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331.
332.
The ionization quotients of aqueous carbon dioxide (carbonic acid) have been precisely determined in NaCl media to 5 m and from 50° to 300°C using potentiometric apparatus previously developed at Oak Ridge National Laboratory. The pressure coefficient was also determined to 250°C in the same media. These results have been combined with selected information in the literature and modeled in two ways to arrive at the best fits and to derive the thermodynamic parameters for the ionization reaction, including the equilibrium constant, activity coefficient quotients, and pressure coefficients. The variation with temperature of the two fundamental quantities and were examined along the saturation vapor pressure curve and at constant density. The results demonstrated again that for reactions with minimal electrostriction changes the magnitudes and variations of and with temperature are small and, in addition, and are approximately independent of salt concentration.The results have also been applied to an examination of the solubility of calcite as a function of pH (in a given NaCl medium) for the neutral to acidic region both for systems with fixed CO2 pressure and systems where the calcium ion concentration equals the concentration of carbon. The pH of saturated solutions of calcite with PCO2 of 12 bars increases from 5.1 to 5.5 between 100° and 300°C. 相似文献
333.
N and O isotope effects during nitrate assimilation by unicellular prokaryotic and eukaryotic plankton cultures 总被引:4,自引:0,他引:4
In order to provide biological systematics from which to interpret nitrogen (N) and oxygen (O) isotope ratios of nitrate (15N/14N, 18O/16O, respectively) in the environment, we previously investigated the isotopic fractionation of nitrate during its assimilation by mono-cultures of eukaryotic algae (Granger et al., 2004). In this study, we extended our analysis to investigate nitrate assimilation by strains of prokaryotic plankton. We measured the N and O isotope effects, 15ε and 18ε, during nitrate consumption by cultures of prokaryotic strains and by additional eukaryotic phytoplankton strains (where ε is the ratio of reaction rate constants of the light vs. heavy isotopologues, lightk and heavyk; ε = lightk/heavyk − 1 × 1000, expressed in per mil). The observed 15ε ranged from 5‰ to 8‰ among eukaryotes, whereas it did not exceed 5‰ for three cyanobacterial strains, and was as low as 0.4‰ for a heterotrophic α-protoeobacterium. Eukaryotic phytoplankton fractionated the N and O isotopes of nitrate to the same extent (i.e., 18ε ∼ 15ε). The 18ε:15ε among the cyanobacteria was also ∼1, whereas the heterotrophic α-proteobacterial strain, which showed the lowest 15ε, between 0.4‰ and 1‰, had a distinct 18ε:15ε of ∼2, unlike any plankton strain observed previously. Equivalent N vs. O isotope discrimination is thought to occur during internal nitrate reduction by nitrate reductase, such that the cellular efflux of the fractionated nitrate into the medium drives the typically observed 18ε:15ε of ∼1. We hypothesize that the higher in the 18ε:15ε of the α-proteobacterium may result from isotope discrimination by nitrate transport, which is evident only at low amplitude of ε. These observations warrant investigating whether heterotrophic bacterial assimilation of nitrate decreases the community isotope effects at the surface ocean. 相似文献
334.
Integration of reflection seismic and sediment grain-size data from Lake Khubsugul (Northern Mongolia): a reply to Prokopenko and Kendall 总被引:1,自引:0,他引:1
Prokopenko and Kendall (J Paleolimnol doi:, 2008) criticise the work presented in Fedotov et al. (J Paleolimnol 39:335–348, 2008), and instead propose an alternative
interpretation for the grain-size evolution recorded in the KDP-01 core, retrieved from the central part of Lake Khubsugul.
Their interpretation is based (i) on a seismic-stratigraphic re-interpretation of sparker seismic profile khub012 (which they
copied from Fedotov et al. (EOS Trans 87:246–250, 2006)), (ii) on the presupposition that changes in lake level are the dominant
control on facies distribution in Lake Khubsugul, and (iii) on the invalidation of our age-depth model. In this reply to their
comment, we demonstrate that they interpreted seismic artefacts and geometries caused by changes in profile orientation as
true stratigraphic features and that the lake-level reconstruction they derive from this interpretation is therefore incorrect.
We also demonstrate that their grain-size predictions, which they consider to be predominantly driven by changes in lake level,
are inconsistent with the measured sulphate concentration, which is a demonstrated proxy of lake level in Lake Khubsugul,
and with the measured grain-size record. Finally, we point out that even if there would be a problem with the age-depth model,
this problem would not affect the part of the sedimentary sequence discussed in Fedotov et al. (J Paleolimnol 39:335–348,
2008). 相似文献
335.
Long-term observational data (1992?C2009) on heavy metal (Cu, Zn, Pb, Cr, Ni, V, Mo, Co, Fe, and Mn) content of different links in the Ivankovo Reservoir ecosystem are used to consider the regularities in the distribution and behavior of heavy metals in the system anthropogenic pollution sources-reservoir and its drainage area, thus enabling the assessment of the pollution level of the Volga Source of water supply to Moscow. 相似文献
336.
Summary . Born inverse methods give accurate and stable results when the source wavelet is impulsive. However, in many practical applications (reflection seismology) an impulsive source cannot be realized and the inversion needs to be generalized to include an arbitrary source function. In this paper, we present a Born solution to the seismic inverse problem which can accommodate an arbitrary source function and give accurate and stable results. It is shown that the form of the generalized inversion algorithm reduces to a Wiener shaping ***filter, which is solved efficiently using a Levinson recursion algorithm. Numerical examples of synthetic and real field data illustrate the validity of our method. 相似文献
337.
M.?A.?LevitanEmail author T.?N.?Gelvi K.?V.?Syromyatnikov K.?D.?Chekan 《Geochemistry International》2018,56(4):304-317
Lithofacies zoning is described for the first time for the Neo- and Eopleistocene of the Bering Sea. Four lithofacies sedimentation zones are distinguished: (I) terrigenous; (II) siliceous–terrigenous; (III) siliceous, and (IV) volcanoterrigenous ones. Corresponding maps were treated using Ronov volumetric method to quantify sedimentation parameters for distinguished lithofacies zones (subzones) and types of Pleistocene sediments. It was revealed that terrigenous sediments predominate over other sediments. Accumulation of the terrigenous sediments was more intense (by 1.4 times) in the Neopleistocene than in the Eopleistocene. The sedimentation rate of siliceous sediments of the Bowers Ridge in the Eopleistocene was two times higher than in the Neopleistocene. 相似文献
338.
D. M. Morrison 《Pure and Applied Geophysics》1989,129(3-4):619-645
Microseismic systems at five mines in the Sudbury Basin provide the basic data for Falconbridge Limited's rockburst research. Daily and long-term analysis of this data as well as underground observations have confirmed the fault-slip mechanism at three mines. A detailed analysis of the complete history of Falconbridge Mine is being conducted and Distinct Element numerical models are being used to simulate both the stick-slip behaviour of faults and the dynamic effects of the induced vibrations on rock and backfill. University research includes acoustic tomographic imaging of the rock mass based on seismic wave propagation and collection of full microseismic waveforms to allow application of advanced seismic and statistical analysis techniques.Formerly with Mines Technical Services, Falconbridge Limited, Sudbury Operations, Falconbridge , Ont., P0M 1S0.Presented at the Fred Leighton Memorial Workshop on Mining Induced Seismicity, Montreal, Canada, August 30, 1987. 相似文献
339.
Current plate motions 总被引:57,自引:0,他引:57
340.