K-rich titanate from the Jharia ultrapotassic rock, Gondwana coal fields, eastern India, and its petrological significance

We report a rare accessory groundmass mineral of K-rich titanate, having a composition close to that of potassium triskaidecatitanate (K₂Ti₁₃O₂₇), from an underground drill-core sample of ultrapotassic rock from southwestern part of the Jharia coal field in the Damodar valley, at the northern margin of the Singhbhum craton, Eastern India. Potassium triskaidecatitanate is regarded as a typomorphic mineral of orangeites (Group II kimberlites) of Kaapvaal craton, southern Africa, and its occurrence in the Jharia ultrapotassic rock is significant since ultrapotassic suite of rocks elsewhere from the Damodar valley have been recently suggested to be peralkaline lamproites based on mineral-genetic classification. The important role played by a unique geodynamic setting (involving a thinned metasomatised lithospheric mantle and inheritance of an Archaean subduction component) at the northern margin of the Singhbhum craton in deciding the petrological diversity of the early Cretaceous ultrapotassic intrusives from the Damodar valley is highlighted in this study.     

First finding of native gold from the chromitites of the Mesoarchaean Tagadur mines, Nuggihalli Schist Belt, Dharwar Craton, south India

Occurrence of native gold in ultramafic rocks is rather rare. Such occurrences serve as snapshots of the underlying processes leading to their formation and modifications thereafter. Presence of native gold as flakes were earlier reported from the chromites of rock massifs of Kraka, southern Urals, Russia (Kovalev et al. 2007). Gold spherules also occur as tiny inclusions (5–30 μm) in olivine, pyrrohotite and magnetite grains from the ultrabasic rocks of Loveld deposit, South Africa (Rozhkov, 1967). Here we report, probably for the first time, occurrence of native gold from the chromitites of the Mesoarchaean Tagadur Mines of the Nuggihalli Schist Belt (NSB), Dharwar Craton, south India. Geological Survey of India (2006) has already reported significant gold content from the bulk ultramafic rocks of Kempinakote area far south of the current study area. A short discussion on the preliminary petrographic features of the gold grains and its significance is presented.     

Tokapal tuff-facies kimberlite, Bastar craton, Central India: A nickel prospect?

We report the occurrence of garnierite (a general term referring to Ni-Mg bearing hydrous silicates in laterites) from the crater-facies Tokapal kimberlite of the Bastar craton, Central India. Garnierite occurs as discrete ovoid or amoeboid segregations (up to 200 mm) or as veinlets with up to 18.1 wt% NiO and high iron contents (up to 36.2 wt% FeO^T). Chemical composition of the garnierite implies its derivation from a magnesium-rich protolith. Extensive lateritisation of the large crater-facies (～2.5 km diameter) saucer-shaped kimberlite under tropical weathering conditions, aided by suitable topography, drainage and favourable structural set-up, are the factors inferred to be responsible for the formation of garnierite in the Tokapal system. As lateritic nickel ores constitute significant resources for nickel exploration, the perspective of the Tokapal kimberlite as a nickel prospect needs to be investigated.     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

The October 20, 2011 Mw 5.1 Talala earthquake in the stable continental region of India

The Talala (Sasangir) area in the Saurashtra region of Gujarat, western India, is experiencing tremors since 2001. The swarm type of earthquake activity in 2001, 2004, and every year from 2007 onward has occurred after the monsoon and lasted 2?C3?months each time. In 2007 some 200 shocks (largest M_w 5.0) and in 2011 about 400 shocks down to M1 are well recorded with 1?C2?km location error. The focal depths are about 2?C10?km and shocks are accompanied by blast-like subterranean sounds. The epicenter (21.09?N 70.45E, focal depth: 5?km from location program, 3?km from MTS) of the October 20, 2011 mainshock occurred about 12-km WNW of Talala town or 8-km SSW of the 2007?M _w 5.0 earthquake epicenter. The epicentral trends deciphered from local earthquake data indicate two ENE trends (Narmada trend) for about 50?km length and a conjugate 15-km-long NNW trend (Aravali trend). The focal mechanisms by moment-tensor analysis of full wave forms of two 2007 events of M_w 4.8 and 5.0 and the 2011 event of M_w 5.1 indicate rupture along either of the two trends. The ENE trends follow a gravity low between the gravity highs of Girnar mounts. Seismic reflections also indicate a fault in the area named Girnar Fault. Most of Saurashtra region including the Talala area is covered by Deccan Trap Basalt forming plateaus and conical ridges. There is no major fault within Saurashtra Peninsula though it is believed to have major faults along the boundaries that are non-seismic. The intensity of the October 20, 2011 Talala earthquake is estimated to be 6.5 in MM scale while isoseismals of 6, 5, and 4 and felt distance give M_w 5.1 based on Johnston??s 1994 empirical regressions. The source parameters of the 2011 Talala earthquake are estimated using data from 14 broadband seismograph stations. Estimated seismic moment, moment magnitude, stress drop, corner frequency, and source radius are found to be 10^16.6 N-m, 5.1, 1.6?MPa, 1.3?Hz, and 2,300?m, respectively. The b and p values are obtained to be low, being 0.67 and 0.71, respectively. PGA of 35?cm/sec² is noted and the decay rate of acceleration has been estimated from strong motion data recorded at 5 stations with epicentral distances ranging from 32 to 200?km.     

Triggered/migrated seismicity due to the 2001 M w7.7 Bhuj earthquake, Western India

Paper describes triggered seismicity to 200?km distance and for a decade due to the 2001 M _w7.7 Bhuj earthquake. The Kachchh region is seismically one of the most active intraplate regions of the World due to the occurrence of two large earthquakes 1819 (M _w7.8) and 2001 (M _w7.7). Though, it has high hazard but was known to have low seismicity in view of the occurrence of fewer smaller shocks. However, the status seems to have changed after 2001. Besides the strong aftershock activity for over a decade, seismicity has spread to nearby faults in Kachchh peninsula and at several places southward for 200?km distance in Saurashtra peninsula. Beyond the rupture zone of the 2001 Bhuj earthquake, more than 40 mainshocks of M _w?~?3?C5 have occurred at 20 different locations, which is unusual. The increased seismicity is inferred to be caused by stress perturbation due to the 2001 Bhuj earthquake by viscoelastic process. In Saurashtra, over and above the viscoelastic stress increase, the transient stress increase by water table rise in monsoons seems to be affecting the timing of mainshocks and associated sequences of earthquakes.     

Crystalline and Osmotic Swelling of an Expansive Clay Inundated with Sodium Chloride Solutions

Compacted expansive clays swell due to crystalline swelling and osmotic/double layer swelling mechanisms. Crystalline swelling is driven by adsorption of water molecules at clay particle surfaces that occurs at inter-layer separations of 10–22 Å. Diffuse double layer swelling occurs at inter-layer separations >22 Å. The tendency of compacted clay to develop osmotic or double layer swelling reduces with increase in solute concentration in bulk solution. This study examines the consequence of increase in solute concentration in bulk solution on the relative magnitudes of the two swelling modes. The objective is achieved by inundating compacted expansive clay specimens with distilled water and sodium chloride solutions in free-swell oedometer tests and comparing the experimental swell with predictions from Van’t Hoff equation. The results of the study indicate that swell potential of compacted expansive clay specimens wetted with relatively saline (0.4, 1 and 4 M sodium chloride) solutions are satisfied by crystalline swelling alone. Comparatively, compacted clay specimens inundated with less saline solutions (0.005–0.1 M sodium chloride) require both crystalline and osmotic swelling to satiate the swell potential.     

电法勘探在探测加油站石油烃污染中的应用

对一个有近40年历史的废弃加油站,分别使用探地雷达方法和高密度电阻率法进行探测,同时布置了4口监测井进行取样分析,以验证两种方法探测石油烃类轻质非水相液体(LNAPLs)污染物的准确性。测量结果明确显示了污染源及其扩散范围。实际应用证实了探地雷达与高密度电阻率法可以作为有效的工具在加油站及类似场地用于环境探测。     

Assessment of trace element contamination in soils around Chinnaeru River Basin, Nalgonda District, India

Concentrations of trace elements such as As, Ba, Co, Cr, Cu, Ni, Pb, Rb, Sr, V, Y, Zn and Zr were studied in soils to understand metal contamination due to agriculture and geogenic activities in Chinnaeru River Basin, Nalgonda District, India. This area is affected by the geogenic fluoride contamination. The contamination of the soils was assessed on the basis of geoaccumulation index, enrichment factor (EF), contamination factor and degree of contamination. Forty-four soil samples were collected from the agricultural field from the study area from top 10–50 cm layer of soil. Soil samples were analyzed for trace elements using X-ray fluorescence spectrometer. Data revealed that soils in the study area are significantly contaminated, showing high level of toxic elements than normal distribution. The ranges of concentration of Ba (370–1,710 mg/kg), Cr (8.7–543 mg/kg), Cu (7.7–96.6 mg/kg), Ni (5.4–168 mg/kg), Rb (29.6–223 mg/kg), Sr (134–438 mg/kg), Zr (141.2–8,232 mg/kg) and Zn (29–478 mg/kg). The concentration of other elements was similar to the levels in the earth’s crust or pointed to metal depletion in the soil (EF < 1). The high EFs for some trace elements obtained in soil samples show that there is a considerable heavy metal pollution, which could be due to excessive use of fertilizers and pesticides used for agricultural or may be due to natural geogenic processes in the area. Comparative study has been made with other soil-polluted heavy metal areas and its mobility in soil and groundwater has been discussed. A contamination site poses significant environmental hazards for terrestrial and aquatic ecosystems. They are important sources of pollution and may result in ecotoxicological effects on terrestrial, groundwater and aquatic ecosystems.     

Assessment of groundwater inflows into Kuteshwar Limestone Mines through flow modeling study, Madhya Pradesh, India

The development of limestone mining activities in Katni, Madhya Pradesh becomes necessary to increase the depth of exploration to produce ore. Increase in the exploration depth means that mining pits were subjected to water inrush. A hydrological and a hydrogeological model for the Katni area have been developed using USGS flow code, MODFLOW 2000. Collected GIS-based information was synthesized in a finite difference numerical model. The regional steady flow was calibrated under pre-development conditions assuming an equivalent porous medium approach. Water budget calculations show that the total groundwater flow into the aquifer system due to interaction with river amounts to 14,783 m³/day. Infiltration from precipitation provides 1,600 m³/day of the groundwater supply, while 1,446 m³/day comes from lateral inflow and the remaining. The inflows into mine pit area amounts to 15,725 m³/day. Although the karstic nature of the limestone aquifer the equivalent porous medium flow model is appropriate to represent hydraulic heads and recharge/discharge relationships on a regional scale. The results of this study can be used to predict the required amounts of pumping and the possible locations to dewater the groundwater in the mining pits.