Removal of Hydrogen Sulfide by Physico‐Biological Filter Using Mixed Rice Husk Silica and Dried Activated Sludge

This study investigated the effectiveness of a new packing material, namely mixed rice husk silica with dried activated sludge for removing H₂S. Dried sewage sludge was collected from Putrajaya sewage treatment plant in Malaysia. Rice husk silica was prepared at temperature of 800°C, after acid leaching and mixed with dried sewage sludge to be utilized in a polyvinyl chloride filter. The system was operated under variable conditions of two parameters, different inlet gas concentration and different inlet flow rate. H₂S was passed through the filter with one liter of the packing material. More than 99.96% removal efficiency (RE) with empty bed residence time (EBRT) of 90–45 s and 300 ppm inlet concentration was observed. However, the RE decreased to 96.87% with the EBRT of 30 s. The maximum elimination capacity (EC) of 52.32 g/m³/h was obtained with the RE of 96.87% and H₂S mass loading rate of 54 g/m³/h, while at the RE of 99.96%, maximum EC was 26.99 g/m³/h with the H₂S mass‐loading rate of 27 g/m³/h. A strong significant correlation between increasing of H₂S mass loading rate and pressure drop was also detected (p < 0.01). Maximum pressure drop was 3.0 mm H₂O after 53 days of operating time, the EBRT of 30 s, and 54 g/m³/h of H₂S loading rate. These observations suggest that the mixture of rice husk silica with dried activated sludge is a suitable physico‐biological filter for H₂S removal.     

On the development of a seismic source zonation model for seismic hazard assessment in western Saudi Arabia

A new seismic source model has been developed for the western part of the Arabian Peninsula, which has experienced considerable earthquake activity in the historical past and in recent times. The data used for the model include an up-to-date seismic catalog, results of recent studies of Cenozoic faulting in the area, aeromagnetic anomaly and gravity maps, geological maps, and miscellaneous information on volcanic activity. The model includes 18 zones ranging along the Red Sea and the Arabian Peninsula from the Gulf of Aqaba and the Dead Sea in the north to the Gulf of Aden in the south. The seismic source model developed in this study may be considered as one of the basic branches in a logic tree approach for seismic hazard assessment in Saudi Arabia and adjacent territories.     

Lower/middle tropospheric ozone variability in Senegal during pre-monsoon and monsoon periods of summer 2008: observations and model results

During the summer (8 June through 3 September) of 2008, 9 ozone profiles are examined from Dakar, Senegal (14.75°N, 17.49°W) to investigate ozone (O₃) variability in the lower/middle troposphere during the pre-monsoon and monsoon periods. Results during June 2008 (pre-monsoon period) show a reduction in O₃ concentrations, especially in the 850–700 hPa layer with Saharan Air Layer (SAL) events. However, O₃ concentrations are increased in the 950–900 hPa layer where the peak of the inversion is found and presumably the highest dust concentrations. We also use the WRF-CHEM model to gain greater insights for observations of reduced O₃ concentrations during the monsoon periods. In the transition period between 26 June and 2 July in the lower troposphere (925–600 hPa), a significant increase in O₃ concentrations (10–20 ppb) occur which we suggest is caused by enhanced biogenic NO_X emissions from Sahelian soils following rain events on 28 June and 1 July. The results suggest that during the pre-monsoon period ozone concentrations in the lower troposphere are controlled by the SAL, reducing ozone concentrations through heterogeneous chemical processes. At the base of the SAL we also find elevated levels of ozone, which we attribute to biogenic sources of NO_X from Saharan dust that are released in the presence of moist conditions. Once the monsoon period commences, lower ozone concentrations are observed and modeled which we attribute to the dry deposition of ozone and episodes of ozone poor air that is horizontally transported into the Sahel from low latitudes by African Easterly Waves (AEWs).     

Detecting temporal shoreline changes and erosion/accretion rates,using remote sensing,and their associated sediment characteristics along the coast of North Sinai,Egypt

The variation during 15 years in the shoreline along the North Sinai coast has been determined by analysing TM and ETM true colour Landsat images from 1986 to 2001. The analyses identified erosion and accretion patterns along the coast. The shoreline has advanced west of El Bardawil inlet1, El Bardawil inlet2, and El Arish Harbour, where the wave-induced littoral transport has been halted by jetty construction and beach growth rates are 20,681, 69,855 and 20,160 m²/year, respectively. On the downdrift side of the constructed jetties to the east, the shoreline is retreating and beaches erode at rates of −71,710, −69,968, and −11,760 m²/year, respectively. Sedimentological analyses of beach sediment samples have indicated selective transport of heavy minerals according to their densities and grain sizes. A general correspondence has been found between variation in grain size, sorting and heavy-mineral content of beach sand and the patterns of shoreline changes.     

Reconstructing late Eocene–lower Oligocene seismic facies framework of a rhythmic deposits from eastern China

Due to the apparent rhythmic characteristics of the stratigraphically complex unit formed of deltaic and mostly lacustrine deposits in Qianjiang depression (Jianghan basin), we used the seismic pattern proxies inside a seismic sequence, by analyzing the character of reflections (amplitude, continuity, and configuration) to detect the different seismic facies and to predict their depositional environmental settings. The depression fills are characterized by a distinct upward change in seismic facies; beginning with a fan facies in the bottom, followed by free facies occurring where thick salt sediments were presented, then convergent base-lapping facies, succeeded by chaotic facies and overlain by parallel to sub-parallel facies. The convergent base-lapping facies is the most common and the parallel and draping facies is restricted to slope areas shallower than 1000 m in water depth. Three depositional environments that range from fluvial, delta, to marine (lake) are predicted too. This paper lays the foundation for the development of a seismic sequence stratigraphic framework, and contributing to better understanding of the potential evaluation of hydrocarbon occurrence in the Eastern center of China.     

Shear wave velocity as function of cone penetration resistance and grain size for Holocene-age uncemented soils: a new perspective

For feasibility studies and preliminary design estimates, field measurements of shear wave velocity, V _s, may not be economically adequate and empirical correlations between V _s and more available penetration measurements such as cone penetration test, CPT, data turn out to be potentially valuable at least for initial evaluation of the small-strain stiffness of soils. These types of correlations between geophysical (Vs) and geotechnical (N-SPT, q _c-CPT) measurements are also of utmost importance where a great precision in the calculation of the deposit response is required such as in liquefaction evaluation or earthquake ground response analyses. In this study, the stress-normalized shear wave velocity V _s1 (in m/s) is defined as statistical functions of the normalized dimensionless resistance, Q _tn-CPT, and the mean effective diameter, D ₅₀ (in mm), using a data set of different uncemented soils of Holocene age accumulated at various sites in North America, Europe, and Asia. The V _s1–Q _tn data exhibit different trends with respect to grain sizes. For soils with mean grain size (D ₅₀) < 0.2 mm, the V _s1/Q _tn ^0.25 ratio undergoes a significant reduction with the increase in D ₅₀ of the soil. This trend is completely reversed with further increase in D ₅₀ (D ₅₀ > 0.2 mm). These results corroborate earlier results that stressed the use of different CPT-based correlations with different soil types, and those emphasized the need to impose particle-size limits on the validity of the majority of available correlations.     

Calcareous nannofossil biostratigraphy of the Paleocene at the Misheiti section,East Central Sinai,Egypt

Integration of calcareous nannofossil data, δ¹³C and δ¹⁸O values, and carbonate contents of the lower Paleocene–upper Paleocene sequence that crops out at the Misheiti section, East Central Sinai, Egypt, were used to denote the Danian/Selandian (D/S) and Selandian/Thanetian (S/T) stage boundaries. The study interval belongs to the Dakhla and Tarawan formations. Four calcareous nannofossil zones (NP4, NP5, NP6, and NP7/8) were recognized. The base of the Selandian Stage is tentatively placed at the lowest occurrences (LOs) of taxa ascribable to the second radiation of fasciculiths (i.e., Lithoptychius janii). This level is marked by a sudden drop of δ¹³C and δ¹⁸O values and carbonate content. No distinctive lithological changes were observed across the D/S boundary at the study section. A hiatus at the NP5/NP6 zonal boundary is indicated by the condensation of zones NP5 and NP6.The base of the Thanetian is placed at the base of Zone NP7/8 at the lithological change observed in correspondence to the boundary between the Dakhla and Tarawan formations. The δ¹³C and δ¹⁸O values abruptly decrease slightly above the base of Zone NP7/8. No consistent variations in the carbonate contents were recorded within Zone NP6 or across the NP6/NP7/8 zonal boundary.