Timing of UHP metamorphism in the Hong’an area,western Dabie Mountains,China: evidence from zircon U–Pb age,trace element and Hf isotope composition

The Hong’an area (western Dabie Mountains) is the westernmost terrane in the Qinling-Dabie-Sulu orogen that preserves UHP eclogites. The ages of the UHP metamorphism have not been well constrained, and thus hinder our understanding of the tectonic evolution of this area. LA-ICPMS U–Pb age, trace element and Hf isotope compositions of zircons of a granitic gneiss and an eclogite from the Xinxian UHP unit in the Hong’an area were analyzed to constrain the age of the UHP metamorphism. Most zircons are unzoned or show sector zoning. They have low trace element concentrations, without significant negative Eu anomalies. These metamorphic zircons can be further subdivided into two groups according to their U–Pb ages, and trace element and Lu–Hf isotope compositions. One group with an average age of 239 ± 2 Ma show relatively high and variable HREE contents (527 ≥ Lu_N ≥ 14) and ¹⁷⁶Lu/¹⁷⁷Hf ratios (0.00008–0.000931), indicating their growth prior to a great deal of garnet growth in the late stage of continental subduction. The other group yields an average age of 227 ± 2 Ma, and shows consistent low HREE contents and ¹⁷⁶Lu/¹⁷⁷Hf ratios, suggesting their growth with concurrent garnet crystallization and/or recrystallization. These two groups of age are taken as recording the time of prograde HP to UHP and retrograde UHP–HP stages, respectively. A few cores have high Th/U ratios, high trace element contents, and a clear negative Eu anomaly. These features support a magmatic origin of these zircon cores. The upper intercept ages of 771 ± 86 and 752 ± 70 Ma for the granitic gneiss and eclogite, respectively, indicate that their protoliths probably formed as a bimodal suite in rifting zones in the northern margin of the Yangtze Block. Young Hf model ages (T _DM1) of magmatic cores indicate juvenile (mantle-derived) materials were involved in their protolith formation. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Deep sea in situ excess pore pressure and sediment deformation off NW Sumatra and its relation with the December 26, 2004 Great Sumatra-Andaman Earthquake

The swath bathymetric data acquired during the “Sumatra Aftershocks” cruise from the Sunda trench in the Indian Ocean to the north of the Sumatra Island imaged several scars and deposits. In situ pore pressure measurements using the Ifremer piezometer and coring demonstrate that high excess pore pressure and sediment deformation was generated by a recent event in the scar of the slope failure zone identified by J.T. Henstock and co-authors. This excess pore pressure is localized in the upper sedimentary layers and is not related to an interplate subduction process. Numerical simulations of the hydrological system that take into account the hydro-mechanical properties of the upper sediment layer show that the excess pore pressure and sediment deformations could be generated at the time of the December 26, 2004 Great Sumatra Earthquake. The Sumatra Aftershocks team: J.-C. Sibuet, S. Singh, R. Apprioual, N.C. Aryanto, J. Begot, A. Cattaneo, A.P.S. Chauchan, R. Creach, J. Crozon, A. Domzig, N. Falleau, D. Graindorge, F. Harmegnies, Y. Haryadi, F. Klingelhoffer, S.K. Kolluru, J.-Y. Landuré, C. Le Lann, J. Malod, A. Normand, G. Oggian, C. Rangin, D. Restunin Galih, J.-L. Schneider, N. Sultan, M. Taufik, M. Umber and H. Yamaguchi.     

Nanoparticles in natural systems II: The natural oxide fraction at interaction with natural organic matter and phosphate

Information on the particle size and reactive surface area of natural samples and its interaction with natural organic matter (NOM) is essential for the understanding bioavailability, toxicity, and transport of elements in the natural environment. In part I of this series (Hiemstra et al., 2010), a method is presented that allows the determination of the effective reactive surface area (A, m²/g soil) of the oxide particles of natural samples which uses a native probe ion (phosphate) and a model oxide (goethite) as proxy. In soils, the natural oxide particles are generally embedded in a matrix of natural organic matter (NOM) and this will affect the ion binding properties of the oxide fraction. A remarkably high variation in the natural phosphate loading of the oxide surfaces (Γ, μmol/m²) is observed in our soils and the present paper shows that it is due to surface complexation of NOM, acting as a competitor via site competition and electrostatic interaction. The competitive interaction of NOM can be described with the charge distribution (CD) model by defining a ≡NOM surface species. The interfacial charge distribution of this ≡NOM surface species can be rationalized based on calculations done with an evolved surface complexation model, known as the ligand and charge distribution (LCD) model. An adequate choice is the presence of a charge of −1 v.u. at the 1-plane and −0.5 v.u. at the 2-plane of the electrical double layer used (Extended Stern layer model).The effective interfacial NOM adsorption can be quantified by comparing the experimental phosphate concentration, measured under standardized field conditions (e.g. 0.01 M CaCl₂), with a prediction that uses the experimentally derived surface area (A) and the reversibly bound phosphate loading (Γ, μmol/m²) of the sample (part I) as input in the CD model. Ignoring the competitive action of adsorbed NOM leads to a severe under-prediction of the phosphate concentration by a factor ∼10 to 1000. The calculated effective loading of NOM is low at a high phosphate loading (Γ) and vice versa, showing the mutual competition of both constituents. Both constituents in combination usually dominate the surface loading of natural oxide fraction of samples and form the backbone in modeling the fate of other (minor) ions in the natural environment.Empirically, the effective NOM adsorption is found to correlate well to the organic carbon content (OC) of the samples. The effective NOM adsorption can also be linked to DOC. For this, a Non-Ideal Competitive adsorption (NICA) model is used. DOC is found to be a major explaining factor for the interfacial loading of NOM as well as phosphate. The empirical NOM-OC relation or the parameterized NICA model can be used as an alternative for estimating the effective NOM adsorption to be implemented in the CD model for calculation of the surface complexation of field samples. The biogeochemical impact of the NOM-PO₄ interaction is discussed.     

Theoretical calculation of equilibrium Mg isotope fractionation between silicate melt and its vapor

Isotope fractionation during the evaporation of silicate melt and condensation of vapor has been widely used to explain various isotope signals observed in lunar soils, cosmic spherules, calcium–aluminum-rich inclusions, and bulk compositions of planetary materials. During evaporation and condensation, the equilibrium isotope fractionation factor (α) between high-temperature silicate melt and vapor is a fundamental parameter that can constrain the melt’s isotopic compositions. However, equilibrium α is difficult to calibrate experimentally. Here we used Mg as an example and calculated equilibrium Mg isotope fractionation in MgSiO₃ and Mg₂SiO₄ melt–vapor systems based on first-principles molecular dynamics and the high-temperature approximation of the Bigeleisen–Mayer equation. We found that, at 2500 K, δ²⁵Mg values in the MgSiO₃ and Mg₂SiO₄ melts were 0.141?±?0.004 and 0.143?±?0.003‰ more positive than in their respective vapors. The corresponding δ²⁶Mg values were 0.270?±?0.008 and 0.274?±?0.006‰ more positive than in vapors, respectively. The general \(\alpha - T\) equations describing the equilibrium Mg α in MgSiO₃ and Mg₂SiO₄ melt–vapor systems were: \(\alpha_{{{\text{Mg}}\left( {\text{l}} \right) - {\text{Mg}}\left( {\text{g}} \right)}} = 1 + \frac{{5.264 \times 10^{5} }}{{T^{2} }}\left( {\frac{1}{m} - \frac{1}{{m^{\prime}}}} \right)\) and \(\alpha_{{{\text{Mg}}\left( {\text{l}} \right) - {\text{Mg}}\left( {\text{g}} \right)}} = 1 + \frac{{5.340 \times 10^{5} }}{{T^{2} }}\left( {\frac{1}{m} - \frac{1}{{m^{\prime}}}} \right)\), respectively, where m is the mass of light isotope ²⁴Mg and m′ is the mass of the heavier isotope, ²⁵Mg or ²⁶Mg. These results offer a necessary parameter for mechanistic understanding of Mg isotope fractionation during evaporation and condensation that commonly occurs during the early stages of planetary formation and evolution.     

Oxygen Regime of the Channel Flow in the Small Maima River,Upper Ob Basin

Water Resources - The oxygen regime of the channel flow of the small Maima River (Upper Ob basin) has been considered. A study of the spatial and seasonal variations of oxygen regime...     

PROBLEMS IN CONSTRUCTING A BATHYMETRIC BASE MAP FOR THE GULF OF FINLAND

The various steps required for compilation of a bathymetric chart of the Gulf of Finland are outlined, taking into account the specific conditions characteristic of that water body. The use of available initial source materials and special survey work required for supplementing these sources is discussed. Translated by Edward Torrey, Alexandria, VA 22308 from: Geodeziya i kartografiya, 1988, No. 8, pp. 40-42.     

Long-Term Changes in the Extreme Significant Wave Heights on the Western North Pacific: Impacts of Tropical Cyclone Activity and ENSO

Seasonal extreme wave statistics were reproduced by using the 25-km-grid global wave model of WAVEWATCH-III. The results showed that the simulated wave dataset for the present climate (1979-2009) was similar to Climate Forecast System Reanalysis (CFSR) wave data. Statistics such as the root mean squared error (RMSE) and correlation coefficient (CC) over the western North Pacific (WNP) basin were 0.5 m and 0.69 over the analysis domain. The largest trends and standard deviation were around the southern coast of Japan and western edge of the WNP. Linear regression analysis was employed to identify the relationship between the leading principal components (PCs) of significant wave heights (SWHs) in the peak season of July to September and sea surface temperature (SST) anomalies in the equatorial Pacific. The results indicated that the inter-annual variability of SWH can be associated with the El Niño-Southern Oscillation in the peak season. The CC between the first PC of the SWH and anomalies in the Nino 3.4 SST index was also significant at a 99% confidence level. Significant variations in the SWH are affected by tropical cyclones (TCs) caused by increased SST anomalies. The genesis and development of simulated TCs can be important to the variation in SWHs for the WNP in the peak season. Therefore, we can project the variability of SWHs through TC activity based on changes in SST conditions for the equatorial Pacific in the future.     

Sensitivity of Tropical Cyclone Intensity and Structure to Planetary Boundary Layer Parameterization

The advanced weather research and forecasting model is used to investigate the influence of planetary boundary layer (PBL) processes on intensity and structure of the storm Phailin (2013). Five simulations are conducted with five PBL schemes; Yonsei University (YSU), Mellor?Yamada?Nakanishi?Niino order2.5 (MYNN2), Assymetric Convective Model2 (ACM2), Medium Range Forecast (MRF), and Bougeault and Lacarrere (BouLac). The simulation duration includes the pre???intensification and rapid intensification phase of Phailin before landfall. Results indicate that during the pre???intensification phase, storm’s track and intensity are not much sensitivity to PBL but structural changes are noted. A significant sensitivity of track and intensity to PBL parameterizations are found during rapid intensification phase. BouLac and MRF produced two extremes with 39 hPa intense and 16 km compact storm for BouLac than MRF. Further analysis reveals an outward movement of air parcel just above the boundary layer which causes spin-down for YSU and MYNN2. BouLac is associated with stronger eddy diffusivity and moisture fluxes within the boundary layer and stronger cyclonic vorticity just above the boundary layer than other experiments. Stronger cyclonic vorticity above the boundary layer in BouLac favors intense updraft, facilitating more moisture transport from the boundary layer to upper layers aiding stronger secondary circulation and robustly intensifying the storm. A relatively deeper and drier inflow layer associated with weaker cyclonic vorticity just above the boundary layer reduces the moisture transport and weaken the secondary circulation for MRF than others.     

Comparison of the orientation of small-scale electron density irregularities and F region plasma flow direction

Results are shown from an experimental campaign where satellite scintillation was observed at three sites at high latitudes and, simultaneously, the F region plasma flow was measured by the nearby EISCAT incoherent scatter radar. The anisotropy parameters of field-aligned irregularities are determined from amplitude scintillation using a method based on the variance of the relative logarithmic amplitude. The orientation of the anisotropy in a plane perpendicular to the geomagnetic field is compared with the direction of F region plasma flow. The results indicate that in most cases a good agreement between the two directions is obtained.