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951.
Catalytic cathodic stripping voltammetry (CSV) preceded by adsorptive collection of complexes of 1-nitroso-2-napthol (NN) can be used to determine iron in seawater. It is shown here that iron(II) is effectively masked in the presence of 2,2-dipyridyl (Dp) so that iron(III) is measured selectively. The concentration of iron(II) is then calculated as the difference between the concentrations of reactive iron (FeR) in the absence and presence of 2 μM Dp, FeR being defined as that which was complexed by 20 μM NN at pH 6.9 in the presence of 1.8 mM H2O2 and 5 ppm sodium dodecyl sulphate. A 30 min reaction time was allowed for Dp to react with iron(II) in seawater prior to the determination of reactive iron(III) using the same conditions as used for FeR. Detection limits of 0.08 nM, 0.077 nM and 0.12 nM were obtained for FeR, iron(III) and iron(II), respectively, using a 60 s deposition time.The method was utilised to determine the redox speciation of iron in the northern North Sea. Concentrations of FeR ranged between 0.8 and 3.5 nM with nutrient-like depth profiles. Iron(II) was found to be present at concentrations up to 1.2 nM, the highest concentrations occurring in the upper 20 m of the water column. 相似文献
952.
M. B. de Groot H. den Adel T. P. Stoutjesdijk C. J. van Westenbrugge 《Coastal Engineering》1995,26(3-4)
Flow slides may affect the stability of dikes. A flow slide is an instability of a submerged slope caused by liquefaction of loose, (medium) fine sand. Whether a flow slide will occur depends on the properties of the sand, which are a function of its density, and the geometry of the slope, as determined by wave and current induced scour and sedimentation. The influence of sand properties and the geometry parameters on the risk of flow slides are discussed. The application of a flow slide prediction method to an example and a risk analysis is briefly discussed. 相似文献
953.
Current specification of the ocean wave environment for the design of offshore platforms does not adequately describe the directional nature of a real seaway. The strong wave frequency dependent nature of the directional behavior of observed seas is often over-simplified for design. A general formulation encompassing a wide range of directional sea models is presented. Parameter values used in some of the more popular directional sea models are examined. Approximate expressions for the two frequency dependent parameters in a modified Longuet-Higgins cosine wave spreading model are presented. A general procedure which allows an engineer to estimate parameters for alternate wave spreading models is discussed. To illustrate this procedure an empirically based modified cosine spreading model is used as the basis to estimate frequency dependent parameters for circular normal and wrapped Gaussian wave spreading models. A comparison of the contours of the various directional sea models and the prediction of the root-mean-square velocity distribution is presented. 相似文献
954.
Magnetic total intensity values and bathymetric data collected on the continental margin off Saurashtra were, used to prepare magnetic anomalies and bathymetric contour maps. The magnetic anomalies are considered to have been caused by the Deccan Trap flood basalts which underlie the Tertiary sediments. Interpretation of the magnetic data using two-dimensional modelling method suggests that the magnetic basement is block faulted and deepens in steps from less than 1.0 km in the north to about 8.0 km towards the southern portion of the study area. The WNW-ESE trending faults identified in the present study extend across the Saurashtra continental margin between Porbandar and Veraval and appear to represent a major linear tectonic feature. The relationship of these fault lineaments with the regional tectonic framework have been discussed to indicate that they conform better as the northern boundary faults of the Narmada rift graben on the continental margin off Saurashtra. 相似文献
955.
A theoretical assessment is made of mean wave drift forces on groups of vertical circular cylinders, such as the columns of a floating offshore platform. A complete analytical solution is obtained for two cylinders extending from seabed to free surface, and a long wave approximation is found to provide reliable predictions of the drift force in line with the waves at low frequencies. For moderate separation between the two cylinders, this force is found to tend at low frequencies to a value four times the force on an isolated cylinder.A numerical method is employed to study two surface piercing cylinders truncated below the free surface, and an arrangement of four vertical cylinders characteristic of a floating offshore platform. The mean vertical drift force is found to be reasonably well approximated, over the frequency range of practical interest, by the force on an individual cylinder considered in isolation multiplied by the number of cylinders in the group. Interaction effects, however, have a profound influence on the total horizontal drift force. At low frequencies this force is found to tend to the force on an isolated cylinder multiplied by the squate of the number of cylinders in the group. 相似文献
956.
M.S. Kirkgz 《Coastal Engineering》1989,13(4)
Experimental investigation is made on the boundary layers of the transformation zone (i.e. the region between the last symmetrical wave profile depth and the breaking point) of plunging breakers propagating on a smooth beach with 1/12 uniform slope. Using a laser anemometer, the particle velocities are measured at four verticals along the transformation zone for three different steepnesses of waves within the plunging breaker range. The boundary layer flow in the transformation zone is found mostly of turbulent character and vertical distribution of particle velocities does not seem to conform to the classical law of the wall distribution given for steady-flow boundary layers. The results show that free-stream particle velocities, in the boundary layer of the breaker under the crest phase, increase considerably as the wave progresses towards the breaking point. The boundary layer thickness, defined as the velocity-affected region, remains constant throughout the transformation zone but it decreases with increasing deep-water wave steepness for the particular beach slope tested. 相似文献
957.
Oysters and mussels exposed to a concentration of 0·7 ppb (μg/liter) tributyltin from painted panels in flowing seawater accumulated tin in the digestive glands to comparable levels. The mussels experienced approximately 50% mortality during the 60-day test period, but the oysters suffered virtually no deaths. There was no evidence from either bivalve of elevated numbers of hemocytes during the test period and no evidence for cellular disruption as detected by increased levels of serum lysosomal hydrolases. Serum protein of exposed mussels relative to controls increased with time of exposure to the toxicant, while oyster serum protein, normally 10 x higher than in mussels, did not. No evidence was found for elevated stress proteins (heat shock proteins) or metallothioneins in the serum hemocytes of either bivalve. Responses by these animals to fatal or near fatal doses of TBT were thus very different from responses to copper that we have reported elsewhere.1,2 相似文献
958.
From the laboratory experiments and field studies it has been shown that when a wave breaks directly on a vertical wall, impact pressures of high magnitude and short duration, are produced. Despite the recent advances made in collecting data on impact pressure histories and their spatial distributions, analyses on the structural behaviour of the walls loaded by the impact forces do not seem adequate. In the present study the theoretical analysis of the response characteristics of a caisson plate, having different aspect ratios, under the wave impact loading is investigated. Numerical results for the dynamic values of moments and transverse displacements are obtained by the method of finite elements. Some prerequisite experimental data for wave breaking and resulting impact pressures are provided. The static results for moments and deflections are also computed for comparing them with the dynamic values. The dynamic results are found significantly greater than the static values. The ratio between the dynamic and static values is called “Dynamic magnification factor” that varies with plate aspect ratio. Based on this factor a procedure is proposed which may have practical consequences in the design of caisson plates. 相似文献
959.
The paper analyses results of the numerical simulation of upwelling events in the north-western part of the Black Sea, mostly
near the South Crimea. The calculations were performed using a numerical model based on primitive hydrodynamics equations.
Emphasis is laid on the case when a salinity front simulating the Black Sea rim current is prescribed in the initial conditions.
The interaction of the Black Sea rim current's stream with the coastline and bottom topography leads to the development of
an upwelling near the Crimea's coast, even in the absence of wind forcing. The paper discusses the structure of the three-dimensional
circulation of waters in the shelf area of the NW Black Sea. Numerical modelling results are matched up with the satellite
data obtained by the HRPT receiving station.
Translated by Vladimir A. Puchkin. 相似文献
960.
In the frame of the linear theory for long waves, the paper studies long waves generated by a barotropic tide running at an
arbitrary angle over a bottom ridge. The ocean is assumed to be two-layered. In the area of a ridge with a rectangular cross
section, geostrophic flows are considered, coupled with the inclinations of the free surface and interface. Wave amplitudes
are shown to depend on the angle of an onrunning tide and this allows us to reach a conclusion about the influence of a geostrophic
current on the generation of internal waves.
Translated by Vladimir A. Puchkin. 相似文献