Natural attenuation of TCE, As, Hg linked to the heterogeneous oxidation of Fe(II): an AFM study

Hydrous ferric oxide (HFO) colloids formed, in strictly anoxic conditions upon oxidation of Fe²⁺ ions adsorbed on mineral surface, were investigated under in situ conditions by contact mode atomic force microscopy (AFM). Freshly cleaved and acid-etched large single crystals of near endmember phlogopite were pre-equilibrated with dissolved Fe(II) and then reacted with Hg(II), As(V) and trichlorethene (TCE)-bearing solutions at 25 °C and 1 atm. HFO structures are found to be of nanometer scale. The As(V)–Fe(II) and Hg(II)–Fe(II) reaction products are round (25 nm) microcrystallites located predominantly on the layer edges and are indicative of an accelerated Fe(II) oxidation rate upon formation of Fe(II) inner sphere surface complexes with the phyllosilicate edge surface sites. On the other hand, TCE–Fe(II)–phlogopite reaction products are needle-shaped (45 nm long) particles located on the basal plane along the Periodic Bond Chains (PCBs) directions. Experiments with additions of sodium chloride confirm the importance of the Fe(II) adsorption step in the control of the overall heterogeneous Fe(II)–TCE electron transfer reaction.

Kinetic measurements at the nanomolar level of Hg° formed upon reduction of Hg(II) by Fe(II) in presence of phlogopite particles provide further convincing evidence for reduction of Hg(II)_aq coupled to the oxidation of Fe(II) adsorbed at the phlogopite–fluid interface, and indicate that sorption of Fe(II) to mineral surfaces enhances the reduction rate of Hg(II) species. The Hg(II) reduction reaction follows a first-order kinetic law. Under our experimental conditions, which were representative of many natural systems, 80% of the mercury is transferred to the atmosphere as Hg° in less than 2 h.

The reduction of a heavy metal (Hg), a toxic oxyanion (arsenate ion) and a chlorinated solvent (TCE) thus appear to be driven by the high reactivity of adsorbed Fe(II). This is of environmental relevance since these three priority pollutants are that way reductively transformed to a volatile, an immobilizable and a biodegradable species, respectively. Such kinetic data and reaction pathways are important in the evaluation of natural evaluation scenarios, in the optimization of Fe(II)/mineral mixtures as reductants in technical systems, and in general, in predicting the fate and transport of pollutants in natural systems.     

Integration of local participatory and regional planning: A GIS data aggregation procedure

This paper presents an approach for GIS integrating local participatory land management information used for regional planning, and contributing to a bottom-up approach to land use planning. In participatory planning, the integration between local and regional levels should facilitate the communication and co-operation among the parties at both levels, for an efficient use of available resources. For coherently linking these two levels it is necessary to transform the data produced at one level, in order to be usable by the other. This transformation consists of a spatial procedure, which allows scaling-up the local participatory rural appraisal (PRA) information for regional purposes and scaling down the regional information for local use, using a GIS. Such an integration procedure is presented and discussed using data from a case study in south-western Burkina Faso.     

Strain analysis of a shear zone in a granodiorite

A ductile shear zone in a late Precambrian granodiorite, from the Rouergue (southwest part of the French Massif Central) has been studied.A single episode of deformation is responsible for the formation of a foliation and a well-defined lineation which are localized into an elongated zone, a few decimeters wide.The strain features can be attributed to a simple-shear mechanism (Ramsay and Graham, 1970), so that the main parameters of the deformation are defined.At stages of increasing deformation, the quartz isotropic sub-fabric of the undeformed host rock is progressively transformed into an anisotropic fabric composed of a single oblique girdle while the subgrain size progressively decrease and the dislocation density remains constant. It is suggested that the gliding planes of quartz are the basal plane (0001) and a predominant prismatic plane 101̄0 the slip directions may be a for both glide-planes.The results obtained in this investigation provide a basis for a high voltage electron microscope (H.V.E.M.) study which shows that the fabrics development may be related to dislocation processes. The difference of strain rates in the host rock and in the shear zone is calculated from the dislocation microstructures.     

Multi-hazard risk mapping and assessment on an active volcano: the GRINP project at Mount Cameroon

To help improve the safety of its population faced with natural disasters, the Cameroon Government, with the support of the French Government, initiated a programme of geological risk analysis and mapping on Mount Cameroon. This active volcano is subject to a variety of hazards: volcanic eruptions, slope instability and earthquakes. Approximately 450,000 people live or work around this volcano, in an area which includes one of Cameroon’s main economic resources. An original methodology was used for obtaining the information to reply to questions raised by the authorities. It involves several stages: identifying the different geological hazard components, defining each phenomenon’s threat matrix by crossing intensity and frequency indices, mapping the hazards, listing and mapping the exposed elements, analysing their respective values in economic, functional and strategic terms, establishing typologies for the different element-at-risk groups and assessing their vulnerability to the various physical pressures produced by the hazard phenomena, and establishing risk maps for each of the major element-at-risk groups (population, infrastructures, vegetation, atmosphere). At the end of the study we were able (a) to identify the main critical points within the area, and (b) provide quantified orders of magnitude concerning the dimensions of the risk by producing a plausible eruption scenario. The results allowed us to put forward a number of recommendations to the Cameroon Government concerning risk prevention and management. The adopted approach corresponds to a first level of response to the authorities. Later developments should make it possible to refine the quality of the methodology.     

Modelling-based assessment of suspended sediment dynamics in a hypertidal estuarine channel

We investigate the dynamics of suspended sediment transport in a hypertidal estuarine channel which displays a vertically sheared exchange flow. We apply a three-dimensional process-based model coupling hydrodynamics, turbulence and sediment transport to the Dee Estuary, in the north-west region of the UK. The numerical model is used to reproduce observations of suspended sediment and to assess physical processes responsible for the observed suspended sediment concentration patterns. The study period focuses on a calm period during which wave-current interactions can reasonably be neglected. Good agreement between model and observations has been obtained. A series of numerical experiments aim to isolate specific processes and confirm that the suspended sediment dynamics result primarily from advection of a longitudinal gradient in concentration during our study period, combined with resuspension and vertical exchange processes. Horizontal advection of sediment presents a strong semi-diurnal variability, while vertical exchange processes (including time-varying settling as a proxy for flocculation) exhibit a quarter-diurnal variability. Sediment input from the river is found to have very little importance, and spatial gradients in suspended concentration are generated by spatial heterogeneity in bed sediment characteristics and spatial variations in turbulence and bed shear stress.     

Rupture of an evaporating liquid bridge between two grains

The study examines rupture of evaporating liquid bridges between two glass spheres. Evolution of the bridge profile has been recorded with the use of high-speed camera. Geometrical characteristics of the bridge were then used to calculate evolution of the variables during the process: Laplace pressure, capillary force, and surface tension force. For the purpose of reference, the bridge evolution is followed also during kinematic extension. During both processes the diameter of the neck decreases, with an acceleration of about 1–2 ms before the rupture. Two distinct rupture modes are observed, depending on the bridge aspect ratio. After the rupture, the mass of liquid splits, forming two separate oscillating drops attached to the spheres, and a suspended satellite droplet. Just before the rupture, an increasing repulsive Laplace pressure, and decreasing negative surface tension force develop. Capillary force follows the trend of the surface tension force, with an accelerating decline. Duration of the whole process and liquid mass stabilization is from 10 to 60 ms.     

Phytolith indices as proxies of grass subfamilies on East African tropical mountains

The main objective of this paper is to provide researchers that investigate fossil phytolith assemblages and model/data comparisons a new tool for estimating C₃/C₄ grass composition over time. We tested the reliability of modern soil phytolith assemblages and phytolith indices for tracing the dominance of different grass subfamilies and tree cover density. We analyzed modern soil phytolith assemblages from sites over elevation gradients on Mount Kenya (Kenya), Mount Rungwe and around Lake Masoko (southern Tanzania). These data were compared with available botanical data. A phytolith index named Ic, proved to be an effective proxy of the proportions of Pooideae, Arundinoideae and Bambusoideae grasses (mainly C₃ grasses) versus Panicoideae grasses (mainly C₄ grasses), increasing with elevation in East-Africa. When tropical mountains are covered by open habitats (e.g. grasses and shrublands), Ic should be a reliable proxy of the C₃/C₄ grass composition. These results highlight the value of the phytolith index Ic, when interpreting paleo-environmental records from tropical mountains, to: 1) better understand past local and regional C₃/C₄ grass distributions and associated climatic changes and 2) increase the set of C₃/C₄ data available for model/data comparisons.