Lead orthophosphates—III. Stabilities of fluoropyromorphite and bromopyromorphite at 25°C

The reactions of secondary lead orthophosphate with approximately 10^?1 M sodium fluoride and sodium bromide solutions have been investigated at 25°C. Interpretation of the solubility data resulted in solubility product constants for fluoropyromorphite and bromopyromorphite of 10^?71.6 and 10^?78.1, respectively. According to these constants, the stability sequence for lead pyromorphites is Pb₅(PO₄)₃Cl > Pb₅(PO₄)₃Br > Pb₅(PO₄)₃OH > Pb₅(PO₄)₃F. The derived free energy data have been used to evaluate the respective stabilities of fluoro-pyromorphite and bromopyromorphite within the systems PbF₂-PbO-P₂O₅-H₂O and PbBr₂-PbO-P₂O₅-H₂O and to predict the equilibrium behavior of the Pb₅(PO₄)₃F-Pb₅(PO₄)₃OH solid solution under aqueous conditions.     

Luna 20: mineralogy and petrology of fragments less than 125 μm size

Two milligrams of less than 125 μm size particles from the Luna 20 soil sample (22001,17) have been examined. The results of the mineral identification and analysis verify earlier assumptions that the nature of the lunar highlands is predominantly anorthositic in composition. The presence of highly magnesian clinopyroxene, orthopyroxene and olivine suggests crystallization of Highland rocks in an ultrabasic environment. No fragments were observed that could be unequivocally assigned to mare basalt types.     

More on noble gases in Yellowstone National Park hot waters

Water and gas samples from research wells in hydrothermal areas of Yellowstone National Park, U.S.A., have been mass spectrometrically analyzed for their rare gas contents and isotopic composition. In agreement with previous findings, the rare gases have been found to originate from infiltrating run-off water, saturated with air at 10 to 20°C. The atmospheric rare gas retention values found for the water varied between 3 and 87 per cent. The fine structure of the Ar, Kr and Xe abundance pattern in the water reveals fraotionational enrichment of the heavier gases due to partial outgassing of the waters. Radiogenic He and Ar have been detected. No positive evidence for magmatic water contribution has been found. Nevertheless, additions of magmatic waters free of rare gas can not be excluded, but if present the proportion is significantly less than 13 to 36 per cent.     

Sillimanite—disordering enthalpy by calorimetry

Heat of solution measurements in an oxide-melt were performed on samples of natural sillimanite heat-treated in the range 1200–1700°C at pressures of 16–23 kbar. A distinct enthalpy of solution decrement relative to the unheated sillimanite of about 1.3 kc/mole is shown by samples run at 1400–1550°C. Pressure variations in the range 16–23 kbar cause little change in the heat of solution in this temperature range. This pressure-independent ‘plateau’ in heat of solution is interpreted to be due to Al-Si disordering on tetrahedral sites in the sillimanite structure. A simple temperature-dependent disordering model developed by navrotsky and Kleppa (1967) for spinels leads to an Al-Si interchange enthalpy, Δ_Hnt, of16 ± 1 kcal/mole, in good agreement with the value derived by Holdaway(1971) on entirely different grounds.Above 1550°C, larger heat of solution decrements were observed. Microprobe analyses of quenched samples indicate that the sillimanite has not deviated significantly from the ideal formula. Some unknown profound disordering process may account for the heat effects in the very high temperature range.Unit cell volumes of quenched samples also describe a ‘plateau’ region in the temperature range 1400–1550°C. This plateau consists of an increase of the 6 crystallographic axis beginning at 1350°C without much change in the other axes in the range 1350–1550°C. A sudden expansion of the α-axis occurs between 1550 and 1630°C.We conclude that Al-Si disorder of the type postulated by Beger et al. (1970), and Holdaway (1971) has been confirmed calorimetrically for samples heated under pressure in the temperature range 1400–1550°C.     

Effect of chelation on toxicity of copper

Metals in the sea may form complexes with organic compounds, a process known as chelation, and this may modify their properties very greatly. Here the effect of chelation on the toxicity of copper to algae has been studied in the laboratory using the powerful chelating agent EDTA. Similar phenomena in the sea have implications both for anti-fouling paints, which usually contain copper, and for metal pollution in waters with a high organic content.     

The genesis of basaltic magmas

This paper reports the results of a detailed experimental investigation of fractionation of natural basaltic compositions under conditions of high pressure and high temperature. A single stage, piston-cylinder apparatus has been used in the pressure range up to 27 kb and at temperatures up to 1500° C to study the melting behaviour of several basaltic compositions. The compositions chosen are olivine-rich (20% or more normative olivine) and include olivine tholeiite (12% normative hypersthene), olivine basalt (1% normative hypersthene) alkali olivine basalt (2% normative nepheline) and picrite (3% normative hypersthene). The liquidus phases of the olivine tholeiite and olivine basalt are olivine at 1 Atmosphere, 4.5 kb and 9 kb, orthopyroxene at 13.5 and 18 kb, clinopyroxene at 22.5 kb and garnet at 27 kb. In the alkali olivine basalt composition, the liquidus phases are olivine at 1 Atmosphere and 9 kb, orthopyroxene with clinopyroxene at 13.5 kb, clinopyroxene at 18 kb and garnet at 27 kb. The sequence of appearance of phases below the liquidus has also been studied in detail. The electron probe micro-analyser has been used to make partial quantitative analyses of olivines, orthopyroxenes, clinopyroxenes and garnets which have crystallized at high pressure.These experimental and analytical results are used to determine the directions of fractionation of basaltic magmas during crystallization over a wide range of pressures. At pressures corresponding to depths of 35–70 km separation of aluminous enstatite from olivine tholeiite magma produces a direct fractionation trend from olivine tholeiites through olivine basalts to alkali olivine basalts. Co-precipitation of sub-calcic, aluminous clinopyroxene with the orthopyroxene in the more undersaturated compositions of this sequence produces derivative liquids of basanite type. Magmas of alkali olivine basalt and basanite type represent the lower temperature liquids derived by approximately 30% crystallization of olivine-rich tholeiite at 35–70 km depth. At depths of about 30 km, fractionation of olivine-rich tholeiite with separation of both olivine and low-alumina enstatite, joined at lower temperatures by sub-calcic clinopyroxene, leads to derivative liquids with relatively constant SiO₂ (48 to 50%) increasingly high Al₂O₃ (15–17%) contents and retaining olivine + hypersthene normative chemistry (5–15% normative olivine). These have the composition of typical high-alumina olivine tholeiites. The effects of low pressure fractionation may be superimposed on magma compositions derived from various depths within the mantle. These lead to divergence of the alkali olivine basalt and tholeiitic series but convergence of both the low-alumina and high-alumina tholeiites towards quartz tholeiite derivative liquids.The general problem of derivation of basaltic magmas from a mantle of peridotitic composition is discussed in some detail. Magmas are considered to be a consequence of partial melting but the composition of a magma is determined not by the depth of partial melting but by the depth at which magma segregation from residual crystals occurs. Magma generation from parental peridotite (pyrolite) at depths up to 100 km involves liquid-crystal equilibria between basaltic liquids and olivine + aluminous pyroxenes and does not involve garnet. At 35–70 km depth, basaltic liquids segregating from a pyrolite mantle will be of alkali olivine basalt type with about 20% partial melting but with increasing degrees of partial melting, liquids will change to olivine-rich tholeiite type with about 30% melting. If the depth of magma segregation is about 30 km, then magmas produced by 20–25% partial melting will be of high-alumina olivine tholeiite type, similar to the oceanic tholeiites occurring on the sea floor along the mid-oceanic ridges.Hypotheses of magma fractionation and generation by partial melting are considered in relation to the abundances and ratios of trace elements and in relation to isotopic abundance data on natural basalts. It is shown that there is a group of elements (including K, Ti, P, U, Th, Ba, Rb, Sr, Cs, Zr, Hf and the rare-earth elements) which show enrichment factors in alkali olivine basalts and in some tholeiites, which are inconsistent with simple crystal fractionation relationships between the magma types. This group of elements has been called incompatible elements referring to their inability to substitute to any appreciable extent in the major minerals of the upper mantle (olivine, aluminous pyroxenes). Because of the lack of temperature contrast between magma and wall-rock for a body of magma near to its depth of segregation in the mantle, cooling of the magma involves complementary processes of reaction with the wall-rook, including selective melting and extraction of the lowest melting fraction. The incompatible elements are probably highly concentrated in the lowest melting fraction of the pyrolite. The production of large overall enrichments in incompatible elements in a magma by reaction with and highly selective sampling of large volumes of mantle wall-rock during slow ascent of a magma is considered to be a normal, complementary process to crystal fractionation in the mantle. This process has been called wall-rock reaction. Magma generation in the mantle is rarely a simple, closed-system partial melting process and the isotopic abundances and incompatible element abundances of a basalt as observed at the earth's surface may be largely determined by the degree of reaction with the mantle or lower crustal wall-rocks and bear little relation to the abundances and ratios of the original parental mantle material (pyrolite).Occurrences of cognate xenoliths and xenocrysts in basalts are considered in relation to the experimental data on liquid-crystal equilibria at high pressure. It is inferred that the lherzolite nodules largely represent residual material after extraction of alkali olivine basalt from mantle pyrolite or pyrolite which has been selectively depleted in incompatible elements by wall-rock reaction processes. Lherzolite nodules included in tholeiitic magmas would melt to a relatively large extent and disintegrate, but would have a largely refractory character if included in alkali olivine basalt magma. Other examples of xenocrystal material in basalts are shown to be probable liquidus crystals or accumulates at high pressure from basaltic magma and provide a useful link between the experimental study and natural processes.     

Effect of Aftershocks on Earthquake Hazard Estimation: An Example from the North Anatolian Fault Zone

In order to investigate the effect of aftershocks on earthquake hazard estimation, earthquake hazard parameters (_m, b and M_max) have been estimated by the maximum likelihood method from the main shocks catalogue and the raw earthquakes catalogue for the North Anatolian Fault Zone (NAFZ). The main shocks catalogue has been compiled from the raw earthquake catalogue by eliminating the aftershocks using the window method. The raw earthquake catalogue consisted of instrumentally detected earthquakes between 1900 and 1992, and historical earthquakes that occurred between 1000–1900. For the events of the mainshock catalogue the Poisson process is valid and for the raw earthquake catalogue it does not fit. The paper demonstrates differences in the hazard outputs if on one hand the main catalogues and on the other hand the raw catalogue is used. The maximum likelihood method which allows the use of the mixed earthquake catalogue containing incomplete (historical) and complete (instrumental) earthquake data is used to determine the earthquake hazard parameters. The maximum regional magnitude (M_max, the seismic activity rate (_m), the mean return period (R) and the b value of the magnitude-frequency relation have been estimated for the 24°–31° E, 31°–41° E, 41°–45° E sections of the North Anatolian Fault Zone from the raw earthquake catalogue and the main shocks catalogue. Our results indicate that inclusion of aftershocks changes the b value and the seismic activity rate _m depending on the proportion of aftershocks in a region while it does not significantly effect the value of the maximum regional magnitude since it is related to the maximum observed magnitude. These changes in the earthquake hazard parameters caused the return periods to be over- and underestimated for smaller and larger events, respectively.     

Natural hazards in British Columbia: an interdisciplinary and inter-institutional challenge

 Although British Columbia experiences many natural hazards, there is as yet no unified policy to promote natural hazard management in the province. The problem is not in the quantity and quality of geoscience assessment of natural hazards, but instead, it is suggested, in the isolation of that work from broader risk perspectives and in the lack of clarity of division of responsibilities between various levels of government. The example of recent changes in perception of the terrain stability problem illustrates how natural hazard problems are driven by social and political priorities rather than by geoscience priorities. Received: 22 November 1998 / Accepted: 22 November 1998     

On the move: explaining migration patterns in Estonia during the transition period

This paper attempts to explore the migration patterns during the transition period in Estonia. A structuration approach was used to analyze data from the Estonian Statistical Office collected in 1997. Findings show that for migration between urban and rural areas, work-related reasons have been the most important motivating factor in urban growth during the transition period. Also considered are the family and education. In relation to sociodemographic structure of the population, men cite work, while women count family-related reasons, as the main motive for migrating. As to nonregistration, the most significant reason relates to issues of ownership. Because migrants are living in rented housing, it is not possible for them to register even if they desire to do so. Other reasons include "temporary", associated with study and work; "juridical", bureaucratic matters; and "multiple places of residence". This analysis, however, is incomplete because the attitudes and patterns of behavior have only partially or perfunctorily been related to the dramatic changes that have occurred in Estonian society. Proper statistical data are needed to help examine trends at a more disaggregated spatial level.     

Stepwise mass extinctions: the case for the Late Cenomanian event

The various extinctions of marine taxa in the Late Cenomanian can be shown as conforming to the 'step-wise extinction' model. The order of such extinctions is, however, compatible with the presence of an expanded oxygen minimum zone in the world ocean. The occurrence of iridium anomalies at this level in the succession may, however, indicate a volcanogenic control on the global environment. Detailed time-analysis of the Late Cenomanian event has been used to produce a correlation of some key successions.