Large-Scale Instability in Supernovae and the Neutrino Spectrum

Astronomy Reports - A large fraction of the energy released during the gravitational collapse of the core of a massive star is carried by neutrinos. Neutrinos play the main role in explaining...     

The Structure and Formation Conditions of the Callovian–Oxfordian Deposits of Sudak Bay (Crimea)

The composition and origin of the Callovian–Oxfordian deposits of the Sudak Bay were characterized on the basis of the generalization and analysis of our own results, as well as published and unpublished data. The botanical future was first implemented for the geological mapping of the Oxfordian deposits.     

Long-Term Geochemical Monitoring of the Source of the Angara River (Runoff from Lake Baikal)

The long-term data (1950–2017) on the chemical composition of the water from the source of the Angara River, which is the only run-off from Lake Baikal, a large and clean fresh water reservoir, are presented. The absence of water contamination despite the anthropogenic influence is shown. The similarity and constancy of the current composition of the waters in the lake and the Angara River are recorded. It is recommended to continue geochemical studies of this unique world heritage site.     

Clay Minerals in Basalt Sills from the Sediment Cover,East Pacific Rise

Clay minerals in basalt sills from the northern East Pacific Rise, covered by Upper Pleistocene clayey–sandy–silty sediments (turbidites, hemipelagites, and diatom oozes) sampled from DSDP Holes 477, 478, and 481A, were studied by X-ray methods based on the modeling of diffraction patterns. Trioctahedral smectites formed in thin (0.1–0.5 and 1.8–4 m) fissured sills that are well permeable for water delivered from the water-saturated host sediments heated by the sills. Smectites in basalts are found in the interstices (20–40 vol % in the rock and up to 50–80 vol % in hyalobasalts). They replace olivine and fill cracks and vesicles. Plagioclase and clinopyroxene are generally unaltered. The structure of smectites is characterized by different height of layers depending on the composition of cations in the interlayers and the degree of their hydration. The different-height layers either make up individual smectite phases or alternate in different proportions and with a high degree of segregation in the mixed-layer structures. Under conditions of a prolonged cooling, thick (43 m) sills are distinguished from the thin varieties by the formation of trioctahedral minerals (smectite–chlorite, chlorite, defective chlorite, and talc). They are found mainly in the interstices that make up 3–7 vol % of the rock.     

High temperature calorimetry of sulfide systems

The standard enthalpies of formation of FeS (troilite), FeS₂ (pyrite), Co_0.9342S, Co₃S₄ (linnaeite), Co₉S₈ (cobalt pentlandite), CoS₂ (cattierite), CuS (covellite), and Cu₂S (chalcocite) have been determined by high temperature direct reaction calorimetry at temperatures between 700 K and 1021 K. The following results are reported: $$\Delta {\rm H}_{f,FeS}^{tr} = - 102.59 \pm 0.20kJ mol^{ - 1} ,$$ $$\Delta {\rm H}_{f,FeS}^{py} = - 171.64 \pm 0.93kJ mol^{ - 1} ,$$ $$\Delta {\rm H}_{f,Co_{0.934} S} = - 99.42 \pm 1.52kJ mol^{ - 1} ,$$ $$\Delta {\rm H}_{f,Co_9 S_8 }^{ptl} = - 885.66 \pm 16.83kJ mol^{ - 1} ,$$ $$\Delta {\rm H}_{f,Co_3 S_4 }^{In} = - 347.47 \pm 7.27kJ mol^{ - 1} ,$$ $$\Delta {\rm H}_{f,CoS_2 }^{ct} = - 150.94 \pm 4.85kJ mol^{ - 1} ,$$ $$\Delta {\rm H}_{f,Cu_2 S}^{cc} = - 80.21 \pm 1.51kJ mol^{ - 1} ,$$ and $$\Delta {\rm H}_{f,CuS}^{cv} = - 53.14 \pm 2.28kJ mol^{ - 1} ,$$ The enthalpy of formation of CuFeS₂ (chalcopyrite) from (CuS+FeS) and from (Cu+FeS₂) was determined by solution calorimetry in a liquid Ni_0.60S_0.40 melt at 1100 K. The results of these measurements were combined with the standard enthalpies of formation of CuS, FeS, and FeS₂, to calculate the standard enthalpy of formation of CuFeS₂. We found \(\Delta {\rm H}_{f,CuFeS_2 }^{ccp} = - 194.93 \pm 4.84kJ mol^{ - 1}\) . Our results are compared with earlier data given in the literature; generally the agreement is good and our values agree with previous estimates within the uncertainties present in both.