The Ag/Au ratio of native gold and electrum and the geochemical environment of gold vein deposits in Japan

The chemical composition of native gold and electrum from auriferous vein and gold-silver vein deposits in Japan has been analyzed and summarized. The Ag/Au ratios of native gold and electrum from these two types of deposits are distinct, i.e., 10–20 Ag at % (auriferous vein) and 30–70 Ag at % (gold-silver vein). Thermochemical calculations suggest that the Ag/Au ratio of native gold and electrum should decrease with increasing chloride concentration and temperature. This is consistent with analytical results of native gold and electrum and fluid inclusion studies. Based on the Ag content of native gold and electrum, the Fe content of sphalerite, and the estimated temperatures, it is deduced that the sulfur activity for auriferous vein-type systems was lower than that of gold-silver vein-type systems.     

The use of sintered diamond anvils in the MA8 type high-pressure apparatus

A new multi-anvil type high-presure apparatus has been developed using sintered diamond anvils to generate pressures over 30 GPa and temperatures up to about 2000°C. A maximum sample volume of about 1 mm³ is available in this system. The pressure was confirmed by dissociation of forsterite into Mg-perovskite and periclase. The basic techniques and problems in utilizing sintered diamond in the MA8 type high-pressure apparatus are discussed with an emphasis on the future prospect of incorporating simultancous X-ray diffraction observation.     

Strong interaction between the ring system and the ionosphere of saturn

An abnormally low electron density in the Saturnian ionosphere observed by the radio occultation experiment of the Pioneer 11 may be explained in terms of the contamination of water in the Saturnian upper atmosphere from its ring system.     

The structure of cometary atmospheres

The temperature distributions in cometary atmospheres at various heliocentric distances for comets of Bennett and Encke types have been calculated by taking into account heating due to the absorption of solar ultraviolet radiation, cooling by H₂O far infrared emission, and various dynamical processes (expansion, advection, and thermal conduction). The agreement of the results with the observations is in general satisfactory. The conversion of CH₄ and NH₃ to CO and N₂ through thermochemical reaction with H₂O is concluded to be impossible, since the temperature is too low at a heliocentric distance 1.5 AU where CO⁺ ions begin to be observable.     

Spatial distribution of deuterium in atmospheric water vapor: Diagnosing sources and the mixing of atmospheric moisture

We measured the stable isotopic composition of hydrogen (δD) within atmospheric water vapor collected simultaneously at six sites in the vicinity of a lake (Lake Kasumigaura, Eastern Japan) to determine its spatial distribution characteristics and thereby diagnose sources and mixing of atmospheric moisture. The measured spatial distribution of δD showed no relation to distance from the lake, although it showed a correlation with the distribution of the water-vapor mixing ratio Q. For two of the three sampling days, we found a simple two-component (i.e., water vapor transpiring from local land surfaces and pre-existing vapor in the background atmosphere) mixing line in a Keeling plot (i.e., δ − 1/Q diagram). On a third day, however, contributions from lake evaporation were detected in addition to the above components. On this day, lake-derived vapor accounted for approximately 10-20% of atmospheric water vapor at the sites located leeward of the lake. The observed differences in mixing patterns among sampling days can be explained by a simple atmospheric moisture budget. Thus, it is likely that simultaneous isotopic measurements of atmospheric water vapor at multiple locations with aid of Keeling plot are capable of giving us useful information in diagnosing the sources and mixing pattern of the vapor.     

Tectono–Magmatic Evolution and Metallogenesis along the Northeast Jiangxi Deep Fault, China

Abstract: From the southernmost part of Jiangsu province to the northeastern part of Jiangxi province, China, the Northeast Jiangxi Deep Fault runs for about 400 km length with a width of 30 to 40 km. This fault marks the suture zone of two ter-ranes of Proterozoic age. At the both sides of the fault, Yanshanian granitic activity is recognized. That is, the Dexing-Wuyuan porphyry belt on the NW side of the fault, and the Damaoshan-Lingshan granite belt on the SE side. The former activity is characterized by the occurrence of small stocks of granodioritic composition, rich in siderophile elements but poor in LIL elements. No distinct Eu anomaly is recognized in the REE pattern, and a low initial ⁸⁷Sr/⁸⁶Sr ratio is reported. Magnetite, sphene and apatite are observed as accessory minerals. On the contrary, granitic activity on the SE side of the fault is characterized by the occurrence of composite batholiths, in general of granitic to monzogranitic composition, rich in LIL and alkali elements but poor in siderophile and alkali earth elements. A strong Eu anamaly is recognized in the REE pattern, and initial ⁸⁷Sr/⁸⁶Sr ratios are as high as 0. 716. Fluorite, zircon and REE minerals are observed as accessory minerals. These two contrasting granitic activities are refered to as syntexis– and transformation–types, respectively, following the classification commonly used in China, and have similar petrochemical characteristics to those defined for the magnetite– and ilmenite–series, and I– and S-type granitoids. Considering that the above igneous activity occurred far from the supposed subduction zone along the East Coast of China, intracontinental A-type (continent to continent) subduction is proposed to have occurred northwestwards along the NE Jiangxi Deep Fault during Yanshanian time due to a strong compressional stress from SE to NW. A-type subduction introduced the continental slab to some depth, and resulted in the production of the paired granitic activity observed on both sides of the fault. Many mineral deposits are associated with both granitic belts. In the Dexing-Wuyuan porphyry belt, the Dexing porphyry Cu and Yinshan polymetallic deposits are representative, whereas in the Damaoshan-Lingshan granite belt, several tens of rare metal deposits are known such as the Geyuan Nb–Ta–W–Sn deposits. Metal assemblages of those deposits reflect the source materials of magmas in both granitic belts.     

An experimental study of the partitioning of K,Rb, Cs,Sr and Ba between clinopyroxene and liquid at high pressures

The partition coefficients of K, Rb, Cs, Sr and Ba between clinopyroxene and liquid were experimentally determined in the system diopside-albite-anorthite-water at 15–30 kb and 1100–1200°C. Clinopyroxene and liquid (glass) were separated by a new technique (differential dissolution technique—DDT) and analyzed by isotope dilution. The partition coefficients lie in the range 0.054–0.081 for Sr, 0.0014–0.0026 for K, 0.00078–0.0023 for Ba, 0.0010–0.0041 for Rb, 0.00035–0.0036 for Cs. Variations of the partition coefficients with pressure, temperature and composition of the phases are relatively small, though no systematic study of these parameters was attempted.     

Japanese early-warning for debris flows and slope failures using rainfall indices with Radial Basis Function Network

Early-warning systems for natural disasters are important tools for disaster risk reduction and for achieving sustainable development and livelihoods. In 2005, the Japanese government initiated a new nationwide early-warning system for landslides disasters. The main methodology of the system is to set a criterion for occurrences of debris flows and slope failures based on several rainfall indices (60-min cumulative rainfall and soil–water index) in each 5-km grid mesh covering all of Japan. Because many of the records of mass movements are lacking in scientific precision on timing and location, the system applies Radial Basis Function Network methods to set the criterion based primarily on rainfall data recorded as not triggering disasters. Since the end of March 2007, under torrential rainfall conditions, early-warning information has been disseminated as part of weather news using TV, radio, and the Internet. Because of the increasing worldwide recognition of the importance of early-warning systems for natural disaster reduction, the aim of this article is to introduce the new Japanese early-warning system to the international landslide community. In this article, the method, the system, and the result of its application to landslide disasters in 2009 are presented.     

http://www.sciencedirect.com/science/article/pii/S1674987114000917

Important ecological changes of the Earth(oxidization of the atmosphere and the ocean) increase in nutrient supply due to the break-up of the super continent(Rodinia) and the appearance of multi-cellular organisms(macroscopic algae and metazoan) took place in the Ediacaran period,priming the Cambrian explosion.The strong perturbations in carbon cycles in the ocean are recorded as excursions in carbonate and organic carbon isotope ratio(δ~(13)C_(carb) and δ~(13)C_(org)) from the Ediacaran through early Cambrian periods.The Ediacaran-early Cambrian sediment records of δ~(13)C_(carb) and δ~(13)C_(org),obtained from the drill-core samples in Three Gorges in South China,are compared with the results of numerical simulation of a simple one-zone model of the carbon cycle of the ocean,which has two reservoirs(i.e.,dissolved organic carbon(DOC) and dissolved inorganic carbon(DIC).The fluxes from the reservoirs are assumed to be proportional to the mass of the carbon reservoirs.We constructed a model,referred to here as the Best Fit Model(BFM),which reproduce δ~(13)C_(carb) and δ~(13)C_(org) records in the Ediacaran-early Cambrian period noted above.BFM reveals that the Shuram excursion is related to three major changes in the carbon cycle or the global ecological system of the Earth:(1) an increase in the coefficient of remineralization by a factor of ca.100,possibly corresponding to a change in the dominant metabolism from anaerobic respiration to aerobic respiration,(2) an increase of carbon fractionation index from 25‰ to 33‰,possibly corresponding to the change in the primary producer from rock-living cyanobacteria to free-living macro algae,and(3) an increase in the coefficient of the organic carbon burial by a factor of ca.100,possibly corresponding to the onset of a biological pump driven by the flourishing metazoan and zooplankton.The former two changes took place at the start of the Shuram excursion,while the third occurred at the end of the Shuram excursion.The other two excursions are explained by the tentative decrease in primary production due to cold periods,which correspond to the Gaskiers(ca.580 Ma) and Bikonor(ca.542 Ma) glaciations.     

Seasonal changes of the South American monsoon system during the Mid-Holocene in the CMIP5 simulations

The South American Monsoon System (SAMS) is a major climatic feature of South America, and its domain extends from Amazon to La Plata basin. The SAMS region is vulnerable to variations of climate and precipitation patterns, which could impact economic activities and lead to potential societal consequences. In the face of a warming future scenario, the importance of the study of the past climate with numerical simulations is to evaluate the climate models and to assure the reliability of future projections. Here we investigate the Mid-Holocene SAMS, evaluating changes in strength, life cycle and associated dynamical mechanisms in ten Earth System Models simulations. Our results show that the SAMS was weaker in the Mid-Holocene than in the pre-industrial climate in December–January–February (DJF), but stronger in September–October–November (SON). This is probably a consequence of insolation variations in the Mid-Holocene, which contributed to changes in the moisture flux from the Atlantic Ocean to the continent, the strength of the upper-level atmospheric circulation, and the amount of precipitation over the SAMS region. Moreover, we suggest that the life cycle of the SAMS was altered during the Mid-Holocene, with an earlier onset and demise. Our results also indicate that Mid-Holocene SAMS changes are connected to precipitation variations near Northeast Brazil, in a dipole configuration of precipitation between western Amazon and Northeast Brazil, due to the influence of the Walker cell. Finally, this study highlights a need for improvement of the numerical models to better simulate the amount of precipitation over South America and the upper-level circulation over western Amazon in SON, which are crucial factors for a more realistic representation of the SAMS.