Adsorption und Hydrolyse von Methylparathion an Aktivkohle und Adsorberharz Adsorption and Hydrolysis of Methyl Parathion (MPT) on Activated Carbon and Adsorption Resin

Investigating adsorption of methyl parathion on the activated carbons Filtrasorb 400 and F 44 and on the adsorption polymer Wofatit Y 77 we found a stronger adsorption on the carbons at smaller concentration whereas the resin has the larger capacity at higher concentration. Adsorbents were regenerated through hydrolysis of the pesticide at pH = 11.7. The velocity of hydrolysis in the adsorbed state is reduced to a tenth of that in solution. However, a transport resistance in the pores of adsorbents seems to be negligible as may be concluded from the very small measured particle diameter dependence of the velocity constants. In adsorption-regeneration measurements the capacity of the adsorbents stabilized at about 70% of that of the fresh adsorbents.     

Species Composition and Some Ecological Notes on Diatom Communities of a Lotic Environment in Tarhunãh,Libya Artenzusammensetzung und einige ökologische Notizen über Diatomeengesellschaften eines lotischen Biotops in Tarhunãh/Libyen

Libya occupies a large part of the Sahara Desert, and is a predominantly arid country with extremely scarce freshwaters. Despite aridity, a distinct higher rainfall zone exists along its mediterranean coastal belt. A lotic environment (perennial stream) in Ain-Scersciara, Tarhunãh in northwest Libya was studied for the species composition of diatom communities and their ecological characteristics. The waters are generally alkaline (pH = 7.5) and of hard-water (conductivity = 2008 μS/cm) type. The epiphytic diatom growth on benthic filamentous algae was high (32 taxa) with Amphora veneta as a very common taxon. Gomphonema parvulum var. micropus was an important taxon found in scrapings from the leaves of macrophytes and stony substratum. Nitzschia and Navicula showed high species richness (9 taxa in each) followed by Gomphonema (6 taxa). The ecological attributes of the majority of taxa show an oligohalobe status and alkaliphilous indicator.     

Methods of Analyzing Qninones in Water and Their Application in Studying the Effects of Hydrophytes on Phenols. Part 1: Quinone Determination with Benzene Sulfinic Acid

By the example of some phenols and qninones, in aqueous solutions possibilities for the quantitative determination are tested separately and in the mixture. Methods for thin-layer chromatography and spectrophotometry were developed. There can be chromatographically deteeted between 5 and 80 μg of substance. Phenol and quinone concentrations of 1.5 · 10^?3 … 0.5 · 10^?4 M were spectrophotometrically investigated.     

Silicic differentiates of abyssal oceanic magmas: Evidence for late-magmatic vapor transport of potassium

Massive, nearly holocrystalline dolerites from DSDP Hole 417D contain from 0.5 to 1.5% of granophyric patches composed mainly of Na-plagioclase and quartz. These patches are compositionally similar to other crystalline silicic rocks from oceanic spreading centers and differ from rarer abyssal silicic glasses. Crystalline varieties withSiO₂60wt.% generally haveNa/K>10, whereas silicic glasses have Na/K in the range 3–6. While crystal fractionation readily accounts for the Na₂O and K₂O contents of abyssal silicic glasses, both the 417D granophyres and other crystalline abyssal silicic rocks have much lower K₂O than that predicted by any reasonable crystal-liquid fractionation model. We propose that high-temperature vapor phase transport is responsible for removal of potassium during late-stage crystallization of these rocks. This allows for the formation of cogenetic silicic glassy and crystalline rocks with greatly different Na/K ratios. These observations and interpretations lead to a more confident assignment of high Na/K silicic rocks of oceanic and ophiolitic environments to a cogenetic origin with basaltic oceanic crust.     

Diffraction of plane sh waves in a half-space

Scattering of antiplane shear waves (SH) in two dimensions by surface and near-surface defects in a homogeneous, isotropic elastic semi-infinite medium has been studied. Attention has been focused here in the range of medium to long wavelengths. A combined finite element and analytical technique has been used to study the problems of scattering by semi-circular and triangular canyons. The results for the former case are compared with the known exact solution and those for the latter case are compared with some available approximate solutions. Finally a problem of multiple scattering by a triangular canyon and a nearby circular tunnel is studied. Numerical results are presented showing the effects of multiple scattering and different angles of incidence. These results are of interest in earthquake engineering.     

A synthetic model for daily streamflow

This paper presents a model for synthesising daily average streamflow data that is suitable for most rivers in Great Britain. The method is based on a linear interpolation of the logorithms of 5-day average flows. The 5-day average flows are produced using N.T. Kottegoda's statistical model (Thesis, Univ. of Birmingham, 1970). The 5-day model preserves the long-term statistical characteristics of the daily data, while the short-term characteristics such as hydrograph shape are imposed by the interpolation method.

A stochastic error term is superimposed on the interpolated daily flows. This term represents the non-deterministic component of the daily time series. The analysis of the observed error terms represents an important part of this paper.

The riverflow in the Severn at Bewdley is used to demonstrate both the analysis of actual data and the generation of synthetic data. The technique is then applied to data from two other rivers with widely differing characteristics to demonstrate the range of the method.