Migration Fractionation of Neutral Nitrogen Compounds of Crude Oils from Tabei Oilfield in the Tarim Basin, China

The absolute amounts and relative distributions of neutral nitrogen compounds in the Tabei oilfield (e. G. Blocks Ln1-Ln1 1) showed remarkable migration fractionation in the vertical direction. From Ordovician reservoirs (O) to oil legs TⅢ and T Ⅰ of Triassic reservoirs in blocks LN1-LN11, the concentrations of [a] [c] decreased from 1. 59μg/g, 0.49μg/g to 0.17 μg/g (oil). The ratios of various alkylcarbazole isomers, such as 1,8-dimethylcarbazole/nitrogenpartially shielded isomers and 1,8-dimethylcarbazole/nitrogen-exposed isomers, were adopted as the indicators of petroleum migration. The ratios increased from 0.13, 0.20 to 0.67 and from going from the south to the north of the Tabei oilfield, the absolute concentrations of neutral nitrogen compounds decreased drastically, and the nitrogen-shielded isomers were enriched relative to nitrogen-exposed isomers and nitrogen-partially shielded isomers. Crude oils in the Tabei oilfield migrated laterally from the Jilake structure to the Sangtamu fault uplift and Lunnan fault uplift, and crude oils in the same fault uplift migrated and remigrated vertically from Ordovician reservoirs, to oil legs TⅢ to TⅠ of Triassic reservoirs.     

Optimal design of viscoelastic dampers using eigenvalue assignment

In this study a procedure for determining the optimum size and location of viscoelastic dampers is proposed using the eigenvalue assignment technique. Natural frequencies and modal damping ratios, required to realize a given target response, are determined first by the convex model. Then the desired dynamic structural properties are realized by optimally distributing the damping and stiffness coefficients of viscoelastic dampers using non‐linear programming based on the gradient of eigenvalues. This optimization method provides information on the optimal location as well as the magnitude of the damper parameters. The proposed procedure is applied to the retrofit of a 10‐story shear frame, and to a three‐dimensional structure with an asymmetric plan. The analysis results confirm that the responses of model structures retrofitted by the proposed method correspond well with the given target response. Copyright © 2003 John Wiley & Sons, Ltd.     

重庆石碗溪小流域坡度和高程对土地利用及经济发展的影响

坡度和高程是土地资源固有的两个重要环境因子,与土地利用关系密切,尤其是在山区,坡度和高程基本上决定了土地利用的方向和方式,从而影响农业和经济的发展。石碗溪小流域面积20.73km2,为丘陵低山区。按坡度和高程对土地利用的影响程度,把坡度和高程各分为3级,即:0°～15°、15°~25°、>25°和500m以下、500~800 m、800m以上。从1:10 000地形圈上提取土地坡度和高程分级图,与土地利用现状图又叠加,获取各坡度、高程级及其土地利用类型和数据。结果表明,土地面积随坡度、海拔级的增加而加大。耕地分布在各个高程级0～15°的缓坡上,800m以上地区面积最大,果园和森林大多分布在800m以上>25°的陡坡地上。通过分析比较小流域各个行政村2002年农业总收入及种植业、林业、牧业收入与坡度和高程的关系,可以看出坡度和高程对经济发展的影响。最后,根据坡度和高程状况,结合小流域社会经济条件,提出几点建议,以其为山区小流域土地可持续利用及经济持续发展提供科学依据。     

中国兴凯湖北岸平原晚全新世花粉记录及泥炭沼泽形成

通过兴凯湖北岸平原泥炭剖面高分辩率花粉分析研究，对晚全新世花粉划分4个组合带。XKH-4组合时期(1857～1746aB．P．)为沼泽发育前期，这一时期花粉浓度小，陆生草本植物占优势，气候干冷。XKH-3组合时期(1746～1287aB．P．)为沼泽发育早期，这一时期花粉浓度较大，且水生植物花粉含量为剖面最高，喜温落叶阔叶植物大发展时期，气候温和湿润。XKH-2组合时期(1287～602aB．P．)为沼泽发育中期，这一时期花粉浓度最小，但以陆生草本植物为主，木本植物为辅，水生植物急剧减少，针叶植物出现两次高峰，气候向冷干方向发展。XKH-1组合时期(602aB．P．至今)为沼泽发育盛期，这一时期花粉浓度最大，陆生草本植物大发展时期，气候波动较大。     

Data Fusion in Distributed Multi-sensor System

This paper presents a data fusion method in distributed multi-sensor system including GPS and INS sensors“ data processing. First, a residual X^2-test strategy with the corresponding algorithm is designed.Then a coefficient matrices calculation method of the information sharing principle is derived. Finally, the federated Kalman filter is used to combine these independent, parallel, real-time data. A pseudolite (PL) simulation example is given.     

Probabilistic approach for active control of structures: experimental verification

In our previous study (Earthquake Engineering and Structural Dynamics 2003; 32 :2301), we have developed a probabilistic algorithm for active control of structures. In the probabilistic control algorithm, the control force is determined by the probability that the structural energy exceeds a specified target critical energy, and the direction of a control force is determined by the Lyapunov controller design method. In this paper, an experimental verification of the proposed probabilistic control algorithm is presented. A three‐story test structure equipped with an active mass driver (AMD) has been used. The effectiveness of the control algorithm has been examined by exciting the test structure using a sinusoidal signal, a scaled El Centro earthquake and a broadband Gaussian white noise; and, especially, experiments on control have been performed under different conditions to that of system identification in order to prove the stability and robustness of the proposed control algorithm. The experimental results indicate that the probabilistic control algorithm can achieve a significant response reduction under various types of ground excitations even when the modeling error exists. Copyright © 2004 John Wiley & Sons, Ltd.     

Soil respiration in tropical seasonal rain forest in Xishuangbanna, SW China

With the static opaque chamber and gas chromatography technique, from January 2003 to January 2004 soil respiration was investigated in a tropical seasonal rain forest in Xishuangbanna, SW China. In this study three treatments were applied, each with three replicates: A (bare soil), B (soil+litter), and C (soil+litter+seedling). The results showed that soil respiration varied seasonally, low from December 2003 to February 2004, and high from June to July 2004. The annual average values of CO2 efflux from soil respiration differed among the treatments at 1% level, with the rank of C (14642 mgCO2· m-2. h-1)＞B (12807 mgCO2· m-2. h-1)＞A (9532 mgCO2· m-2. h-1). Diurnal variation in soil respiration was not apparent due to little diurnal temperate change in Xishuangbanna. There was a parabola relationship between soil respiration and soil moisture at 1% level. Soil respiration rates were higher when soil moisture ranged from 35% to 45%. There was an exponential relationship between soil respiration and soil temperature (at a depth of 5cm in mineral soil) at 1% level. The calculated Q1o values in this study,ranging from 2.03 to 2.36, were very near to those of tropical soil reported. The CO2 efflux in 2003was 5.34 kgCO2· m-2. a-1 from soil plus litter plus seedling, of them 3.48 kgCO2· m-2. a-1 from soil (accounting for 62.5%), 1.19 kgCO2· m-2. a-1 from litter (22.3%) and 0.67 kgCO2·m-2. a-1 from seedling (12.5%).     

Major reactive species of ambient volatile organic compounds (VOCs) and their sources in Beijing

Volatile organic compounds (VOCs) are important precursors of atmospheric chemical processes. As a whole mixture, the ambient VOCs show very strong chemical reactivity. Based on OH radical loss rates in the air, the chemical reactivity of VOCs in Beijing was calculated. The results revealed that alkenes, accounting for only about 15% in the mixing ratio of VOCs, provide nearly 75% of the reactivity of ambient VOCs and the C4 to C5 alkenes were the major reactive species among the alkenes. The study of emission characteristics of various VOCs sources indicated that these alkenes are mainly from vehicle exhaust and gasoline evaporation. The reduction of alkene species in these two sources will be effective in photochemical pollution control in Beijing.     

Microthermometric measurement of fluid inclusions and its constraints on genesis of PGE-polymetallic deposits in Lower Cambrian black rock series, southern China

Systematic microthermometric measurements of fluid inclusions in the PGE-polymetallic deposits hosted in the Lower Cambrian black rock series in southern China were performed, and the results suggest: (1) there exist two types of fluid inclusions. TypeⅠis of NaCl-H2O system with low-medium salinity, and its homogenization temperatures (Th) and salinities are 106.9- 286.4℃ and ( 0.8- 21.8) wt%NaCl eq. respectively; TypeⅡ is of CaCl2-NaCl-H2O system with medium-high salinities, and its homogenization temperatures and salinities range from 120.1℃ to 269.6℃ and ( 11.4- 31.4) wt%NaCl eq., respectively. The typeⅡ fluid inclusions have been discovered for the first time in this kind of deposits; (2) two generations of ore-forming fluids were recognized. Characteristics of fluid inclusions in the PGE-polymetallic ores and carbonate-quartz stockworks in the underlying phosphorites are almost of no difference, they may represent ore-forming fluids at the main metallogenic stage. The peak value of homogenization temperature of those fluid inclusions is about 170℃, while their salinities possess a remarkable bimodal distribution pattern with two peak values of (27-31) wt%NaCl eq. and (4-6) wt%NaCl eq. On the contrary, fluid inclusions in the carbonate-quartz veins in the hanging wall may represent ore-forming fluids at the post-metallogenetic stage. The homogenization temperatures and the peak values of salinities are mostly 130-170℃ and (12-14) wt%NaCl eq., respectively; (3) nobel gas isotopic composition analyses in combination with the microthermometric measurements of fluid inclusions suggest that the ore-forming fluids at the main metallogenetic stage were probably derived from mixing of basinal hot brines with the CaCl2-NaCl-H2O system and seawater with the NaCl-H2O system; (4) in the Early Cambrian, the basinal hot brines were trapped in the Caledonian basins, which were distributed along the southern margin of the Yangtze Craton, and where giant thick sediments were accumulated, and expelled and migrated laterally along the strata because of the pressure caused by overlying sediments. The basinal hot brines absorbed Ni, Mo, V, PGE from the surrounding rocks and were transformed into ore-bearing hydrothermal fluids with the CaCl2-NaCl-H2O system and medium-high salinities, then ascended along faults and mixed with seawater of the NaCl-H2O system, and finally PGE-polymetallic deposits or occurrences were formed in the black rock series.     

珠江口盆地白云凹陷新生代构造演化动力学

白云凹陷构造演化史的研究对在白云凹陷开展油气勘探和深水沉积研究具有重要的意义。通过对断裂与沉积结构平面和剖面特点的分析,结合岩浆活动特点,文中提出白云凹陷是一个复式地堑,推测这种结构特点与凹陷下地壳的强烈韧性减薄和颈缩变形有关,表现为热岩石圈的伸展。其发育机制推测与白云凹陷位于构造转换带上有关,特殊的构造位置使白云凹陷成为强烈构造变形区,岩石圈地壳强烈减薄,伴随伸展过程和地幔上涌,脆性地壳或上地幔中部分熔融物质的出现导致岩石圈强度的急剧降低,在区域伸展应力场下以韧性流变方式减薄。岩浆在构造转换带下聚集并发育主岩浆房,由于白云凹陷南北边缘没有发育正断裂系统,岩浆主要沿垂直伸展的方向运移,因此在珠琼运动一幕和二幕南南东向伸展应力作用下,岩浆向白云凹陷的东部和西部运移至北西向基底深大断裂处,那里由于北西向断裂表现为左行张剪性质而成为压力较低的地区,从而成为岩浆上涌和侵位的地方。在岩浆聚集的地区,活动岩浆体附近的脆性变形被分散的韧性变形所取代,因此在凹陷的东北和西南两个角上,发育了张性和张剪性小断裂群,由于热岩石圈弹性较差,白云凹陷长期持续沉降。白云凹陷的断裂活动和沉积演化史还受到南海海盆扩张活动的影响。