Partitioning of polycyclic aromatic hydrocarbons between water and particles compared to bioaccumulation in mussels: a harbour case

Water and particles from three sites located in Halifax Harbour, near and further away from combined municipal sewage effluents (CMSE) were analysed for parental and alkylated polycyclic aromatic hydrocarbons (par and alkPAH). Bioavailability of PAH was compared for inter-tidal mussels collected at the same sites in April and November. The PAH fingerprint determined over 9 sampling times covering a period of 19 months differed more between phases (water and particles) and seasons, than between sites. In the spring, more alkPAH associated with diesel and gasoline were detected in the soluble phase, along with more bioaccumulation of alkPAH in inter-tidal mussels. A broader number of parPAH were detected in mussels collected in the fall. The mean sum of dissolved alkPAH concentrations was higher in water at the site closer to raw CMSE than at the other two sites and particles of that site. However, lowest bioconcentration factors (BCF) were determined in mussels of this more contaminated site. Similar biota-particle accumulation factors (BPAF) were determined for parPAH in mussels from the three sites, all lower than the BCF of alkPAH. The study indicates that sewage treatment plants will reduce the amount of parPAH especially larger than fluoranthene and pyrene from being deposited in the harbour; that alk naphthalenes and fluorenes present in water will continue to be discharged; that the disturbance of sediments can make particle-bound PAH available to mussels.     

Characteristics, Formation Periods, and Controlling Factors of Tectonic Fractures in Carbonate Geothermal Reservoirs: A Case Study of the Jixianian System in the Xiong’an New Area, China

As typical carbonate geothermal reservoirs with low porosity in northern China, the Jixianian System in the Xiong’an New Area is the main target for geothermal fluid exploration. The Jixianian System comprises the Gaoyuzhuang, Yangzhuang, Wumishan, Hongshuizhuang, and Tieling formations. The characteristics, formation periods, and controlling factors of reservoir tectonic fractures have been determined based on analyses of outcrops, cores, thin sections, and image logs. The results show that unfilled fractures account for over 87% and most tectonic fractures are high-angle shear fractures with angles concentrated at 40° to 70° and the fracture porosity increases linearly with an increased fracture aperture. Within the same tectonic setting and stress field, the lithology and layer thickness are the dominant factors governing the development of tectonic fractures, which are the most developed in dolomites and thin layers. Tectonic fractures were most likely formed in regions near faults or areas with larger stress gradients. The tectonic fractures in the carbonate geothermal reservoirs are roughly divided into four sets: NNW–SSE and NNE–SSW oriented ‘X’-conjugated shear fractures formed from the Paleozoic to the pre-Yanshanian Movement; NE–SW-oriented shear fractures, formed in episode B of the Yanshanian Movement, occurred at the Early Cretaceous; nearly E–W-oriented tensional fractures formed in the late Yanshanian Movement at the Late Cretaceous to Paleogene, and NEE–SW-oriented shear fractures formed during the Himalayan movement.     

Pathogenic fungi: an unacknowledged risk at coastal resorts? New insights on microbiological sand quality in Portugal

Whilst the potential impact on beach users from microorganisms in water has received considerable attention, there has been relatively little investigation into microbial contaminants in sand. Thirty three beaches across Portugal were analyzed during a five year period (2006-2010) to determine the presence of yeasts, pathogenic fungi, dermatophytes, total coliforms, Escherichia coli and intestinal enterococci in sand.Our results showed that 60.4% of the samples were positive for fungi and that 25.2% were positive for the bacterial parameters. The most frequent fungal species found were Candida sp. and Aspergillus sp., whereas intestinal enterococci were the most frequently isolated bacteria. Positive associations were detected among analyzed parameters and country-regions but none among those parameters and sampling period.Regarding threshold values, we propose 15 cfu/g for yeasts, 17 cfu/g for potential pathogenic fungi, 8 cfu/g for dermatophytes. Eighty four cfu/g for coliforms, 250 cfu/g for E. coli, and 100 cfu/g for intestinal enterococci.     

The relationship between soft-bottom macrobenthic communities and environmental variables off Ningjin, eastern Shandong Peninsula

Macrobenthic infauna and associated environmental factors influencing the benthic community in the eastern coastal region of Shandong Peninsula were analyzed in four seasonal surveys from January 2007 to October 2007 (30 stations in winter, 20 stations in other three seasons), in order to understand the community structure and the factors unfluencing the benthic distribution. PRIMER 6.0 and SPSS 15.0 software packages were adopted to analyze the environmental and macrobenthic data. The results show that there were 260 macrobenthic species in total collected from the research region. The composition of species is:Polychaeta (94 species), Crustacea (75), Mollusca (56) and Echinoderm (12), among which, only 23 species were common species in the cruises of every season. The dominant species varied from season to season; however, the polychaete species Paralacydonia paradoxa Fauvel and Echinoderm species Amphioplus japonicus (Matsumoto) were always present year-round. The abundance and biomass of the macrobenthos in the research region were variable from season to season. The results of CLUSTER and MDS analysis show that the similarities of macrobenthic structures between the stations were low; most of the similarities were at about 30% of similarity value, only two stations were up to 70%. In accordance with the similarity values of the macrobenthic structures, we divided the 20 stations into five groups by arbitrary similarity level of 30%. The ABC curve indicates that the marcofauna communities in the research region had not been disturbed massively, except two stations, SB1 and SB3. Ecologically, benthos were controlled by a combination of factors such as salinity, phytoplankton, zooplankton, SiO₃-Si and temperature, and no single factor could be considered as an ecological master factor.     

Titanium Isotope Analysis of Igneous Reference Materials using a Double-spike MC-ICP-MS Method

Ti separation was achieved by ion-exchange chromatography using Bio-Rad AG 1-X8 anion-exchange and DGA resins. For high-Fe/Ti and high-Mg/Ti igneous samples, a three-column procedure was required, whereas a two-column procedure was used for low-Fe/Ti and low-Mg/Ti igneous samples. The Ti isotopes were analysed by MC-ICP-MS, and instrumental mass bias was corrected using a 47Ti-49Ti double-spike technique. The 47Ti-49Ti double-spike and SRM 3162a were calibrated using SRM 979-Cr, certificated value 53Cr/52Crtrue = 0.11339. Isobaric interference was evaluated by analysing Alfa-Ti doped with Na, Mg, Ca, and Mo, and results indicate that high concentrations of Na and Mg have no significant effect on Ti isotope analyses; however, Ca and Mo interferences lead to erroneous δ49/47Ti values when Ca/Ti and Mo/Ti ratios exceed 0.01 and 0.1, respectively. Titanium isotopic compositions were determined for 12 igneous reference materials, BCR-2, BHVO-2, GBW07105, AGV-1, AGV-2, W-2, GBW07123, GBW07126, GBW07127, GBW07101, JP-1, and DTS-2b. Samples yield δ49/47Ti (‰) of ?0.035 ± 0.022, ?0.038 ± 0.031, 0.031 ± 0.022, 0.059 ± 0.038, 0.044 ± 0.037, 0.000 ± 0.015, 0.154 ± 0.044, ?0.044 ± 0.018, 0.010 ± 0.022, 0.064 ± 0.043, 0.169 ± 0.034, and ?0.047 ± 0.025 (relative to OL-Ti, ±2SD), respectively; of which isotopic compositions of DTS-2b, JP-1, GBW07101, GBW07105, GBW07123, GBW07126, and GBW07127 are reported for the first time. Standard Alfa-Ti was analysed repeatedly over a ten-month period, indicating a reproducibility of ±0.047 (2SD) for δ49/47Ti, similar to the precisions obtained for geochemical reference materials.     

The Quantitative Assessment System for Brine Resource Industry Based on Sustainable Development Theory:a Case Study on Xitai-Jinaier Lake,Qinghai,China

正Salt lake resource is one of preponderant and strategic mineral resources in China.Some important chemical elements contained in brine are highly significant to both agriculture security and national security.Given the     

美国外陆架区油气资源评价报告

美国外陆架区油气资源评价报告美国内务部矿物管理局在对该国滨外未勘探的原油和天然气气资源进行了数年研究、分析之后，于１９９６年６月发表了一题为“国家外陆架未勘探油气潜力评价”的报告，对美国外陆架的可开采油气资源作了鉴别和分析，并对过去１４年的两项全国性...     

Farmers＇ vulnerability to flood risk： A case study in the Poyang Lake Region

This paper quantitatively explores farmers＇ vulnerability to flood in the Poyang Lake Region （PLR） with the supports of GIS spatial functions. The analysis consists of three major steps, which is based on the spatial unit of township. Firstly, the spatial extent and characteristics of flood risk areas were determined using a digital elevation model （DEM） derived from the 1：50,000 topographic map. Secondly, for each of the township, six indices indicating the economic activities of local farmers were calculated. These indices are： rural population proportion, cultivated land proportion, GDP per unit area, employment proportion of primary industry, net rural income per capita and agricultural income proportion. These six indices were then normalized and used for later vulnerability assessment. Thirdly, the normalized indices （as GIS data layers） were overlaid with the flood risk areas to produce the risk coefficient for each township and to calculate the overall vulnerability for each township. The analysis results show that in the PLR there are high flood risk areas where the farmers＇ livings are seriously influenced or threatened. About 55.56% of the total 180 townships in the flood risk areas have a high degree of flood vulnerability. The townships under flood risk are mainly distributed in the areas around the Poyang Lake and the areas along the ＂five rivers＂.     

The Existence and Significance of Two Kinds of Effective Reservoirs in Deep Water Area of the Western Qaidam Basin

<正>Objective Deep-water deposit has become one of the greatest potential and economic areas for petroleum exploration. In the western Qaidam Basin, the deep-water sedimentary area account for nearly 2/3 of the basin area, but the related reports is less. Scholars generally believed that the salt water medium can inhibit the extension of the sand(Qian et al., 1984).     

The Characteristics and Causes of Land Subsidence in Tanggu Based on the GPS Survey System and Numerical Simulation

Land subsidence is a severe hazard threatening Tanggu, a flat lowland area, and evidences of land subsidence can be seen throughout the city. A new reasonable GPS network was set up in this area from 2008 to 2010. The monitoring data show that land subsidence was serious and two main subsidence cones were obviously formed in the region. One emerged at Hujiayuan, with the maximum rate reaching 60 mm/a, and the influence region enlarged prominently from 2005 to 2010. The other one occurred at Kaifaqu, which became obvious only after 2005, and it showed a decreasing tendency with time. To analyze the causes of ground settlement, a correlation between groundwater withdrawal and land subsidence was firstly made. The results confirmed that over-exploitation of groundwater was the major cause for the severe settlement in Hujiayuan. Meanwhile, the subsidence of Kaifaqu was also related to groundwater withdrawal before 2005. However, the relationship became unconspicuous after 2005. To find the cause of this abnormity, a three-dimensional finite element numerical model, coupled with groundwater flow and subsidence, was built. The simulation results indicate that the subsidence induced by high-rise buildings is serious, but the affected range is limited and it also shows a decreasing trend with time, corresponding to the subsidence characteristics at Kaifaqu. Therefore, more attention should be paid to this hazard induced by engineering construction besides groundwater withdrawal, as more high-rise buildings are under construction in Tanggu.