Interannual variation of atmospheric CO2 concentration

A method is described for the analysis of the interannual variability of background atmospheric carbon dioxide concentration. The analysis is carried out on the data from 6 observatories for which records of >8 years were available.A global-scale interannual variation of CO₂ concentration in the troposphere with a characteristic time-scale of 2–3 years has been confirmed throughout the period of the records. These variations are estimated to be associated with carbon cycle imbalances of 2–3 Gt or annual net exchanges between the atmosphere and another carbon reservoir(s) at a rate of about 1.2 Gt of carbon per year. Lag correlations and amplitude comparisons between the records suggests a low latitude southern hemisphere origin to this phenomenon.The interannual variations of CO₂ increase are found to be correlated with those observed in data for Pacific sea surface temperatures and Pacific witd stress, the Southern Oscillation Index and the Quasi-Biennial Oscillation. However multiple regression studies found that once the Southern Oscillation index is used as an explanatory variable for CO₂ variations, the inclusion of additional geophysical variables does not give any significant improvement in the regression.     

Changes in lead and zinc lability during weathering-induced acidification of desert mine tailings: Coupling chemical and micro-scale analyses

Desert mine tailings may accumulate toxic metals in the near surface centimeters because of low water through-flux rates. Along with other constraints, metal toxicity precludes natural plant colonization even over decadal time scales. Since unconsolidated particles can be subjected to transport by wind and water erosion, potentially resulting in direct human and ecosystem exposure, there is a need to know how the lability and form of metals change in the tailings weathering environment. A combination of chemical extractions, X-ray diffraction, micro-X-ray fluorescence spectroscopy, and micro-Raman spectroscopy were employed to study Pb and Zn contamination in surficial arid mine tailings from the Arizona Klondyke State Superfund Site. Initial site characterization indicated a wide range in pH (2.5–8.0) in the surficial tailings pile. Ligand-promoted (DTPA) extractions, used to assess plant-available metal pools, showed decreasing available Zn and Mn with progressive tailings acidification. Aluminum shows the inverse trend, and Pb and Fe show more complex pH dependence. Since the tailings derive from a common source and parent mineralogy, it is presumed that variations in pH and “bio-available” metal concentrations result from associated variation in particle–scale geochemistry. Four sub-samples, ranging in pH from 2.6 to 5.4, were subjected to further characterization to elucidate micro-scale controls on metal mobility. With acidification, total Pb (ranging from 5 to 13 g kg⁻¹) was increasingly associated with Fe and S in plumbojarosite aggregates. For Zn, both total (0.4–6 g kg⁻¹) and labile fractions decreased with decreasing pH. Zinc was found to be primarily associated with the secondary Mn phases manjiroite and chalcophanite. The results suggest that progressive tailings acidification diminishes the overall lability of the total Pb and Zn pools.     

Supermagnetic enhancement,superparamagnetism, and archaeological soils

A range of mineral magnetic measurements have been carried out on archaeological sediments from Orkney and Cyprus. In a soil profile from Orkney, a magnetic enhancement factor of over 200 is observed in susceptibility data between the bedrock and a Norse sediment. The magnetic enhancement is associated with an increase in superparamagnetic grains probably caused by burning. Until now it has proved difficult to confirm the presence of superparamagnetic grains in natural samples using room temperature magnetic measurements. However, clear differences are to be found between the hysteresis loops of various magnetic domain states, including superparamagnetism. An algorithm has been developed to unmix hysteresis loops in terms of constituent domain states of ferrimagnetic iron oxides. Unmixing 128 hysteresis loops of archaeological sediments has shown that the dominant domain state in all sediments is superparamagnetic. Remarkably uniform superparamagnetic grain sizes of between 80 and 95 Å were found for all 128 sediments. © 1999 John Wiley & Sons, Inc.     

The Big Circles in Jordan: First absolute ages using rock luminescence surface dating

In this study, we provide the first absolute ages for a Big Circle megalithic structure in Jordan, using rock surface luminescence dating of the buried surface of rocks collected from circle J4 in southern Jordan. Five rocks were used for this study. All rocks showed evidence of previous daylight exposure before being used in the construction of the circle. The exposure was sufficient to bleach the latent luminescence signal to a negligible level compared to the subsequent burial dose. Three rocks gave indistinguishable ages, and were last exposed to daylight in 1500 ± 100 BCE; this is very likely to be the date of circle construction. Two others gave younger ages, indicating later disturbance or reworking. These new results provide very strong evidence for construction during the Late Bronze Age, and refute the earlier hypothesis of construction during Umayyad period (661–750 CE) as a hunting trap.     

Melting relations of some oceanic basalts

The melting relations of a group of oceanic basalts—olivine basalts, tholeiitic to midly alkaline, and high-alumina tholeiites are determined. The liquidi of these rocks follow closely the course of the temperature—iron enrichment relationship of Kilauean thoeliitic basalts, ranging from 1430°C for an olivine enriched tholeiite, to a tholeiite of liquidus temperature of 1190°C, the liquidus phase of the assemblages being either olivine or plagioclase.     

folding and slumping in a layered gabbro

The layered gabbroic intrusion of Sarqata qaqa, Ubekendt Ejland, West Greenland contains numerous xenoliths of thermally metamorphosed picrite-basalt. Folding and slumping of the layering occurs adjacent to some of these blocks. It is postulated that the structures were formed by sloped lava xenoliths hitting the unconsolidated layers of crystals forming the floor of the magma chamber during the cooling history of the intrusion. The settling velocities of the xenoliths, and thickness and viscosity of the crystal mush are estimated and discussed.