Coulometric total carbon dioxide analysis for marine studies: maximizing the performance of an automated gas extraction system and coulometric detector

A global survey of the distribution of dissolved CO₂ taking advantage of sampling opportunities provided by the World Ocean Circulation Experiment: World Hydrographic Program (WOCE-WHP) is being carried out through 1995. Goals include the measurement of oceanic inorganic carbon transport and the development of a data base from which future fossil-fuel CO₂ build-up can be monitored. The analytical method selected for total carbon dioxide (C_T) is gas extraction of acidified seawater with coulometric titration of the acid formed by the resultant carbon dioxide and monoethanolamine. To combine high accuracy and precision (± 1.5 μmol/kg for C_T ≥ 2000 μmol/kg) with a high rate of analysis, we have modified an automated single-parameter system. Following prototype development between 1987 and 1990, an instrument emerged with the acronym Somma standing for single-operator multiparameter metabolic analyzer. Improved functional and operating procedures have integrated electronic calibration, CO₂ gas calibration, and sample analysis with automated pressure, temperature, and conductivity (salinity) sensing into a single convenient transportable package.     

The production of biogenic silica in the Weddell and Scotia Seas

During the EPOS leg 2 cruise (European Polarstern Study, November 1988–January 1989), the production rate of biogenic silica in the euphotic zone was measured by the ³⁰Si method at stations in the Scotia and Weddell Seas.The highest integrated production rates were observed in the Scotia Sea (range: 11.2–20.6 mmol Si m⁻² day⁻¹), the marginal ice zone of the Weddell Sea exhibiting somewhat lower values (range: 6.0–20.0 mmol Si m⁻²day⁻¹).Our results demonstrate that as far as biogenic silica production is concerned the marginal ice zone of the Weddell Sea is considerably less productive than that of the Ross Sea. Our results also indicate that the water of the Antarctic Circumpolar Current (ACC) could be more productive in late spring and early summer than at the beginning of spring. Possible reasons for the differences among the three subsystems (Ross Sea, Weddell Sea and ACC) are discussed.     

Errors in recent ocean tide models: possible origin and cause

Recently, the TOPEX/POSEIDON Science Working Team has recommended the FES95.2.1 and CSR3.0 ocean tide models for reprocessing the TOPEX/POSEIDON Geophysical Data Records. Without doubt, the performance of these models, especially in the deep oceans, is excellent. However, from a comparison of these hydrodynamically consistent models with the purely empirical DW3.2 and DEOS96.1 models, it appears that FES95.2.1 and CSR3.0 are affected by basin boundary related errors which are caused by the basin-wise solution procedure of the FES ocean tide model series. In their turn, the empirical DW3.2 and DEOS96.1 models seem to suffer from significant errors in the Antarctic seas due to the seasonal growth and decay of Antarctic sea ice. Also, bathymetry-induced differences were found between the hydrodynamically consistent models and the empirical models. Concerning these differences, TOPEX/POSEIDON and ERS-1 crossover statistics unfortunately do not provide conclusive results on which models are in error.     

The biokinetic behavior of Tc in juvenile Coho Salmon, Oncorhynchus kisutch (Walbaum)

Juvenile coho salmon, Onchorynchus kisutch, were exposed to ^95mTc in both saltwater and freshwater to study the biokinetic behavior of this element in an anadromous fish. In freshwater, equilibrium whole-body concentration factors (CF₅) ranged from 28 to 32 in two separate experiments, in sharp contrast to an equilibriumCF of < 5 in saltwater. While the uptake kinetics were unimodal in saltwater, in freshwater, biomodal uptake kinetics were observed.Technetium-95m retention was biphasic in freshwater depuration experiments, an initial rapid loss of 21% to 26% of the steady-state activity with an elimination half-life of 3 to 5 days was followed by a slower loss rate, with a whole-body elimination half-life ranging from 23 to 33 days. In saltwater, retention was monophasic with an elimination half-life of 5–16 days. Dramatic decreases in ^95mTc body burdens when freshwater-labeled fish are transferred to Tc-labeled saltwater indicate that the changes in physiology accompanying saltwater acclimation lead to the loss of ^95mTc.     

Adaptive balance of global development processes

We study the processes of global self-regulation of Earth’s biota (GAIA-theory) by applying the method of adaptive balance of causes proposed by the authors. By using, as an example, the Daisy World model constructed by this method, we reveal the phenomenon of preservation of the mean temperature of Earth’s surface due to the presence of the vegetation cover. We develop an integral model of global natural, social, and economic processes in which the World Ocean is one of the factors regulating the amount of greenhouse gases in the atmosphere. The decrease in the amount of greenhouse gases in the atmosphere caused by the GAIA-effects increases the number of hurricanes and floods on the Earth. As a result, the levels of ecological and social hazards for the mankind become much higher. To eliminate these threats, it is necessary to intensify the processes of self-organization of the society realized via the improvement of education, development of science, and global regulation of the competition for natural resources. We present the results of numerical experiments performed by using the model demonstrating possible scenarios of global development with regard for the processes of self-organization of the society. __________ Translated From Morskoi Gidrofizicheskii Zhurnal, No. 3, Pp. 62–80, May–June, 2007.