REE abundances in the matrix of the Allende (CV) meteorite: Implications for matrix origin

Abstract— The trace element distributions in the matrix of primitive chondrites were examined using four least‐contaminated matrix specimens from the polished sections of the Allende (CV) meteorite. Analysis of rare earth element (REE), Ba, Sr, Rb, and K abundances by isotope dilution mass spectrometry revealed that the elemental abundances of lithophile elements except for alkali metals (K, Rb) in the specimens of the Allende matrix studied here are nearly CI (carbonaceous Orgueil) chondritic (～1 × CI). Compared to refractory elements, all the matrix samples exhibited systematic depletion of the moderately volatile elements K and Rb (0.1–0.5 × CI). We suggest that the matrix precursor material did not carry significant amounts of alkali metals or that the alkalis were removed from the matrix precursor material during the parent body process and/or before matrix formation and accretion. The matrix specimens displayed slightly fractionated REE abundance patterns with positive Ce anomalies (CI‐normalized La/Yb ratio = 1.32–1.65; Ce/Ce* = 1.16–1.28; Eu/Eu* = 0.98–1.10). The REE features of the Allende matrix do not indicate a direct relationship with chondrules or calcium‐aluminum‐rich inclusions (CAIs), which in turn suggests that the matrix was not formed from materials produced by the breakage and disaggregation of the chondrules or CAIs. Therefore, we infer that the Allende matrix retains the REE features acquired during the condensation process in the nebula gas.     

GAME-TIBET青藏高原云和降水综合观测概况及初步结果

对中日合作青藏高原能量水分循环试验项目中云和降水的多普勒雷达观测使用的气象观测仪器和获取的资料等情况进行了总结,并给出了那曲地区水的日变化,不同 雨量计测量降水的对比分析,风速对测量降水影响,多普勒雷达资料的个例分析及云的数值模拟的等初步结果。     

Analysis of runoff–storage relationships to evaluate the runoff-buffering potential of a sloping permeable domain

The runoff–storage relationship for a runoff system in a steady-state is analyzed as an indicator of the buffering potential of rainfall-runoff responses. In this relationship, a large storage increase in response to a given runoff increase indicates high buffering potential in the water balance equation. The evaluation method is applied to a sloping permeable domain. A two-dimensional form of the Richards equation is used to calculate runoff and storage. Macropore existence is represented by an enlargement effect of hydraulic conductivity near saturation. The runoff–storage relationship is controlled by the distribution of hydraulic quantities. The distribution of a pressure-head value is approximately classified into the following three zones: the I zone with vertical unsaturated flow, the U zone with unsaturated downslope flow, and the S zone with saturated downslope flow. The runoff-buffering potential is systematically evaluated by dependencies of the runoff–storage relationship on the classification of the pressure-head distribution. The potential is generally high for soil with a high permeability, but rather small in the range of low runoff rates where the S zone is not created. The macropore effect causes the range of high buffering potential to shift to high runoff rates through enlargement of the I zone. As a result, a moderate magnitude of the macropore effect gives the maximum increase in storage in response to a given increase in runoff.     

Activity Profile of the Sextantid Meteor Shower

The detailed activity profile of the Sextandids - one of the day-time meteor showers - is poorly known and still unclear. Using the forward-scatter radio technique we have successfully been able to obtain further detailed overall activity profile of the Sextantids for seven consecutive years: 1991–1997. Analysis confirmed the Sextantid activity duration in solar longitude (J2000) of at least 184–193° and the maximum solar longitude at 188.35 ± 0.10° with a full width at half maximum (FWHM) of 2.0 ± 0.2°. Performing the numerical integrations, we also substantiated a possibility of the association between Apollo-type asteroid (3200) Phaethon and the Sextantids. Furthermore, we roughly estimated relative maximum flux rate of Sextantids : Geminids as 1 : 3 amplitude ratio. Depending upon the flux rates and the time lags of the orbital evolution with Phaethon, we conclude that the Sextantids are at a more progressive stage of orbital evolution than the Geminids if both meteor streams are really associated with Phaethon. This revised version was published online in July 2006 with corrections to the Cover Date.     

Mass distribution of Antarctic ordinary chondrites and the estimation of the fall-to-specimen ratios

Abstract— The cumulative mass distributions (mass range > 100 g) of each type of Japanese and U.S. Antarctic ordinary chondrites are compared with those of non-Antarctic falls and those obtained from the present-day flux of meteorites. The steeper slope of the mass distribution of Antarctic chondrites is indicative of the presence of several chondrite showers. The fall-to-specimen ratio of Antarctic ordinary chondrites larger than 100 g is about 1:2, indicating that half of them are shower components. The fall-to-specimen ratios of each group range from 1:1 to 1:6; those of the Japanese and U.S. Antarctic meteorite collections are 1:1 to 1:2 and 1:4 for H chondrites, 1:1 to 1:2 and 1:2 for L chondrites, and 1:2 and 1:6 for LL chondrites, indicating that the Japanese collection includes less abundant shower components than the U.S. collection. The fall-to-specimen ratios of each H4-6 and L4-6 type range from 1:1 to 1:4, and U.S. H6 and Japanese H4 have the low ratios of 1:4.     

Deterioration of eelgrass,Zostera marina L., meadows by water pollution in Seto Inland Sea,Japan

Survival of transplanted Zostera marina L. (eelgrass) and environmental conditions (water quality, bottom sediments, sedimentation on leaves and flow regime) were studied concurrently in the center, edge, and at the outside of a eelgrass meadow located in a eutrophic coastal zone in northern Hiroshima Bay, Seto Inland Sea, Japan. Eelgrass transplants at the outside of the meadow declined significantly, whereas those at the center were consistently well established. Silt content in the bottom sediments at the outside was higher than that at the center. The sediment was oxic from the surface to 2 cm deep at the center, whereas those at the edge and the outside were reductive almost from the surface. The sediment characteristics typical in eutrophic water seemed to be a factor responsible for the deterioration of eelgrass meadows. Although suspended solid concentrations in the water columns were almost the same, the amount of sediments deposited on leaves of eelgrass at the outside was higher than that at the center of the meadow. The amount of the deposition at the outside seems to be enough to inhibit photosynthesis; i.e. photosynthetic photon flux density (PPFD) available for eelgrass was only 36% of that without any deposition. The deposition in the center, however, was small enough to allow 84% of the original PPFD. Flow rates, determined at 30 cm above the bottom, a half height of average eelgrass, suggested that the rate at the outside was not enough to remove deposited sediments from the surface of eelgrass leaves. Thus, the large amount of sediment deposition caused by water pollution and/or eutrophication seemed to be another factor to inhibit the survival of eelgrass at the outside edge of the meadow.     

Long-term monitoring of the temperature profile in a deep borehole: Temperature variations associated with water injection experiments and natural groundwater discharge

Long-term temperature monitoring was carried out in a borehole drilled for investigation of the Nojima fault, an active fault in SW Japan, using the distributed optical fiber temperature sensing (DTS) technique. Temperatures in the borehole had been measured every 1 m along an optical fiber cable with a resolution of about 0.1 K over a period of 6 years. Water injection experiments were conducted in this borehole in 1997, 2000 and 2003. Monitoring of the temperature profile was started after the first injection experiment, and the temperature profile remained very stable until the start of the second injection experiment. During the second and third experiments, the temperatures in the borehole dropped due to cooling by the injected water but no appreciable temperature change was observed below about 580 m. It clearly shows that the water leaked out of the hole around this point and the leaking depth is estimated to be about 540 m based on the shape of the temperature profile. After the injection was stopped, the recovery of the temperature to the undisturbed profile was exceptionally slow around the leaking point, resulting in a local temperature anomaly, probably because the water leaking out of the hole had cooled the surrounding formations extensively. A very similar temperature anomaly was observed at the beginning of temperature monitoring, which suggests that water leaked out at the same depth in the first injection experiment as well. Between the second and third injection experiments, the top of the borehole was kept open to allow groundwater discharge for about 1 month in 2000 and 2003. In both periods, groundwater flowed out continuously and the shapes of the observed temperature profiles indicate that the groundwater entered in the hole at the same depth as the leaking point during the injection experiments. The temperature records also show that the rate of discharge had been nearly constant through the two test periods. The water discharge appears to have been little affected by the water injection. These results demonstrate that the optical fiber temperature monitoring system is a very effective tool for hydrological experiments.     

U–Pb dating of detrital zircon from Permian successions of the South Kitakami Belt,Northeast Japan: Clues to the paleogeography of the belt

The South Kitakami Belt in the northeast Japan is unique in presence of a thick Paleozoic–Mesozoic sedimentary rocks. The Permian sedimentary succession in the Maiya area of this belt is divided into the Nishikori, Tenjinnoki, and Toyoma formations, in ascending stratigraphic order. The Tenjinnoki Formation includes the Yamazaki Conglomerate Member containing granitic clasts. We performed U–Pb dating for detrital zircon of one sample of tuffaceous sandstone from the Nishikori Formation, six samples of sandstone from the Tenjinnoki and Toyoma formations, and five granitic clasts from the Yamazaki Conglomerate using laser ablation-inductively coupled plasma-mass spectrometry. Our dating results show that the tuffaceous sandstone sample has two age peaks at 287 and 301 Ma for the Nishikori Formation, three age peaks at 320–300, 290, and 270 Ma for the Tenjinnoki and Toyoma Formation, and ages of 311, 300, and 270 Ma from granitic clasts of the Yamazaki Conglomerate. In addition, older ages of 452–435 and 380 Ma were obtained from some zircon grains of the sandstone and granitic clasts. Our results suggest igneous activity in these periods. The South Kitakami Belt's origin with respect to continental blocks has been discussed in regard of the margin of North China Block or South China Block. Based on the stratigraphic ages and timing of igneous activity, we conclude that during the Permian the South Kitakami Belt was located at the margin of the South Central Asian Orogenic Belt, near the Solonker-Xra Moron-Changchun suture and the North China Block in East Asia.     

Study on the manganese nodule V. Thermal studies of the iron-manganese phase

The thermal phase transformation of the iron-manganese phase of the Pacific Ocean manganese nodules were studied by the differential thermal and X-ray diffraction methods. X-ray powder patterns of the heated samples at the temperature of 600°C to 1000°C show the occurrence of hematite, bixbyite and cubic and tetragonal (Fe, Mn)₃O₄. Bixbyite produced by the heat treatment of the iron-manganese phase gives an abnormal X-ray pattern in comparison with the standard sample of bixbyite. Cubic (Fe, Mn)₃O₄ is produced not only by the reaction of bixbyite with hematite over 900°C, but also at the lower temperature, such as 600°C. While, tetragonal (Fe, Mn)₃O₄ is a reaction product of cubic (Fe, Mn)₃O₄ with bixbyite over 900°C in the case of manganese rich nodules. The species and quantities of the products after the heat treatment are assumed to be mostly influenced by the relative contents of iron and manganese in the manganese nodule.     

A Eulerian-Eulerian Physical-Biological Impact Model of Zooplankton Injury Due to CO<Subscript>2</Subscript> Ocean Sequestration

To study the biological impacts of CO₂ ocean sequestration on floating marine organisms, a full Eulerian-Eulerian scheme model has been developed in a large-eddy simulation (LES) version using one-way coupling of the equations of seawater flow to the transport equations of the bio-scalar variables. Special attention was paid to deriving the transport equation, involving non-conservative scalars to describe the degree of injury to floating organisms due to the change in the pH environment resulting from CO₂ dissolution. The source terms of the transport equations of bio-scalar variables are based on experimental data on zooplankton activities affected by lower pH seawater, allowing construction of empirical sub-models of three kinds of floating marine organisms: Gaidius variabilis, Paraeuchaeta Birostrata, and Multi-organisms. An example is given to show the applicability of the model to the assessment of the biological impact of CO₂ sequestration in the ocean. Given an initial CO₂ droplet diameter of 8.0 mm and an injection rate of 1.0 kg/sec, the model simulation predicts that the zooplanktons lose approximately 90% of their activity when the lowest pH inside the plume decreases from 7.57 to 5.61. These injured zooplanktons then recovered gradually to their normal state within two hours due to dilution of the plume. This revised version was published online in July 2006 with corrections to the Cover Date.