Mineralogy and petrology of a piemontite-bearing schist, western Otago, New Zealand

Abstract. Pink piemontite-spessartine-bearing and grey-green spessartine-bearing manganiferous quartzose schists derived from siliceous pelagites, and green quartzofeldspathic schists, are described from the greenschist facies of the Haast Schist terrane, near Arrow Junction, western Otago. Electron microprobe data are reported for sphene, spessartine-rich garnet, manganoan epidote, piemontite, tourmaline, phengitic muscovite, chlorite, albite, haematite, rutile, manganoan calcite and chalcopyrite. Metamorphism occurred at about 6.4kbar, 400°C. X_co2 was above the quartz-rutile-calcite-sphene buffer (X_co2± 0.02) throughout the recorded metamorphic history of the piemontite schists. It dropped from above to below this critical buffering value in a spessartine-rich schist and it was close to or below the buffering value in the quartzofeldspathic schists. Production of piemontite required high f_O2, believed to be inherited from MnO_x in the parent pelagite. Substantial loss of O₂ (e.g. minimum of 0.19% by weight in one rock) during diagenesis and/or metamorphism is inferred. In the grey-green schists this inhibited piemontite formation. Slight loss of O₂ and Ca²⁺ accompanied minor late-stage replacement of piemontite by second generation spessartine. Observed zoning and mineral replacements indicate rise of temperature, drop in pressure, or invasion by solutions of lower f_O2 and X_CO2 equilibrated with surrounding schists. The detailed chemistry of the minerals studied correlates with available Mn and with bulk-rock (Fe³⁺ x 100)/(Fe²⁺+ Fe³⁺). The oxidation ratio ranges from 24 in average green quartzofeldspathic schist, through 78 in average grey-green manganiferous quartzose schist, to almost 100 in some piemontite-bearing schists. As Fe²⁺ gives way to Fe³⁺, Mg/Fe ratios tend to rise in chlorite, phengite, tourmaline, spessartine, and calcite, Mn increases and Ti decreases in haematite, Mn increases in spessartine and calcite, and Fe increases in rutile. Available divalent cations are depleted relative to Al; chlorite is more aluminous, and phengite more paragonitic than in typical Haast schists.     

Estimating the size and travel distance of Klapperhorn Mountain debris flows for risk analysis along railway, Canada

Debris flows occurring on Klapperhorn Mountain in the Yellowhead Pass in the Canadian Rocky Mountains pose a significant hazard to railway operations at the base of the mountain. The size （volume） and travel distance of these debris flows play an important role in assessing the risk to the railway. GIS analysis, airphoto interpretation together with field work were undertaken on two debris flows located at track mileage 54.0 and 54.3. Characteristics of these two debris flow events were analyzed, including debris flow path morphology and event behavior. Their sizes and travel distances were estimated using an empirical-statistical model （UBCDFLOW） under different initiation conditions. Their potential impact on the railway bridge was evaluated using a bridge blockage ratio.     

TWO METHODS FOR CONTINUOUS MONITORING OF HARMONIC DISTORTION IN VIBROSEIS SIGNALS1

The quality of Vibroseis survey data can be improved by continuously monitoring the vibrator's baseplate and reaction mass accelerations. Equipment failures can be detected as they occur, rather than relying on similarity trials at the beginning and end of the day's production. Equipment faults can then be corrected as they happen and thus would not have a detrimental effect on the quality of the survey data. Source efficiency can be optimized by monitoring the amount of harmonic distortion generated by the vibrator at different drive levels on the different surfaces which may be encountered during a survey. Phase problems introduced by poor coupling of the baseplate to the ground can also be identified and addressed in the field. Rapid analysis of vibrator signals is required if continuous monitoring is to be useful. Frequency-time (f-t) analyses of vibrator signals are often used in processing centres, but are slow and require a large storage capacity which makes the technique unsuitable for a field analysis system. The two methods proposed to analyse vibrator signals entail the use of hodograms and time-varying notch filters. Hodograms provide a qualitative analysis of harmonic distortion and vibrator performance. A fast, time-varying notch filter gives quantitative and qualitative information about the harmonic distortion present in the signal and can be used to identify problems with vibrator behaviour. Both the hodogram and fast, time-varying notch filter methods can analyse the vibrator's reaction mass and baseplate accelerations as it progresses through its sweep and can present automatically interpreted results to the operator before moving to the next vibrator point.     

Palaeovalleys and protozoan assemblages in a Late Carboniferous cyclothem, Sydney Basin, Nova Scotia

The early Stephanian Bonar Cyclothem of the Sydney Basin, Nova Scotia, contains an erosional surface cut through coastal plain strata with economic coals and distributary channel bodies. The erosion surface is interpreted as a palaeovalley 20 m deep and at least 7 km wide that marks a sequence boundary formed during relative fall in sea level. The palaeovalley is filled with stacked alluvial channel bodies which become more isolated as the valley fill passes upward into red, alluvial plain deposits, probably laid down in an anastomosed river system. In an adjacent, interfluve area, calcretes and red, vertic palaeosols cap coastal strata. Assemblage analysis of agglutinated foraminifera and thecamoebians indicates that the palaeovalley was filled with freshwater sediments before an initial marine transgression flooded the alluvial surface and adjacent interfluve. Valley incision probably reflects glacioeustatic sea level fall. However, the alluvial nature of the valley deposits suggests that valley filling reflects an abundant sediment supply during lowstand and/or transgressive stages and was not a direct consequence of sea level rise. During the subsequent transgression phase, aggradation was rapid as sediment supply apparently kept pace with rising sea level. Features of both channel and extra-channel facies suggest that seasonality intensified during the transition from coastal plain to palaeovalley and alluvial plain deposition.     

Late Neanderthal occupation in North‐West Europe: rediscovery,investigation and dating of a last glacial sediment sequence at the site of La Cotte de Saint Brelade,Jersey

In 2011, a programme of field research was undertaken to effect the stabilization of an unstable section in the West Ravine at the key Neanderthal occupation site of La Cotte de St Brelade on the Channel Island of Jersey. As part of this essential remedial work the threatened section was analysed to characterize its archaeological and palaeoenvironmental potential as well provide optically stimulated luminescence (OSL) dates. The work determined, through two concordant OSL dating programmes, that the section formed part of an extensive sequence of sedimentation spanning >105 to <48 ka. Furthermore, reanalysis of the archive determined that the sediment sequence examined contained the stratigraphic equivalent of deposits lying below those that have previously produced Neanderthal fossils. Through our work, we can now constrain these younger sediments to being younger than 48 ka. The combined results suggest that this sequence now represents the recovery of an extensive dataset, thought lost to science through complete excavation, which holds the potential to throw light on the disappearance of Neanderthal populations from the Atlantic‐edge outpost on the north‐west frontier of their world.     

Skillful Seasonal Forecasts of Summer Surface Air Temperature in Western China by Global Seasonal Forecast System Version 5

Variations of surface air temperature(SAT) are key in affecting the hydrological cycle,ecosystems and agriculture in western China in summer.This study assesses the seasonal forecast skill and reliability of SAT in western China,using the Glo Sea5 operational forecast system from the UK Met Office.Useful predictions are demonstrated,with considerable skill over most regions of western China.The temporal correlation coefficients of SAT between model predictions and observations are larger than 0.6,in both northwestern China and the Tibetan Plateau.There are two important sources of skill for these predictions in western China:interannual variation of SST in the western Pacific and the SST trend in the tropical Pacific.The tropical SST change in the recent two decades,with a warming in the western Pacific and cooling in the eastern Pacific,which is reproduced well by the forecast system,provides a large contribution to the skill of SAT in northwestern China.Additionally,the interannual variation of SST in the western Pacific gives rise to the reliable prediction of SAT around the Tibetan Plateau.It modulates convection around the Maritime Continent and further modulates the variation of SAT on the Tibetan Plateau via the surrounding circulation.This process is evident irrespective of detrending both in observations and the model predictions,and acts as a source of skill in predictions for the Tibetan Plateau.The predictability and reliability demonstrated in this study is potentially useful for climate services providing early warning of extreme climate events and could imply useful economic benefits.     

Isotopic composition and origin of polar precipitation in present and glacial climate simulations

The Hamburg atmospheric general circulation model (AGCM) ECHAM‐4 is used to identify the main source regions of precipitation falling on Greenland and Antarctica. Both water isotopes H₂¹⁸O and HDO are explicitly built into the water cycle of the AGCM, and in addition the capability to trace water from different source regions was added to the model. Present and LGM climate simulations show that water from the most important source regions has an isotopic signature similar to the mean isotope values of the total precipitation amount. But water from other source regions (with very different isotopic signatures) contributes an additional, non‐negligible part of the total precipitation amount on both Greenland and Antarctica. Analyses of the temperature‐isotope‐relations for both polar regions reveal a solely bias of the glacial isotope signal on Greenland, which is caused by a strong change in the seasonal deposition of precipitation originating from nearby polar seas and the northern Atlantic. Although the performed simulations under LGM boundary conditions show a decrease of the δ ¹⁸O values in precipitation in agreement with ice core measurements, the AGCM fails to reproduce the observed simultaneous decrease of the deuterium excess signal.     

Dolomite formation in the dynamic deep biosphere: results from the Peru Margin

Early diagenetic dolomite beds were sampled during the Ocean Drilling Programme (ODP) Leg 201 at four reoccupied ODP Leg 112 sites on the Peru continental margin (Sites 1227/684, 1228/680, 1229/681 and 1230/685) and analysed for petrography, mineralogy, δ¹³C, δ¹⁸O and ⁸⁷Sr/⁸⁶Sr values. The results are compared with the chemistry, and δ¹³C and ⁸⁷Sr/⁸⁶Sr values of the associated porewater. Petrographic relationships indicate that dolomite forms as a primary precipitate in porous diatom ooze and siliciclastic sediment and is not replacing the small amounts of precursor carbonate. Dolomite precipitation often pre‐dates the formation of framboidal pyrite. Most dolomite layers show ⁸⁷Sr/⁸⁶Sr‐ratios similar to the composition of Quaternary seawater and do not indicate a contribution from the hypersaline brine, which is present at a greater burial depth. Also, the δ¹³C values of the dolomite are not in equilibrium with the δ¹³C values of the dissolved inorganic carbon in the associated modern porewater. Both petrography and ⁸⁷Sr/⁸⁶Sr ratios suggest a shallow depth of dolomite formation in the uppermost sediment (<30 m below the seafloor). A significant depletion in the dissolved Mg and Ca in the porewater constrains the present site of dolomite precipitation, which co‐occurs with a sharp increase in alkalinity and microbial cell concentration at the sulphate–methane interface. It has been hypothesized that microbial ‘hot‐spots’, such as the sulphate–methane interface, may act as focused sites of dolomite precipitation. Varying δ¹³C values from −15‰ to +15‰ for the dolomite are consistent with precipitation at a dynamic sulphate–methane interface, where δ¹³C of the dissolved inorganic carbon would likewise be variable. A dynamic deep biosphere with upward and downward migration of the sulphate–methane interface can be simulated using a simple numerical diffusion model for sulphate concentration in a sedimentary sequence with variable input of organic matter. Thus, the study of dolomite layers in ancient organic carbon‐rich sedimentary sequences can provide a useful window into the palaeo‐dynamics of the deep biosphere.     

DIVIDING THE OCEAN SEA*

ABSTRACT. The conventional view of global hydrography, which maps three or four oceans (Pacific, Atlantic, Indian, and, sometimes, Arctic) did not emerge until the late nineteenth and early twentieth centuries. Previously, markedly different conceptions of sea space prevailed, conceptions that changed not only to reflect new discoveries but also in accordance with changing intellectual fashions. By examining the history of global hydrography and by entertaining novel schemes of oceanic division, one can see the world afresh and perhaps discover connections that are obscured by conventional geographical divisions.     

Sunset on Heimdall's Stones. A View from Archaeology and Archaeoastronomy of the Ravlunda 169 Iron Age Cemetery

Salt, A. and Rundkvist, M., 2011. Letter to the editor: Sunset on Heimdall's stones. A view from archaeology and archaeoastronomy of the Ravlunda 169 Iron Age cemetery. Geografiska Annaler: Series A, Physical Geography, 93, 193–196. DOI: 10.1111/j.1468‐0459.2011.00428.x