Behavior of a colluvial slope located in Southeastern Brazil

Colluvial deposits are commonly found throughout the Serra do Mar escarpment in Brazil. This article discusses predisposing geotechnical and geological factors related to the movement of a colluvium deposit located at km 29 of the Brazilian Federal Highway 116, Rio de Janeiro/RJ (BR-116/RJ). During the highway construction in mid-1976, an excavation of the toe of the slope was implemented, exacerbating preexisting movement. In order to understand the behavior of this deposit, field investigations, monitoring, and laboratory tests, as well as theoretical analyses were carried out. A subsoil survey in the area indicated the presence of a colluvium-filled paleo-thalweg. The site is located in a region with a specific geomorphology that favors significant sources of recharge to groundwater. The highly foliated rock has persistent parallel fractures, with a dip favorable to the groundwater flow in the direction of the slope. Statistical analyses were performed and good correlations were observed for rainfall, movements, groundwater table (GWT) levels, piezometer readings, and the discharge from deep horizontal drains (DHDs). The installation of the DHDs led to a GWT draw-down of 15 m, as well as reductions in movement and artesian pressure. The drains that presented the best performance were those installed in the colluvium-filled paleo-thalweg. Nevertheless, the present number of DHDs installed is not sufficient to permanently lower the GWT and stop the creep movement in the slope which was reactivated during a period of intense rainfall. Stability analysis indicates that a proper slope stability condition may be achieved by reducing the GWT level.     

Biostratigraphy,sequence stratigraphy,and paleoecology of the Lower–Middle Miocene of Northern Bandar Abbas,Southeast Zagros basin in south of Iran

The Guri Member is a limestone interval at the base of the calcareous marls of the Mishan Formation. It is the youngest hydrocarbon reservoir of the southeast part of the Zagros sedimentary basin. This Member overlaid siliciclastic rocks of Razak Formation and is overlain by green and gray marls of the Mishan Formation. In order to consider the paleoecology and paleoenvironments of the Lower–Middle Miocene (Guri Member), we have studied biostratigraphy and sequence stratigraphy of the Guri Member based on foraminifer and microfacies in two stratigraphic sections including Dorahi–Homag and Chahestan. A total of 33 genera and 56 species of benthic and planktonic foraminifera were identified in two studied stratigraphic sections. Benthic and planktonic foraminifera demonstrate Aquitanian to Langhian age (Early–Middle Miocene) for this Member at the study area. Studied interval has deposited in four facies association including supratidal, lagoon, coral reef, and open sea on a carbonate ramp. Carbonate rocks of the Guri Member have precipitated in two and three depositional sequences at Chahestan and Dorahi–Homag sections, respectively. Sedimentation of marine carbonates of the Guri Member on siliciclastic deposits reflects a major transgression of sea level at Lower to Middle Miocene that led to creating a new sea in the Zagros basin at that age. Increasing siliciclastic influx along with a sea level fall finally caused burying of the carbonate ramp. Except for the beginning of sedimentation of carbonate at the base of both stratigraphic sections (depositional sequence 1), most of the system tracts are not matched to global sea level curve that reflect local effects of the basin. Distribution of foraminifera suggests precipitation in tropical to subtropical in mesotrophic to oligotrophic and eutrophic to oligotrophic conditions. Based on large benthic foraminifera (porcelaneous large benthic foraminifera and hyaline larger benthic foraminifera), water temperature average was determined between 25 and 30 °C that was confirmed by analyzing oxygen and carbon stable isotopes. Finally, we have utilized achieved data to reconstruction and modeling of paleoecology, paleoenvironments, and sea level changes in the southeast part of the Zagros basin.     

Environmental factors influencing skeletal grain sediment associations: a critical review of Miocene examples from the western Mediterranean

The presence of foramol, rhodalgal and bryomol skeletal grain associations in ancient shallow‐marine limestones is commonly interpreted as evidence for non‐tropical palaeoclimate, despite temperature being only one of several factors influencing skeletal grain associations. Such interpretations neglect the multitude of factors other than temperature that influence carbonate‐producing biota. These include nutrients, water energy, water transparency, depth of the sea floor, salinity, oxygen, Ca²⁺ and CO₂ concentrations, Mg/Ca ratio, alkalinity, substrate requirements, competitive displacement as well as biological and evolutionary trends. This uniformitarian approach also disregards the probability that conditions of present‐day biological systems may not be representative of past conditions of analogous systems. Here, the importance of considering these other factors is illustrated through two examples of carbonate platforms in the western Mediterranean. These platforms are dominated by foramol, rhodalgal and bryomol associations of Miocene age in spite of having formed in tropical conditions. The platforms discussed are: (1) the Lower Tortonian ramp on Menorca, Balearic Islands; and (2) the Lower–Middle Miocene ramps of the central Apennines, Italy. Evidence for tropical conditions in the Mediterranean during the period of growth of these platforms is provided by species of red algae and larger foraminifera, by data from coeval continental basins and by global oxygen isotope data.     

Hydrochemistry of waters from five cenotes and evaluation of their suitability for drinking-water supplies, northeastern Yucatan, Mexico

 Waters from five cenotes that are currently being used for aquatic recreational activities and that lie along the Cancun–Tulum touristic corridor, Mexico, were evaluated hydrochemically to determine whether the cenotes may be considered as potential drinking-water sources. Several parameters exceed the Mexican Drinking Water Standards (MDWS), but since they do not pose a significant health threat, four of the five cenotes may be used as drinking-water sources. The common contaminants in the Yucatan Peninsula, fecal coliforms and nitrate, are in most cases below the MDWS (0–460 MPN/100 ml and 0.31–1.18 mg/L, respectively). Although these four cenotes meet the MDWS, a careful groundwater management policy needs to be developed to avoid contamination (fecal and nitrates) and salt-water intrusion. Received, October 1996 Revised, June 1997; March 1998 Accepted, July 1997     

Magmatic evolution of the Mantos Blancos copper deposit, Coastal Range of northern Chile: insight from Sr–Nd isotope, geochemical data and silicate melt inclusions

The Mantos Blancos copper deposit (500 Mt at 1.0% Cu) was affected by two superimposed hydrothermal events: (i) phyllic alteration related to a rhyolitic dome emplacement and brecciation at ca 155 Ma; and (ii) potassic, sodic and propylitic alteration at ca 142 Ma, coeval with stocks and sills emplacement of dioritic and granodioritic porphyries, that locally grade upwards into polymictic magmatic hydrothermal breccias. Major hypogene copper sulfide mineralization is related to the second event. A late‐ore mafic dike swarm cross‐cuts all rocks in the deposit. Two types of granodioritic porphyries can be distinguished from petrographic observations and geochemical data: granodiorite porphyry I (GP I) and granodiorite porphyry II (GP II), which resulted from two different trends of magmatic evolution. The concave shape of the rare earth element (REE) distribution pattern together with the weak or absence of negative Eu anomalies in mafic dikes, dioritic and GP I porphyries, suggest hornblende‐dominated fractionation for this magmatic suite. In contrast, distinct negative Eu anomalies and the flat REE patterns suggest plagioclase‐dominated fractionation, at low oxygen fugacity, for the GP II porphyry suite. But shallow mixing and mingling between silicic and dioritic melts are also likely for the formation of the GP II and polymictic breccias, respectively. Sr‐Nd isotopic compositions suggest that the rhyolitic dome rocks were generated from a dominantly crustal source, while the GP I has mantle affinity. The composition of melt inclusions (MI) in quartz crystals from the rhyolitic dome is similar to the bulk composition of their host rock. The MI analyzed in quartz from GP II and in the polymictic magmatic hydrothermal breccia of the deposit are compositionally more evolved than their host rocks. Field, geochemical and petrographic data provided here point to dioritic and siliceous melt interaction as an inducing mechanism for the release of hydrothermal fluids to form the Cu mineralization.     

Lithologic controls on mineralization at the Lagunas Norte high-sulfidation epithermal gold deposit, northern Peru

The 13.1-Moz high-sulfidation epithermal gold deposit of Lagunas Norte, Alto Chicama District, northern Peru, is hosted in weakly metamorphosed quartzites of the Upper Jurassic to Lower Cretaceous Chimú Formation and in overlying Miocene volcanic rocks of dacitic to rhyolitic composition. The Dafne and Josefa diatremes crosscut the quartzites and are interpreted to be sources of the pyroclastic volcanic rocks. Hydrothermal activity was centered on the diatremes and four hydrothermal stages have been defined, three of which introduced Au ± Ag mineralization. The first hydrothermal stage is restricted to the quartzites of the Chimú Formation and is characterized by silice parda, a tan-colored aggregate of quartz-auriferous pyrite–rutile ± digenite infilling fractures and faults, partially replacing silty beds and forming cement of small hydraulic breccia bodies. The δ³⁴S values for pyrite (1.7–2.2?‰) and digenite (2.1?‰) indicate a magmatic source for the sulfur. The second hydrothermal stage resulted in the emplacement of diatremes and the related volcanic rocks. The Dafne diatreme features a relatively impermeable core dominated by milled slate from the Chicama Formation, whereas the Josefa diatreme only contains Chimú Formation quartzite clasts. The third hydrothermal stage introduced the bulk of the mineralization and affected the volcanic rocks, the diatremes, and the Chimú Formation. In the volcanic rocks, classic high-sulfidation epithermal alteration zonation exhibiting vuggy quartz surrounded by a quartz–alunite and a quartz–alunite–kaolinite zone is observed. Company data suggest that gold is present in solid solution or micro inclusions in pyrite. In the quartzite, the alteration is subtle and is manifested by the presence of pyrophyllite or kaolinite in the silty beds, the former resulting from relatively high silica activities in the fluid. In the quartzite, gold mineralization is hosted in a fracture network filled with coarse alunite, auriferous pyrite, and enargite. Alteration and mineralization in the breccias were controlled by permeability, which depends on the type and composition of the matrix, cement, and clast abundance. Coarse alunite from the main mineralization stage in textural equilibrium with pyrite and enargite has δ³⁴S values of 24.8–29.4?‰ and $ {\delta^{18 }}{{\mathrm{O}}_{{\mathrm{S}{{\mathrm{O}}_4}}}} $ values of 6.8–13.9?‰, consistent with H₂S as the dominant sulfur species in the mostly magmatic fluid and constraining the fluid composition to low pH (0–2) and logfO₂ of ?28 to ?30. Alunite–pyrite sulfur isotope thermometry records temperatures of 190–260 °C; the highest temperatures corresponding to samples from near the diatremes. Alunite of the third hydrothermal stage has been dated by ⁴⁰Ar/³⁹Ar at 17.0?±?0.22 Ma. The fourth hydrothermal stage introduced only modest amounts of gold and is characterized by the presence of massive alunite–pyrite in fractures, whereas barite, drusy quartz, and native sulfur were deposited in the volcanic rocks. The $ {\delta^{18 }}{{\mathrm{O}}_{{\mathrm{S}{{\mathrm{O}}_4}}}} $ values of stage IV alunite vary between 11.5 and 11.7?‰ and indicate that the fluid was magmatic, an interpretation also supported by the isotopic composition of barite (δ³⁴S?=?27.1 to 33.8?‰ and $ {\delta^{18 }}{{\mathrm{O}}_{{\mathrm{S}{{\mathrm{O}}_4}}}} $ ?=?8.1 to 12.7?‰). The Δ³⁴S_py–alu isotope thermometry records temperatures of 210 to 280 °C with the highest values concentrated around the Josefa diatreme. The Lagunas Norte deposit was oxidized to a depth of about 80 m below the current surface making exploitation by heap leach methods viable.     

Social segregation and academic achievement in state-run elementary schools in the municipality of Campinas, Brazil

Space not only reflects social inequality, it also reinforces the advantages or disadvantages associated with social class. However, the study of how neighbourhoods affect their residents has only recently entered the debate on urban poverty in Latin America. We use 2000 data from the Brazilian population census, school census, and the state of São Paulo’s educational evaluation system to analyze the relationship between school infrastructure, school academic achievement, and the neighbourhoods in which these schools are located. Our analyses indicate that state-run elementary schools located in areas of concentrated poverty have lower academic achievement in mathematics tests and Portuguese than mixed and affluent areas of the city, even though these schools are all administered by the same government body. We end with a discussion of the relationship between Brazilian education policy and its influence on spatial differences in São Paulo State.     

Origin of the color in cobalt-doped quartz

Synthetic Co-doped quartz was grown hydrothermally in steel autoclaves at the Technological Center of Minas Gerais (CETEC), Brazil. The quartz samples, originally yellow in the as-grown state acquired blue coloration after prolonged heat treatment times at 500°C near the alpha–beta transition temperature. UV–VIS–NIR absorption spectroscopy shows the characteristic spectra of Co³⁺ before heat treatment. After heat treatment, the optical absorption spectrum is dominated by two split-triplet bands the first in the near infrared region centered at about 6,700 cm⁻¹ (1,490 nm) and the second in the visible spectral range at about 16,900 cm⁻¹ (590 nm). Both split-triplet bands are typical for Co²⁺ ions in tetrahedral coordination environments. From the absence of electron paramagnetic resonance (EPR) spectra, we conclude that the Co²⁺ found in the optical absorption spectra of the blue quartz is not due to an isolated structural site in the quartz lattice. Instead, the blue color is associated with electronic transitions of Co²⁺ in small inclusions in which the Co site has tetrahedral symmetry. The non-observation of polarization-depend optical absorption spectra is also in agreement with this model. The results for Co²⁺ in quartz are different from Co-bearing spinel and staurolite and other silicates like orthopyroxene, olivine, and beryls. The formation process of the color center is discussed.     

Magma hybridization in the Western Tatra Mts. granitoid intrusion (S-Poland, Western Carpathians)

In the Variscan Western Tatra granites hybridization phenomena such as mixing and mingling can be observed at the contact of mafic precursors of dioritic composition and more felsic granitic host rocks. The textural evidence of hybridization include: plagioclase?CK-feldspar?Csphene ocelli, hornblende- and biotite-rimmed quartz ocelli, plagioclase with Ca-rich spike zonation, inversely zoned K-feldspar crystals, mafic clots, poikilitic plagioclase and quartz crystals, mixed apatite morphologies, zoned K-feldspar phenocrysts. The apparent pressure range of the magma hybridization event was calculated at 6.1?kbar to 4.6?kbar, while the temperature, calculated by independent methods, is in the range of 810°C?770°C. U-Pb age data of the hybrid rocks were obtained by in-situ LA-MC-ICP-MS analysis of zircon. The oscillatory zoned zircon crystals yield a concordia age of 368?±?8?Ma (MSWD?=?1.1), interpreted as the age of magma hybridization and timing of formation of the magmatic precursors. It is the oldest Variscan magmatic event in that part of the Tatra Mountains.     

中国北方典型沙尘暴的遥感分析

综述了沙尘暴研究的领域和进展，提出了利用NOAA/AVHRR数据提取沙尘暴信息和沙尘暴信息密度分割的方法，经与气象数据对比验证，结果比较满意。结合沙尘暴途经区域的土地覆盖类型和植被覆盖度，对我国北方典型沙尘暴与下垫面之间的关系进行了分析，认为在同样的气象条件下，沙尘暴途经地区下垫面的土地利用/覆盖状况和植被覆盖程度决定着沙尘暴的形成与强度的变化。