying Middle Miocene sedimentary formation. The volcanic rock sequence is characterized by chemical compositions ranging from transitional (T)‐MORB, normal (N)‐MORB and to chemistry intermediate between those of MORB and island arc basalt (IAB). The residual upper mantle sequence is harzburgitic and generally more depleted than the upper mantle underlying modern mid‐oceanic ridges. Calculations using whole‐rock and mineral compositions show that they can represent the residue of a fertile mantle source, which have undergone degrees of partial melting ranging from 9‐22.5 %. Some of the mantle samples display chondrite‐nor‐malized REE and extended multi‐element patterns suggesting enrichments in LREE, Rb, Sr and Zr, which are comparable to those found in fore‐arc peridotites from the Izu‐Bonin‐Mariana (IBM) arc system. The Antique ultramafic rocks also record relatively oxidizing mantle conditions (Δlog f_O2 (FMQ)=0.9‐3.5). As a whole, the ophiolite probably represents an agglomeration of oceanic ridge and fore‐arc crust fragments, which were juxtaposed during the Miocene collision of the PMB and the NPB. The intrusion of the serpentinites might be either coeval or subsequent to the accretion of the oceanic crust onto the fore‐arc. Volcanogenic massive sulfide (VMS) deposits occur either in or near the contact between the pillow basalts and the overlying sediments or interbedded with the sediments. The morphology of the deposits, type of metals, ore texture and the nature of the host rocks suggest that the formation of the VMS bodies was similar to the accumulation of metals around and in the subsurface of hydrothermal vents observed in modern mid‐oceanic ridge and back‐arc basin rift settings. The podiform chromitites occur as pods and subordinate layers within totally serpentinized dunite in the residual upper mantle sequence. No large coherent chromitite deposit was found since the host dunitic rocks often occur as blocks within the serpentinites. It is difficult to evaluate the original geodynamic setting of the mineralized bodies since the chemistry of the host rocks were considerably modified by alteration during their tectonic emplacement. A preliminary conclusion for Antique is that the VMS is apparently associated with a primitive tholeiitic intermediate MORB‐IAB volcanic suite, the chemistry of which is close to the calculated composition of the liquid that coexisted with the podiform chromitites.     

Atmospheric absorption in the O2 Schumann-Runge band spectral range and photodissociation rates in the stratosphere and mesophere

A general analysis of the absorption of the Schumann-Runge bands of molecular oxygen has been made in order to compare the various experimental and theoretical results which have been obtained for an application to the O₂ atmospheric absorption and its photodissociation in the mesosphere and stratosphere. The different values of the oscillator strengths deduced from the laboratory absorption spectra and of the predissociation linewidths used for the calculation of the absorption have been compared.Calculations based on a Voight profile of the O₂ rotational lines have led to simple formulas for atmospheric applications taking into account that the total photodissociation rate in the stratosphere depends strongly on the absorption of solar radiation in the spectral range of the O₂ Herzberg continuum. Specific examples are given.     

The solar spectral irradiance and its action in the atmospheric photodissociation processes

A critical analysis has been made of solar irradiance in the spectral region covering wavelengths from 100 nm upwards; the absorption characteristics of molecules of oxygen and ozone have been taken into account with a view to the direct application of the results to atmospheric photochemistry. The absorption of radiation by these molecules results in the photodissociation of both of them in the homosphere, and it also makes possible the penetration of solar radiation from the thermosphere, through the mesosphere and the stratosphere, down to the troposphere.Special attention has been given to each of the following spectral regions: Lyman-alpha radiation at 121.6 nm, the O₂ Schumann-Runge continuum at wavelengths less than 175 nm, the O₂ Schumann-Runge band system from 200 to 175 nm, and the O₂ Herzberg continuum at 242.4 nm. For absorption by ozone, the solar spectrum has been analysed in the following regions: the Hartley band at wavelengths less than 310 nm, the Huggins bands at wavelengths above 310 nm and the visible Chappuis bands. Finally, for the photodissociation of O₃, particular attention has been given to the transition region (300–320 nm) in which there is a change-over from the production of the excited atom O(¹D) to that of the atom in its ground state O(³p).     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

Tracing of variabilities within a geological barrier by molecular organic geochemistry.: Case of the Callovo-Oxfordian sedimentary series in the East of the Paris Basin (France)

The Callovo-Oxfordian claystones located at 500 m depth at Bure (Meuse, France) are currently being investigated by Andra (the French National Radioactive Waste Management Agency) for testing the feasibility of long-term and deep geological nuclear waste disposal. In order to evaluate its potential as a geological barrier, it is very important to study, assess and describe its physico-chemical variability. The molecular biomarker composition of 150 samples of these claystones and their surrounding limestones carry diverse information on the sources of the sedimentary organic matter, the chemistry of the depositional environment, the preservation and diagenesis conditions. It also allows assessing the degree of lateral and vertical variability of the organic matter within these sedimentary series. The abundance of unsaturated biomarkers, the distribution of steroids and hopanoids and CPI values >2 prove the thermal immaturity of the organic matter. The co-occurrence of plankton, bacteria and land plant biomarkers indicate that the organic matter is a mixture of marine and continental contributions. The data also reveal that the organic matter was deposited under oxic and open-sea conditions except for a brief event of photic zone anoxia at the beginning of the Middle Callovian. In the claystones, the geosynthesis of diasterenes is favored to the detriment of the formation of steranes, especially in smectite-rich levels, and the organic matter is rapidly isolated from oxidizing then reducing conditions after the deposition due to the protective effect of clays. On the scale investigated, the claystones are characterized by a unique molecular facies and are thus homogenous from their organic content point of view. Yet, detailed investigation of specific molecular families indicates changes related to major claystone–limestone transitions. The homogeneity of these claystones can be explained by the paleogeographic position of their depositional setting and the plane and sub-horizontal paleotopography on which they were deposited. This study demonstrates the efficiency of organic geochemistry in the assessment of the variability of geological barriers.     

The Stannern trend eucrites: Contamination of main group eucritic magmas by crustal partial melts

We report on the petrology of a new eucrite belonging to the Stannern trend and discuss the origin of this trend. The eucrite Northwest Africa 4523 (NWA 4523) is an equilibrated eucrite consisting of dark clasts embedded in a fine-grained crystallized matrix. Two types of clasts have been observed: medium-grained ophitic/subophitic clasts, and very fine-grained clasts. Despite textural differences, the clasts display the same mineralogy, in particular the same kind of pyroxenes with pigeonitic cores containing sparse exsolution lamellae, and augitic rims, zoned plagioclases and the occurrence of K-feldspar. The major and trace element abundances of a large medium-grained clast are very similar to Stannern or Bouvante.The Stannern trend eucrites are characterized by high incompatible trace element abundances. Their trace element patterns normalized to a representative Main Group eucrite, exhibit significant Eu, Sr and Be negative anomalies. In this paper, we show that contamination of Main Group eucritic magmas by melts derived by partial melting of the asteroid’s crust can successfully explain both the high incompatible trace elements concentrations and the distinctive Eu, Sr, Be anomalies shown by the Stannern trend eucrites. This model is in agreement with the view that Stannern and some Main Group-Nuevo Laredo trend eucrites have been contemporaneously erupted, and with the probable assumption that Stannern trend eucrites formed rather late in the history of the 4-Vesta’s crust.     

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