Measurement of the redox speciation of iron in seawater by catalytic cathodic stripping voltammetry

Catalytic cathodic stripping voltammetry (CSV) preceded by adsorptive collection of complexes of 1-nitroso-2-napthol (NN) can be used to determine iron in seawater. It is shown here that iron(II) is effectively masked in the presence of 2,2-dipyridyl (Dp) so that iron(III) is measured selectively. The concentration of iron(II) is then calculated as the difference between the concentrations of reactive iron (Fe_R) in the absence and presence of 2 μM Dp, Fe_R being defined as that which was complexed by 20 μM NN at pH 6.9 in the presence of 1.8 mM H₂O₂ and 5 ppm sodium dodecyl sulphate. A 30 min reaction time was allowed for Dp to react with iron(II) in seawater prior to the determination of reactive iron(III) using the same conditions as used for Fe_R. Detection limits of 0.08 nM, 0.077 nM and 0.12 nM were obtained for Fe_R, iron(III) and iron(II), respectively, using a 60 s deposition time.The method was utilised to determine the redox speciation of iron in the northern North Sea. Concentrations of Fe_R ranged between 0.8 and 3.5 nM with nutrient-like depth profiles. Iron(II) was found to be present at concentrations up to 1.2 nM, the highest concentrations occurring in the upper 20 m of the water column.     

High‐resolution seismic monitoring of instrumented buildings using a model‐based state observer

This paper proposes a model‐based state observer to perform high‐definition response estimation in partially instrumented building structures. The proposed estimator is verified in a simulated five‐story shear‐building structure and validated using measurements from a seven‐story reinforced concrete building slice tested at the NEES‐University of California at San Diego shake table. In both cases the proposed estimator yielded satisfactory results by estimating the time history of shear forces, bending moments, displacements, and strains at various points/sections of interest. The proposed algorithm can be used in instrumented buildings for various practical applications such as post‐earthquake damage assessment, structural control, and building code calibration. Copyright © 2016 John Wiley & Sons, Ltd.     

Planetary-Scale Wave Structures of the Earth’s Atmosphere Revealed from the COSMIC Observations

GPS radio occultation（GPS RO） method,an active satellite-to-satellite remote sensing technique,is capable of producing accurate,all-weather,round the clock,global refractive index,density,pressure,and temperature profiles of the troposphere and stratosphere.This study presents planetary-scale equatorially trapped Kelvin waves in temperature profiles retrieved using COSMIC（Constellation Observing System for Meteorology,Ionosphere,and Climate） satellites during 2006-2009 and their interactions with background atmospheric conditions.It is found that the Kelvin waves are not only associated with wave periods of higher than 10 days（slow Kelvin waves） with higher zonal wave numbers（either 1 or 2）,but also possessing downward phase progression,giving evidence that the source regions of them are located at lower altitudes.A thorough verification of outgoing longwave radiation（OLR） reveals that deep convection activity has developed regularly over the Indonesian region,suggesting that the Kelvin waves are driven by the convective activity.The derived Kelvin waves show enhanced（diminished） tendencies during westward（eastward） phase of the quasi-biennial oscillation（QBO） in zonal winds,implying a mutual relation between both of them.The El Nino and Southern Oscillation（ENSO） below 18 km and the QBO features between 18 and 27km in temperature profiles are observed during May 2006-May 2010 with the help of an adaptive data analysis technique known as Hilbert Huang Transform（HHT）.Further,temperature anomalies computed using COSMIC retrieved temperatures are critically evaluated during different phases of ENSO,which has revealed interesting results and are discussed in light of available literature.     

Responses of marine phytoplankton in iron enrichment experiments in the northern North Sea and northeast Atlantic Ocean

Short-term iron enrichment experiments were carried out with samples collected in areas with different phytoplankton activity in the northern North Sea and northeast Atlantic Ocean in the summer of 1993. The research area was dominated by high numbers of pico-phytoplankton, up to 70,000 ml⁻¹. Maximum chlorophyll a concentrations varied from about 1.0 μg l⁻¹ in a high-reflectance zone (caused by loose coccoliths, remnants from a bloom of Emiliania huxleyi) and about 3.5 μg l⁻¹ in a zone in which the phytoplankton were growing, to about 0.5 μg l⁻¹ in the northeast Atlantic Ocean. From the high-reflectance zone to the northeast Atlantic Ocean, nitrate concentrations increased from 0.5 μM to 6.0 μM. Concentrations of reactive iron in surface water showed an opposite trend and decreased from about 2.6 nM in the high-reflectance zone to <1.0 nM in the northeast Atlantic Ocean. In the research area, no signs of true iron deficiency were found, but iron enrichments in the high-reflectance zone, numerically dominated by Synechococcus sp., resulted in increased nitrate uptake. Ammonium uptake was hardly affected. Strong support for the effect of Fe on cell physiology is given by the increase in the f-ratio. Net growth rates of the phytoplankton (changes in cell numbers over 24 h) were almost unchanged. Phytoplankton collected from the northeast Atlantic Ocean, did not show changes in the nitrogen metabolism upon addition of iron. Net growth rates in these incubations were low or negative, with only slightly higher values with additional iron.     

X-ray imagery and physical core logging as a proxy of the content of sediment cores in cold-water coral mound provinces: a case study from Porcupine Seabight,SW of Ireland

Three provinces, characterized by the presence of carbonate mounds interpreted as cold-water coral banks have been reported in Porcupine Seabight, SW of Ireland and were recently subjected to many detailed studies. This contribution discusses the use of X-ray imagery and physical properties in deciphering palaeoceanographic, sedimentological and biological processes. Physical property core logging and X-ray imagery are used to identify and describe sedimentation regimes and so their respective palaeoceanographic and palaeoclimatological settings in two mound provinces, respectively the Belgica mound province and the Magellan mound province. Both provinces show at present time clear differences in the hydrodynamic environment. This study confirms that also during the past the oceanographic and sedimentological environment of both provinces differ clearly. Impacts of glacial–interglacial variations and locally derived ice rafting events (IRE), comparable with the North Atlantic Heinrich events (HE) have been recognized in both provinces. Moreover, the combination of X-ray imagery, magnetic susceptibility, gamma density and P-wave velocity makes it possible to estimate the coral content and coral distribution in unopened cores localized on top of carbonate mounds. A comparison between on-mound and off-mound cores in both provinces allowed revealing some mechanisms of mound evolution and coral growth versus time.     

Geochemistry and potential use of groundwater in the Rocca Busambra area (Sicily, Italy)

In the Rocca Busambra area (mid-west Sicily, Italy), from November 1999 to July 2002, 23 water points including wells and springs were sampled and studied for their chemical and isotopic compositions. Two rain gauges were also installed at different altitudes, and rainwater was collected monthly to determine the isotopic composition. The obtained results revealed the Rocca Busambra carbonate complex as being the main recharge area on account of its high permeability value. From a chemical view point, two main groups of water can be distinguished: calcium–magnesium–bicarbonate-type and calcium–magnesium–chloride–sulphate-type waters. The first group reflects the dissolution of the carbonate rocks; the second group probably originates from circulation within flyschoid sediments. Three water wells differ from the other samples due to their relatively high Na and K content, which probably is to be referred to a marked interaction with the “Calcareniti di Corleone” formation, which is rich in glauconite [(K, Na)(Fe³⁺, Al, Mg)₂(Si, Al)₄O₁₀(OH)₂]. In accordance with WHO guidelines for drinking water (2004), almost all the samples collected can be considered drinkable, with the exception of four of them, whose NO₃ ⁻, F⁻ and Na⁺ contents exceed the limits. On the contrary, the sampled groundwater studied is basically suitable for irrigation.     

Fault structures and their geoelectric parameters in the epicentral zone of the 27 September 2003 Chuya earthquake (Gorny Altai) from resistivity data

This paper presents an integrated measurement technique based on DC methods (vertical electrical sounding, electrical resistivity tomography) which was used to identify faults and determine their geoelectric parameters in the western part of the Chuya basin. New information on the structure of the Chagan River valley located in the zone of the disastrous 27 September 2003 Chuya earthquake has been obtained from the results of these methods. Geoelectric cross-sections of the sedimentary sequence and the upper part of the basement were obtained from VES data, showing the block structure of the study area. Electrical resistivity tomography sections confirm the presence of a major fault between basement blocks of different heights and indicate the presence of faults bounding the valley on its right side and in the southwestern part.     

Catastrophic debris flows near Machu Picchu village (Aguas Calientes), Peru

Slope movements together with intensive river erosion and the following accumulation are the leading processes in the landscape evolution in the area of Machu Picchu village (former Aguas Calientes), which is located close to the Machu Picchu Sanctuary. Debris flows affect not only the bottoms of valleys or canyons, but also debris fans at the termini of the drainage basins, which are heavily inhabited at some places. The most recent event in the Machu Picchu village occurred in April 2004, but several others were documented in a broader area in the last 50 years. The field inspections at Machu Picchu (May and September 2004; June and September 2005) together with oral testimony revealed the nature and behavior of the debris flow. Machu Picchu village can be assessed as a zone with high landslide risk in relation to its urban development. Despite that, the village recorded a rapid growth (threefold population increase) without urban control within the past two decades. Precipitation, which is the main triggering factor of the debris flows, and natural hazard management of the Machu Picchu village are discussed in this paper.     

Effects of atmospheric circulation and boundary layer structure on the dispersion of suspended particulates in the Seoul metropolitan area

Summary A three-dimensional non-hydrostatic numerical model and lagrangian particle model (random walk model) were used to investigate the effects of the atmospheric circulation and boundary layer structure on the dispersion of suspended particulates in the Seoul metropolitan area. Initially, emitted particulate matter rises from the surface of the city towards the top of the convective boundary layer (CBL), owing to daytime thermal heating of the surface and the combined effect of an onshore wind with a westerly synoptic-scale wind. A reinforcing sea-valley breeze directed from the coast toward the city of Seoul, which is enclosed in a basin and bordered by mountains to its east, disperses the suspended particulate matter toward the eastern mountains. Total suspended particulate concentration (TSP) at ground level in the city is very low and relatively high in the mountains. Radiative cooling of the surface produces a shallow nocturnal surface inversion layer (NSIL) and the suspended particulate matter still present near the top of the CBL from the previous day, sinks to the surface. An easterly downslope mountain wind is directed into the metropolitan area, transporting particulate matter towards the city, thereby recycling the pollutants. The particulates descending from the top of the NSIL and mountains, combine with particulates emitted near the surface over the city at night, and under the shallow NSIL spread out, resulting in a maximum ground level concentration of TSP in the metropolitan area at 2300 LST. As those particles move toward the Yellow Sea through the topographically shaped outlet west of Seoul city under the influence of the easterly land breeze, the maximum TSP concentration occurs at the coastal site. During the following morning, onshore winds resulting from a combined synoptic-scale westerly wind and westerly sea breeze, force particulates dispersed the previous night to move over the adjacent sea and back over the inland metropolitan area. The recycled particulates combine with the particulates emitted from the surface in the central part of the metropolitan area, producing a high TSP and again rise towards the top of the CBL ready to repeat the cycle.