Bildung bromhaltiger Desinfektionsnebenprodukte nach Chlorung von Bodenseewasser in Abhängigkeit von Aufbereitungsschritten und der Bromidkonzentration

Formation of Brominated Disinfection By-products after Chlorination of Water from Lake Constance Depending on Treatment Steps and Bromide Concentration The formation of halogenated disinfection by-products (DNP) (trihalomethanes (THM), haloacetic acids (HES), haloacetonitriles (HAN), haloketones (HKE) and chloropicrin (TCNM)) was studied after chlorination (0.5 mg/L) of raw water and drinking water from Lake Constance. The objectives of this study were to investigate the effect of bromide ion on the distribution of DNP-species resulting from chlorination and to draw up a bromide mass-balance. The treatment of water from Lake Constance with ozone decreased the formation of DNP about 35% and of total organic halogens (AOX) about 45%. This decline in DNP-formation is mainly due to the formation of chloroform, dichloro- and trichloroacetic acid. Though there is only a small amount of bromide (6.2 μg/L) in water from Lake Constance, about 32% of THM, 16% of HES, and 30% of HAN contained bromine after chlorination of treated water. The addition of bromide ion (up to 1 mg/L) shifted the DNP-composition to more brominated species. The distribution of the DNP-species depends on the initial molar bromide-to-chlorine ratio. A mathematic model showed the same pattern of DNP-species depending on the initial molar bromide-to-chlorine ratio that was observed experimentally in microstrained raw water and drinking water from Lake Constance. After chlorination of microstrained raw water, 27% of the bromide were incorporated in known DNP, 34% in unknown substances, and about 39% of bromide were not converted to organic bromine. After chlorination of treated water, only 16% of the bromide were incorporated in unknown substances, whereas 34% were found in known DNP. About 50% were found as bromide again. After addition of bromide (up to 25 μg/L) to ozonated and treated water from Lake Constance, between 60 and 72% of the bromide that had reacted after chlorination were found in analyzed low-molecular DNP.     

Archaeal Communities of Frozen Quaternary Sediments of Marine Origin on the Coast of Western Spitsbergen

Izvestiya, Atmospheric and Oceanic Physics - The archaeal composition of permafrost samples taken during the drilling of frozen marine sediments in the area of the Barentsburg coal mine on the east...     

Landslide susceptibility analysis with a heuristic approach in the Eastern Alps (Vorarlberg, Austria)

The aim of the study is landslide hazard assessment carried out on a working scale of 1:25 000. The study area within the Northern Calcareous Alps was geologically and geotechnically mapped in order to identify causes and mechanisms of active mass movements. The field surveys were digitised by a Geographical Information System and divided into data layers. The geological units were classified according to their geotechnical properties. All layers were converted into grids and spatially analysed together with a Digital Elevation Model. Comparing the layers with the inventory of active landslides, the prevailing factors leading to sliding movements were identified. Because of the complex tectonic setting and the small number of active landslides, a statistical method of hazard assessment was not applicable. Using the heuristic approach of an index method, the data layers of geotechnical class, bedding conditions, tectonic layouts, slope angles, slope orientations, vegetation and erosion were analysed. The susceptibility of each layer has been evaluated with help of bivariate statistics. The layers have been weighted with indices due to their importance iteratively and were combined into a landslide susceptibility map.     

Paleohydrology and paleoclimate records in a saline prairie lake core: mineral,isotope and organic indicators

This pilot study examines the potential of obtaining a sedimentary record of paleoenvironmental/climatic/hydrologic conditions for saline Redberry Lake in southern Saskatchewan, Canada. The tools are mineralogy, stable isotopes and pigments. The upper meter of an offshore sediment core contains 10 to 20% by weight aragonite (CaCO₃), which apparently precipitated in the water column. The ¹⁸O and ¹³C of the bulk aragonite (corrected for content of detrital calcite) vary by 4 to 5. Enrichment in ¹⁸O in aragonite is significantly correlated with pigment concentrations (chlorophyll a, phaeophytin). The ¹⁸O and pigment data provide evidence for relatively dry and/or warm conditions and high limnetic productivity for the period 2500 to 1500 yrs B.P. After 1500 B.P., the climate was apparently similar to the present, with two episodes of relatively enhanced productivity, dryness and/or warmth, at around 1000 to 900 and 500 to 200 B.P. During the past century, Redberry Lake has decreased approximately 8 m in depth and its salinity has doubled. No clear sedimentary signal was observed in response to these recent hydrologic trends. These changes have not been associated with a significant climate trend in the region, but may have been induced by land use changes in the catchment.This publication is the third of a series of papers presented at the Conference on Sedimentary and Paleolimnological Records of Saline Lakes. This Conference was held August 13–16, 1991 at the University of Saskatchewan, Saskatoon, Canada. Dr. Evans is serving as Guest Editor for this series.     

Optical Fiber Interferometers for Referencing Surface Benchmarks to Depth

—We have developed and operated optical fiber interferometers for monitoring displace ments within boreholes, as part of a program of crustal deformation measurement. These optical fiber strainmeters—a total of twelve instruments at two sites in southern California—were installed to sense the motion of the end-monuments of much longer baseline strainmeters and tiltmeters, allowing correction for any near-surface ground movement. One of the installations was specifically designed to investigate the distribution of deformation with depth, measuring over several borehole length-intervals from 5 m to 50 m. The displacements recorded over year-long time scales along these length intervals range up to 6 mm and show internal consistency and stability at the 50 μ m level. The use of these interferometers to provide correction signals for kilometer-scale crustal strain measurements has resulted in greatly improved records.     

The Sumba enigma: Is Sumba a diapiric fore-arc nappe in process of formation?

The anomalous updomed morphological expression of Sumba island, its enigmatic lack of strong Neogene deformation and the northward morphological indentation of southern Sumbawa and Flores require explanation.The stratigraphy of Sumba may be correlated with the Cretaceous to Miocene part of the Timor allochthon. The sedimentary and eruptive rock succession in Sumba shows remarkable similarities with the allochthonous Palelo, Wiluba and Cablac deposits of Timor. In both islands the Cretaceous parts of these sequences are regarded as characteristic of fore-arc deposits built on thin continental crust.The Timor nappe is interpreted as a 5 km thick tectonic flake of the Banda fore-arc thrust onto the Australian continental margin in the mid-Pliocene collision. The postulated Sumba nappe has not yet been thrust onto the Australian margin which, in the Sumba region, has not yet converged as close to the arc as in the Timor area. The postulated Sumba nappe is interpreted as a diapiric elongated dome of the Sunda fore-arc that is being squeezed by the converging margin of Australia against the volcanic islands of Sumbawa and Flores.The absence of indications on the seismic reflection profiles for the presence of the thrust fault of the Sumba nappe may perhaps be explained by the thrusts being nearly horizontal within flat-lying strata.The Savu thrust is correlated with the probably older (pre-Late Pliocene) Wetar Suture as a major southward dipping lithospheric rupture. East of 124°E, this suture does not seem to have moved much since the mid-Pliocene collision that emplaced the nappes on Timor. However, microearthquake data suggest some activity is continuing.     

Wollastonite at Nuliyam,Kerala, southern India: a reassessment of CO2-infiltration and charnockite formation at a classic locality

The occurrence of a charnockitised felsic gneiss adjacent to a marble/calc-silicate horizon at Nuliyam, southern India, has been cited in recent literature as a classic example of the dehydration of crustal rocks resulting from the advective infiltration of CO₂-rich fluids generated from a local carbonate source. Petrographic study of the Nuliyam calc-silicate, however, reveals it to consist of abundant wollastonite and scapolite and contain locally discordant veins rich in wollastonite. At the pressure—temperature conditions proposed for charnockite formation in recent studies, 5 kbar and 725°C, this wollastonite-bearing mineral assemblage was stable in the presence of a fluid phase only if X _CO2 was near 0.25 and could not have coexisted with the fluid causing biotite breakdown and charnockite development in adjacent rocks (X _CO2>0.85). The stable coexistence of wollastonite and scapolite prohibits the calc-silicate from being a source for fluid driving charnockitisation at the required P-T conditions. Textural observations such as the limited replacement of wollastonite by calcite+quartz symplectites and mosaics, are consistent with late fluid infiltration into the calc-silicate. The extensive isotopic, chemical and mineral abundance data of Jackson and Santosh (1992) are re-interpreted and integrated with these observations to develop a model involving the infiltration of an externally derived CO₂-rich fluid during high-temperature decompression. Increased charnockite development next to the calc-silicate has arisen because the calc-silicate acted as a relatively unreactive and impermeable barrier to fluid transport and caused fluid ponding beneath antiformal closures. The Nuliyam charnockite/calc-silicate locality is an example of a structural trap in a metamorphic setting rather than a site where charnockite formation can be attributed to local fluid sources.     

MODELLING LONG‐TERM SUMMER AND WINTER BALANCES AND THE CLIMATE SENSITIVITY OF STORBREEN,NORWAY

Measurements of winter balance (b_w) and summer balance (b_s) have been carried out at Storbreen since 1949. Here we apply a simple mass balance model to study the climate sensitivity and to reconstruct the mass balance series priorto 1949. The model is calibrated and validated with data from an automatic weather station (AWS) operating in the ablation zone of Storbreen since 2001. Regression analysis revealed that b_w was best modelled using precipitation data southwest of the glacier. Results from the model compared well with reported mass balance values for the period 1949–2006, obtained correlations (r) for b_w and b_s varied between 0.83 and 0.87 depending on model set up. Reconstruction of the mass balance series for the period 1924/1925–1948/1949 suggested a cumulative mass deficit of c. 30 m w.e. mainly due to highly negative summer balances, but also lower b_wthan the average for 1949–2006. Calculated change in specific mass balance for a ±1°C change in air temperature was ±0.55 m w.e., whereas a ±10 % increase in precipitation represented a change of ±0.20 m w.e. Model results further indicated that for a 2°C warming, the ablation season will be extended by c. 30 days and that the period of ice melt at the AWS location will increase from c. 40 to c. 80 days.