Ruthenium-ion-catalyzed oxidation of asphaltenes and oil-source correlation of heavy oils from the Lunnan and Tahe oilfields in the Tarim Basin, NW China

The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields.     

Microthermometric measurement of fluid inclusions and its constraints on genesis of PGE-polymetallic deposits in Lower Cambrian black rock series, southern China

Systematic microthermometric measurements of fluid inclusions in the PGE-polymetallic deposits hosted in the Lower Cambrian black rock series in southern China were performed, and the results suggest: (1) there exist two types of fluid inclusions. TypeⅠis of NaCl-H2O system with low-medium salinity, and its homogenization temperatures (Th) and salinities are 106.9- 286.4℃ and ( 0.8- 21.8) wt%NaCl eq. respectively; TypeⅡ is of CaCl2-NaCl-H2O system with medium-high salinities, and its homogenization temperatures and salinities range from 120.1℃ to 269.6℃ and ( 11.4- 31.4) wt%NaCl eq., respectively. The typeⅡ fluid inclusions have been discovered for the first time in this kind of deposits; (2) two generations of ore-forming fluids were recognized. Characteristics of fluid inclusions in the PGE-polymetallic ores and carbonate-quartz stockworks in the underlying phosphorites are almost of no difference, they may represent ore-forming fluids at the main metallogenic stage. The peak value of homogenization temperature of those fluid inclusions is about 170℃, while their salinities possess a remarkable bimodal distribution pattern with two peak values of (27-31) wt%NaCl eq. and (4-6) wt%NaCl eq. On the contrary, fluid inclusions in the carbonate-quartz veins in the hanging wall may represent ore-forming fluids at the post-metallogenetic stage. The homogenization temperatures and the peak values of salinities are mostly 130-170℃ and (12-14) wt%NaCl eq., respectively; (3) nobel gas isotopic composition analyses in combination with the microthermometric measurements of fluid inclusions suggest that the ore-forming fluids at the main metallogenetic stage were probably derived from mixing of basinal hot brines with the CaCl2-NaCl-H2O system and seawater with the NaCl-H2O system; (4) in the Early Cambrian, the basinal hot brines were trapped in the Caledonian basins, which were distributed along the southern margin of the Yangtze Craton, and where giant thick sediments were accumulated, and expelled and migrated laterally along the strata because of the pressure caused by overlying sediments. The basinal hot brines absorbed Ni, Mo, V, PGE from the surrounding rocks and were transformed into ore-bearing hydrothermal fluids with the CaCl2-NaCl-H2O system and medium-high salinities, then ascended along faults and mixed with seawater of the NaCl-H2O system, and finally PGE-polymetallic deposits or occurrences were formed in the black rock series.     

Visualization issues in the development of electronic atlas in China

In this paper, we discuss the development of electronic atlas in China, with focus on the issues of visualization. We particularly categorise this development into four periods, and then analyse the characters in each period and discuss the visualization issues. The four periods are highlighted: 1) Infant period (<1990) characterized as computer assisted mapping with products of screen maps; 2) Starting period (1991-1995) characterized as object-oriented mapping with products of interactive maps/atlases; 3) Advancing period (1996-2000) characterized as integrated mapping with products of multimedia cartographic maps; 4) New era (> 2001) characterized as web mapping and adaptive map design with products of Internet maps and atlas as well as adaptive maps. It is obvious that the development follows the logical way from static to dynamic, and even real time visualization, from single user to multiple users, from presentation to exploration for effective communication and knowledge construction. Current research and development projects are focused on customisation of atlas information systems for real-time tasks, Internet operability, small displays and mobile environments. The major challenges involved in each of such customisation processes are identified and commented in relation to the further development of visualization.     

Sr/Sr and Sr/Ca in speleothems for paleoclimate reconstruction in Central China between 70 and 280 kyr ago

Limestone cave deposits (speleothems) provide archives for past changes in regional climates over a range of timescales. While δ¹⁸O and δ¹³C in speleothem calcite have been commonly used for reconstruction of paleoclimates, we report here further efforts in the use of ⁸⁷Sr/⁸⁶Sr and Sr/Ca signals in speleothem calcite to deduce paleomonsoon variability near the Loess Plateau of central China. A two end-member mass-balance model of concentration and isotopic composition of strontium in a cave system is used to estimate variation of the ⁸⁷Sr/⁸⁶Sr ratio in sediments overlying a limestone cave. We show that this ratio reflects climate-driven variations in the provenance and the extent of chemical weathering of the epikarstic sediments. The measurements of ⁸⁷Sr/⁸⁶Sr made on a well-dated stalagmite, SFL, from Buddha Cave (33^o40N′ 109^o05′E) show ratios of 0.71092 to 0.71133 (±0.00001 as 2σ) during relatively cold periods (e.g., Marine Isotope Stage (MIS) 5b, 5d, and 8), lower than ratios of 0.71133 to 0.71194 during relatively warm periods (e.g., MIS 5a, 5c, 5e, and 7). As changes in the Sr/Ca ratio may affect speleothem ⁸⁷Sr/⁸⁶Sr, we show that the direct use of speleothem ⁸⁷Sr/⁸⁶Sr is less ideal than our modeled ⁸⁷Sr/⁸⁶Sr for the exogenic Sr source above the cave as a paleomonsoon proxy. Using the δ¹⁸O, δ¹³C, Sr/Ca, and ⁸⁷Sr/⁸⁶Sr records of the stalagmite, we reconstruct the variability of the East Asian monsoon for the time period between 70 and 280 kyr ago. The results show that summer monsoons were more intense during interglacial periods than during glacial periods.     

一次自上向下发展的高原涡的多尺度动力学分析

高原涡作为经常给我国带来暴雨等灾害的天气系统,其形成一般认为是通过感热和潜热自下而上激发的,然而,2013年5月下旬发生的一次引发其下游灾害性强降水的高原涡却是由对流层高层天气尺度低涡诱发的.为此,基于新发展的多尺度子空间变换和多尺度能量涡度方法以及ERA5再分析资料对其动力学过程进行了详尽的探讨,先将原始场重构到三个...     

一种用于海底类型聚类的新方法

By using sonar imaging, this paper presents a new algorithm for the clustering of seabed types based on the self-organizing feature maps （SOFM） neural network. The theory as well as data processing is studied in detail. Some valuable conclusions and suggestions are given     

用地电阻率探测和监测滑坡体实验

实验采用高密度电阻率方法探测滑坡体的电性结构, 用电阻率变化各向异性方法监测滑坡体的主破裂扩展方向和速率. 实验结果为: ① 电性结构探测实验, 验证了部分原勘测的滑坡体的蠕变体边界和地下水层的深度和厚度, 以及上层介质的性质. 证明滑动带富含地下水层; ② 用电阻率变化各向异性监测实验确定的测点主破裂扩展方向, 与滑坡体GPS位移推断的破裂带方向吻合, 且电阻率变化各向异性系数的变化速率与钻孔倾斜仪测量的滑坡体深部位移变化的速率相应.      

Timing analysis of the black hole candidate EXO 1846-031 with insight-HXMT monitoring

We present the observational results from a detailed timing analysis of the black hole candidate EXO 1846-031 during its outburst in 2019 with the observations ...     

曲流点坝内部剩余油形成与分布规律物理模拟

建立了曲流点坝物理模型,模拟地下曲流点坝储层进行驱替实验。观察注入剂的运动规律,同时,在模型上布置了测量电极,以双电极法测量驱替过程中垂向电阻变化,反映注入剂波及高度的变化规律。分析了侧积泥岩夹层的建筑结构对注入剂在点坝砂体中的流动规律,以及对剩余油的形成分布的影响。通过实验研究证实,在曲流点坝内部,侧积泥岩夹层对注入剂具有强烈的遮挡作用,受其影响形成侧积体差异型剩余油、重力型剩余油以及压力异常型剩余油三种类型剩余油,主要分布在点坝的中上部。在实际生产中,利用水平井钻遇点坝上部进行开采是主要的手段。     

Building damage in Dujiangyan during Wenchuan Earthquake

A field damage survey of 1,005 buildings damaged by the Wenchuan Earthquake in Dujiangyan City was carried out and the resulting data was analyzed using the statistical method. It is shown that buildings that were seismically designed achieved the desired seismic fortification target; they sustained less damage than the non-seismically designed buildings. Among the seismically designed buildings investigated, RC frame buildings performed the best in terms of seismic resistance. Masonry buildings with a ground story of RC frame structure were the second best, and masonry buildings performed the worst. Considering building height, multistory buildings sustained more severe damage than high-rise buildings and 2- and 3-story buildings. Compared to residential buildings, public buildings, such as schools and hospitals, suffered more severe damage.