Mobility and Transport of Nd Isotopes in the Vadose Zone During Weathering of Granitic Till in a Boreal Forest

There is a broad correlation between the ε_Nd values for rivers (including both the water and the particulate material it carries) and the age of the source terrain. This paper presents Nd isotope distribution data for soil, soil water, groundwater, and stream water samples gathered in a small catchment in northern Sweden. The results show that the release of Nd and Sm from boreal forests into streams and, eventually, into the oceans is more complicated than previously realized. The weathering of till causes changes in both the Nd isotopic composition and Sm/Nd ratios. Both the Sm/Nd ratio and ε_Nd were higher in strongly weathered soils horizons than in less weathered till, since minerals with high Sm/Nd ratios were, on average, more resistant to weathering than those with low Sm/Nd ratios. In contrast to the situation for the main minerals and the major elements, the weathering of rare earth elements (REE) was not restricted to the E-horizon: the measured REE concentrations continued to increase with depth in the C-horizon. In addition, REE released by weathering in the upper parts of the soil profile were partly secondarily retained at deeper levels. Therefore, the dissolved Nd released by weathering in the upper soil horizons was trapped and did not enter the groundwater directly. Rather, the Nd in the groundwater largely originated from weathering within the groundwater zone. However, this was not the only source of Nd in the stream water. The Nd isotope composition and Sm/Nd ratio were determined by the mixing between of Nd and Sm in the groundwater and REE-carrying organic material washed out of the soil profile. The groundwater close to the stream reaches the upper soil horizons during high discharge events such as snowmelts, and organic matter carrying Nd and Sm is washed out of the soils and thus released into the stream. Therefore, the Nd exported from catchment is derived from both the weathering within the groundwater zone, and the organic matter washed out from the soil. If longer timescales with more advanced weathering stages in the groundwater zone are considered, it cannot be ruled out that there will be a shift towards more radiogenic values in the exported Nd. Recorded shifts in the Nd isotopic composition in the ocean may thus not only reflect changed source regions, but also the weathering history of the same source region.     

Three‐dimensional modelling of differential railway track settlement using a cycle domain constitutive model

A method for simulation of differential (spatially varying) track settlement in a ballasted railway track is presented. It employs a cycle domain constitutive model to determine accumulated plastic (permanent) deformation of the granular layers supporting the track. The constitutive model is adopted for both the ballast and the sub‐ballast but with different parameter sets. The proposed framework can be used to predict differential track settlement accounting for heterogeneous (space‐variant) track characteristics and loading conditions. Here, it is demonstrated for three‐dimensional continuum modelling of a railway crossing panel subjected to a large number of axle passages. Because of the design of the crossing panel and the transient character of the impact loads on the crossing, the load transferred into the track bed is not uniform along the track, and the resulting differential settlement leads to vertical irregularities in track geometry. The spatial variation of track settlement is calculated both along the sleepers and along the rails. The influences of the number of adjacent sleepers accounted for in the model and the stiffness of the subgrade on the predicted settlement at the crossing are studied. Copyright © 2016 John Wiley & Sons, Ltd.     

Contaminant exposure and effects in Baltic ringed and grey seals as assessed by biomarkers

The Baltic Sea ecosystem has suffered from a heavy pollutant load for more than three decades. Persistent organic pollutants (POPs) and heavy metals have been of most concern due to their persistence and toxic properties. Ringed seals (Phoca hispida baltica) and grey seals (Halichoerus grypus) living in the Baltic Sea have been suffering from pathological impairments, including reproductive disturbances, which have resulted in a depressed reproductive capacity. We investigated several biochemical parameters as potential biomarkers for exposure to and effects of the contaminant load in the Baltic seals. Seals from less polluted areas were used as reference material in terms of the pollution load. In both Baltic seal populations, the levels of some biochemical parameters diverged from those in the reference seals, and some of these showed a clear correlation with the individual contaminant load. Of the potential bioindicators, we propose cytochrome P4501A activity and vitamin E levels, in blubber or plasma, as exposure biomarkers for polychlorinated biphenyls (PCBs) and dichlorodiphenyltrichloroethane (DDT) in both species. The arylhydrocarbon receptor-mediated chemical-activated luciferase gene expression (CALUX) response reflects the whole PCB and DDT burden in ringed seals. Retinyl palmitate (vitamin A) levels showed a negative correlation with the individual POP load, and is proposed as potential effect biomarkers for the depletion of the vitamin A stores. As the nutritional levels of both vitamin A and E have an impact on the vitamin levels in the seals, more information on the dietary vitamin levels is needed before any conclusions can be drawn. As the relationship between biochemical parameters and contaminants varied between the two species, species-specific characteristics has to be considered when monitoring the health status and possible toxic effects of the contaminant load in ringed and grey seals.     

The first use of Fulton's K for assessing and comparing the conditions of inter‐tidal fish populations

Fulton's K condition factor was applied, for the first time, to inter‐tidal specimens of the shanny (Lipophrys pholis) and long‐spined scorpion fish (Taurulus bubalis) from two English rocky shore and two Welsh rocky shore sites during summer 2010 and winter 2011. As both species contribute to the diet of commercial species such as cod (Gadus morhua) and near‐threatened species such as the European otter (Lutra lutra), their condition may affect that of these predators. Fulton's K found that inter‐tidal Welsh fish maintained a ‘good’ condition between seasons, whereas the inter‐tidal English fish were in a poorer condition during winter. Although condition also changed amongst the sites on each coast, further studies are needed into fish morphologies, environmental parameters, prey availabilities and abundances, and fish specimen sex and maturities.     

Identifying landslide preconditions in Swedish quick clays—insights from integration of surface geophysical,core sample- and downhole property measurements

Quick-clay landslides are a serious geohazard in Canada, Norway and Sweden. Identification and mapping of quick clays are essential endeavours because the damage caused by an individual landslide can be large and costly, with potentially fatal consequences. We collected geophysical borehole and soil core data from an area prone to quick-clay landslides in southwestern Sweden. Methodologies included in situ and laboratory measurements, providing information about natural gamma radiation, sonic velocities, electrical conductivity, pH, physical grain size, elemental and mineral composition, magnetic properties, cation exchange capacity and fossil content. A stratigraphic thickness of almost 60 m enables us to study quick clays and their host environment in Sweden at unusually high resolution. Results identify the origin and location of reflections in nearby seismic lines and assign physico-chemical properties to the geological units present in the area. We show that coarse-grained layers are sandwiched between marine clays (some of which are quick clays). These layers function as a conduit for relatively fresh water that infiltrates the marine clays and chemically destabilizes them by leaching out their salts. The salinity distribution in the boreholes indicate that the groundwater movement is downwards, through the coarse-grained layer and towards the Göta river. The presence of these materials is important for the development of quick clays, although not a prerequisite. With the help of surface geophysical methods, the location of the coarse-grained layers can be known faster and more economically, which could be relevant for studying the potential for quick-clay landslide occurrence over large areas.     

CAMAM: A Miniature Laser Ablation Ionisation Mass Spectrometer and Microscope‐Camera System for In Situ Investigation of the Composition and Morphology of Extraterrestrial Materials

Performance studies of a microscope‐camera system (MCS) and a laser ablation/ionisation mass spectrometer (LIMS) instrument (referred to here as a laser mass spectrometer or LMS) are presented. These two instruments were designed independently for in situ analysis of solids on planetary surfaces and will be combined to a single miniature instrument suite for in situ chemical and morphological analysis of surface materials on planetary bodies. LMS can perform sensitive chemical (elemental, isotope and molecular) analyses with spatial resolution close to micrometre‐sized grains. It allows for studies with mass resolution (M/ΔM) up to 800 in ablation mode (elemental composition) and up to 1500 in desorption mode (molecular analysis). With an effective dynamic range of at least eight orders of magnitude, sensitive and quantitative measurements can be conducted of almost all elements and isotopes with a concentration larger than a few ppb atoms. Hence, in addition to the major element composition, which is important for the determination of mineralogical constituents of surface materials, trace elements can also be measured to provide information on mineral formation processes. Highly accurate isotope ratio measurements can be used to determine in situ geochronology of sample material and for investigations of various isotope fractionation processes. MCS can conduct optical imagery of mm‐sized objects at several wavelengths with micrometre spatial resolution for the characterisation of morphological surface details and to provide insight into surface mineralogy. Furthermore, MCS can help in the selection of sample surface areas for further mass spectrometric analysis of the chemical composition. Surface auto‐fluorescence measurements and images in polarised light are additional capabilities of the MCS, to identify either fluorescing minerals or organic materials, if present on the analysed surface, for further investigation by LMS. The results obtained by investigations of NIST reference materials, amino acid films and a natural graphite sample embedded in silicate rock are presented to illustrate the performance of the instruments and their potential to deliver chemical information for mineral and organic phases in their geological context.     

A practical ranking system to compare toxicity of anti-fouling paints

The toxicity of a number of new anti-fouling paints, claimed to function by physical means and not by leakage of toxic substances, have been tested on two common organisms in the Baltic Sea, i.e., the red macro alga Ceramium tenuicorne and the copepod Nitocra spinipes. In order to compare the toxicity between the paints a ranking system was developed based on the EC₅₀- and LC₅₀-values. The results showed a wide span in toxicity with the most toxic paints ranked 160 times more toxic than the ones ranked least toxic.

Also, TBT, irgarol and diuron, which have been used as active ingredients in traditional anti-fouling paints, were used to evaluate the sensitivity of the two test organisms. The results showed that the test organisms were equally sensitive to the substances as similar organisms in earlier studies.

In conclusion, the ranking system presented in this study permits ranking and comparison of total toxicity of complex mixtures.     

Probabilistic model for eruptions and associated flood events in the Katla caldera,Iceland

Eruptions in the subglacial Katla caldera, South Iceland, release catastrophic jokulhlaups (meltwater floods). The ice surface topography divides the caldera into three drainage sectors (Ko, So and En sectors) that drain onto Myrdalssandur, Solheimasandur and Markarfljot plains, respectively. In historical times, floods from the Ko sector have been dominant, with only two recorded So events. Geological records indicate that floods from the En sector occur every 500–800 years. A probabilistic model for an eruption is formulated in general terms by a stochastic parameter that simulates a series giving the time interval in years between two consecutive events. The model also contains a Markovian matrix that controls the location of the event and thereby what watercourse is hit by the flood. A record of Katla eruptions since the 8th and the 9th century a.d., and geological information of volcanogenic floods towards the west over the last 8,000 years is used to calibrate the model. The model is then used to find the probabilities for floods from the three sectors: Ko, So and En. The simulations predict that the most probable eruption interval for the En sector and the So sector is several times smaller than the average time interval, implying infrequent periods of high activity in these sectors. A correlation is found between the magnitude of eruptions and the following time intervals. Using the statistical approach and considering this magnitude–time interval correlation, the probability of an eruption in Katla volcano is considered to be 20% within the next 10 years. This compares to a probability of 93% if only a simple average is considered. These probabilities do not take account of long-term eruption precursors and should therefore be regarded as minimum values.     

Differences in physiological response to increased seawater temperature in nearshore and offshore corals in northern Vietnam

Effects of elevated seawater temperature show high spatial heterogeneity and variation within and among coral species. The objective of this study was to investigate how two coral species, Porites lutea and Galaxea fascicularis, from two high latitude reefs differently exposed to chronic disturbance, respond to elevated seawater temperatures. Corals were collected from reefs nearshore (i.e. subjected to high sediment load, higher chlorophyll α concentrations, turbidity etc.) and offshore (i.e. less exposed). The corals were exposed in the lab to gradually increasing temperatures (25.5-33.5?°C) for 72?h after which they were allowed to recover to ambient temperature (25.5?°C) for 24?h. Production and respiration were measured after 24, 48, 72 and 96?h. The results show that P. lutea from nearshore reefs suffered an initial decrease in gross primary production/respiration (GP/R) ratio after 24?h, after only a moderate temperature increase (+2?°C, from 25.5 to 27.5?°C), while there was no difference in GP/R ratio between heat-exposed and controls the other days, indicating that the chronic disturbance in the nearshore reef had no effect on their thermotolerance. Furthermore, P. lutea from the offshore reef showed a decrease in GP/R ratio both after 24?h and 72?h (33.5?°C) of exposure. In comparison, G. fascicularis showed a decrease in GP/R ratio after 48?h, 72?h and 96?h of exposure for the nearshore corals. Also, after 72?h these corals had withdrawn their polyps. There were no differences between heat-treated and controls for the offshore G. fascicularis. This implies that the chronically disturbed G. fascicularis had lower thermotolerance when exposed to a temperature increase. This study, hence, shows that the response of corals to elevated seawater temperature varies with species and environmental background history.