Laboratory measurement of P-wave velocity in crustal and upper mantle xenoliths from Ichino-megata, NE Japan: ultrabasic hydrous lower crust beneath the NE Honshu arc

Ultrasonic laboratory measurements of P-wave velocity (Vp) were carried out up to 1.0 GPa in a temperature range of 25–400 °C for crustal and mantle xenoliths of Ichino-megata, northeast Japan. The rocks used in the present study cover a nearly entire range of lithological variation of the Ichino-megata xenoliths and are considered as representative rock samples of the lower crust and upper mantle of the back arc side of the northeast (NE) Honshu arc. The Vp values measured at 25 °C and 1.0 GPa are 6.7–7.2 km/s for the hornblende gabbros (38.6–46.9 wt.% SiO₂), 7.2 km/s for the hornblende-pyroxene gabbro (43.8 wt.% SiO₂), 6.9–7.3 km/s for the amphibolites (36.1–44.3 wt.% SiO₂), 8.0–8.1 km/s for the spinel lherzolites (46.2–47.2 wt.% SiO₂) and 6.30 km/s for the biotite granite (72.1 wt.% SiO₂). Combining the present data with the Vp profile of the NE Honshu arc [Iwasaki, T., Kato, W., Moriya, T., Hasemi, A., Umino, N., Okada, T., Miyashita, K., Mizogami, T., Takeda, T., Sekine, S., Matsushima, T., Tashiro, K., Miyamachi, H. 2001. Extensional structure in northern Honshu Arc as inferred from seismic refraction/wide-angle reflection profiling. Geophys. Res. Lett. 28 (12), 2329–2332], we infer that the 15 km thick lower crust of the NE Honshu arc is composed of amphibolite and/or hornblende (±pyroxene) gabbro with ultrabasic composition. The present study suggests that the Vp range of the lower crustal layer (6.6–7.0 km/s) in the NE Honshu arc, which is significantly lower than that obtained from various seismic measurements (e.g. the northern Izu-Bonin-Mariana arc: 7.1–7.3 km/s), is due to the thick hydrous lower crustal layer where hornblende, plagioclase and magnetite are dominant.     

Evaluations of subsurface flow for reconstructions of climate change using borehole temperature and isotope data in Kamchatka

Subsurface temperature is affected by heat advection due to groundwater flow and surface temperature changes. To evaluate their effects, it was implemented the measurements of temperature-depth profile (T-D profile) and the continuous monitoring of soil temperature in the southern part of Kamchatka which has not affected by human activity. Additionally, stable isotopic compositions of surface water and groundwater were analyzed. T-D profile and stable isotopic compositions show groundwater flow system is differ from the shallow aquifer to the deep aquifer. In the shallow aquifer, T-D profile suggests the existence of upward groundwater flux. On the other hand, the annual variation of soil temperature is divided into the large variation period (VP) and the stable period (SP) by the magnitude of daily and seasonal variation. VP and SP correspond to the summer and the winter season, respectively, and it considers that the difference between VP and SP is caused by the effect of snow cover. Therefore, the T-D profile is affected by not only upward groundwater flux but also the surface warming particularly in the summer season (VP).     

Extending Multivariate Space-Time Geostatistics for Environmental Data Analysis

Environmental studies require multivariate data such as chemical concentrations with space-time coordinates. There are two general conditions related to such data: the existence of correlations among the coregionalized variables and the differences in numbers of data which occur because of insufficient data caused by measurement error or bad weather conditions. This study proposes geostatistical techniques for space-time multivariate modeling that take into consideration these correlations and data absences. These techniques consist of suitable modeling of semivariograms and cross-semivariograms for quantifying correlation structures among multivariables and of extending standardized ordinary cokriging. The tensor product cubic smoothing surface method is used for space-time semivariogram modeling. These methods are applied to the chemical component data of the Ariake Sea, a typical closed sea in southwest Japan. In order to clarify environmental changes in the Ariake Sea, the concentration data of four nutritive salts (NO₂–N, NO₃–N, NH₄–N, and PO₄–P) at 38 stations over 25 years are used as environmental indicators. For each of the kinds of data, there are spaces and times for which there is no data available. The effectiveness of the modeling of space-time semivariograms and the high estimation capability of the extended cokriging are demonstrated by cross-validation. Compared with ordinary kriging for a single variable, multivariate space-time standardized ordinary cokriging can provide a more detailed concentration map of nutritive salts and while elucidating their temporal changes over sparsely spaced data areas. In the space-time models by ordinary kriging, on the other hand, smooth trends are obvious.     

Formation of Distinct Granitic Magma Batches by Partial Melting of Hybrid Lower Crust in the Izu Arc Collision Zone, Central Japan

The Miocene Kofu Granitic Complex (KGC) occurs in the Izu CollisionZone where the Izu–Bonin–Mariana (IBM) arc has beencolliding with the Honshu arc since the middle Miocene. TheKGC includes rocks ranging in compositions from biotite-bearinggranite (the Shosenkyo and Mizugaki plutons), and hornblende–biotite-bearinggranodiorite, tonalite, quartz-diorite, and granite (the Shiodaira,Sanpo, Hirose and Sasago plutons), to hornblende-bearing tonaliteand trondhjemite (the Ashigawa–Tonogi pluton), indicatingthat it was constructed from multiple intrusions of magma withdifferent bulk chemistry. The Sr-isotopic compositions correctedto sensitive high-resolution ion microprobe (SHRIMP) zirconages (SrI) suggest that the primary magmas of each pluton wereformed by anatexis of mixed lower crustal sources involvingboth juvenile basalt of the IBM arc and Shimanto sedimentaryrocks of the Honshu arc. After the primary magmas had formed,the individual plutons evolved by crystal fractionation processeswithout significant crustal assimilation or additional mantlecontribution. SHRIMP zircon U–Pb ages in the KGC rangefrom 16·8 to 10·6 Ma and overlap the resumptionof magmatic activity in the IBM and Honshu arcs at c. 17 Maand the onset of IBM arc–Honshu arc collision at c. 15Ma. The age of the granite plutons is closely related to theepisodic activity of arc magmatism and distinct granitic magmabatches could be formed by lower crustal anatexis induced byintrusion of underplated mantle-derived arc magmas. Based onpressures determined with the Al-in-hornblende geobarometer,the KGC magmas intruded into the middle crust. Thus, the KGCcould represent an example of the middle-crust layer indicatedthroughout the IBM arc by 6·0–6·5 km/s seismicvelocities. This granitic middle-crust layer acted buoyantlyduring the IBM arc–Honshu arc collision, leading to accretionof buoyant IBM arc middle crust to the Honshu arc. KEY WORDS: arc–arc collision; crustal anatexis; granite; Izu–Bonin–Mariana (IBM) arc; Izu Collision Zone     

Groundwater-derived nutrient inputs to the Upper Gulf of Thailand

We report here the first direct measurements of nutrient fluxes via groundwater discharge into the Upper Gulf of Thailand. Nutrient and standard oceanographic surveys were conducted during the wet and dry seasons along the Chao Phraya River, Estuary and out into the Upper Gulf of Thailand. Additional measurements in selected near-shore regions of the Gulf included manual and automatic seepage meter deployments, as well as nutrient evaluations of seepage and coastal waters. The river transects characterized the distribution of biogeochemical parameters in this highly contaminated urban environment. Seepage flux measurements together with nutrient analyses of seepage fluids were used to estimate nutrient fluxes via groundwater pathways for comparison to riverine fluxes.     

Correction: Impact of excessive groundwater pumping on rejuvenation processes in the Bandung basin (Indonesia) as determined by hydrogeochemistry and modeling

In the Bandung basin, Indonesia, excessive groundwater pumping caused by rapid increases in industrialization and population growth has caused subsurface environmental problems, such as excessive groundwater drawdown and land subsidence. In this study, multiple hydrogeochemical techniques and numerical modeling have been applied to evaluate the recharge processes and groundwater age (rejuvenation). Although all the groundwater in the Bandung basin is recharged at the same elevation at the periphery of the basin, the water type and residence time of the shallow and deep groundwater could be clearly differentiated. However, there was significant groundwater drawdown in all the depression areas and there is evidence of groundwater mixing between the shallow and deep groundwater. The groundwater mixing was traced from the high dichlorodifluoromethane (CFC-12) concentrations in some deep groundwater samples and by estimating the rejuvenation ratio (R) in some representative observation wells. The magnitude of CFC-12 concentration, as an indicator of young groundwater, showed a good correlation with R, determined using ¹⁴C activity in samples taken between 2008 and 2012. These correlations were confirmed with the estimation of vertical downward flux from shallower to deeper aquifers using numerical modeling. Furthermore, the change in vertical flux is affected by the change in groundwater pumping. Since the 1970s, the vertical flux increased significantly and reached approximately 15% of the total pumping amount during the 2000s, as it compensated the groundwater pumping. This study clearly revealed the processes of groundwater impact caused by excessive groundwater pumping using a combination of hydrogeochemical methods and modeling.

     

Experimental evidence on formation of imminent and short-term hydrochemical precursors for earthquakes

The formation of imminent hydrochemical precursors of earthquakes is investigated by the simulation for water–rock reaction in a brittle aquifer. Sixty-one soaking experiments were carried out with granodiorite and trachyandesite grains of different sizes and three chemically-distinct waters for 6 to 168 h. The experimental data demonstrate that water–rock reaction can result in both measurable increases and decreases of ion concentrations in short times and that the extents of hydrochemical variations are controlled by the grain size, dissolution and secondary mineral precipitation, as well as the chemistry of the rock and groundwater. The results indicate that water–rock reactions in brittle aquifers and aquitards may be an important genetic mechanism of hydrochemical seismic precursors when the aquifers and aquitards are fractured in response to tectonic stress.