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871.
Rafael Pérez-López José Miguel Nieto Israel López-Coto Juan Luis Aguado Juan Pedro Bolívar María Santisteban 《Applied Geochemistry》2010
The dynamics of trace elements from phosphate rock ore to the environment in a phosphoric acid plant located in SW Spain and the impact of phosphogypsum wastes were investigated through total digestion and BCR-sequential extraction. Based on total concentration, element transfer factors as criteria for examining the potential environmental risk of waste with respect to ore rock were calculated, and it was observed that most trace elements are only transferred into phosphogypsum at rates of 2–12%. However, based on those concentrations that are likely to be most readily mobile in the environment, phosphogypsum acts as a higher emission source of contaminants than the original rock. About 100 million tonnes of phosphogypsum are stack-piled in a dump of 1200 ha over salt-marshes of an estuary formed by the confluence of the Tinto and Odiel rivers. Phosphogypsum has been applied, at the recommended rate of 20–25 t/ha since 1978–2001, to improve fertility and reduce Na saturation in agricultural soils of the Guadalquivir river valley (140 km2). Phosphogypsum capacity as a source of mobile contaminants in three environmental scenarios (water leaching, exposure to oxidising and reducing conditions) was quantified by combining sequential extraction and waste mass. The amounts of mobile contaminants that could be released for every tonne of phosphogypsum are approximately 7 × 102 g Sr, 1.1 × 102 g Fe, 55 g Y, 30 g Ce, 12 g Cr, 11 g Ti, 5 g Zn, 4 g each of Cu and Pb, 3 g each of V and Cd, 2 g each of As and Ni and 1 g U. Multiplying these amounts by 100 Mt and 20–25 t/ha, it is possible to calculate risk assessments of phosphogypsum for both estuarine zones, e.g. in a hypothetical stack collapse and waste spilling, and agricultural soils, respectively. 相似文献
872.
Marcos García-Arias Luis Guillermo Corretgé Antonio Castro 《Mineralogy and Petrology》2010,99(3-4):153-164
Melting experiments on a gneissic protolith using the diamond trap technique produced an accumulation of crystals of biotite in the boundary of the diamond trap. Several hypotheses can be inferred to explain this feature, but textural evidence and calculations of the settling and drag velocities of the crystals suggest a model of extraction of melt due to a pressure gradient inside the capsule as the most likely origin of this biotite layer. This biotite layer and the trapped melt resemble the melanosome and leucosome, respectively, of stromatic metatexite migmatites. The melt extraction model developed is similar to the “filter pressing” model for migmatite formation. The diamond trap technique is a suitable method to develop migmatites experimentally. 相似文献
873.
Uranium minerals from the San Marcos District, Chihuahua, Mexico 总被引:1,自引:0,他引:1
Manuel Reyes-Cortés Luis Fuentes-Cobas Enrique Torres-Moye Hilda Esparza-Ponce María Elena Montero-Cabrera 《Mineralogy and Petrology》2010,99(1-2):121-132
The mineralogy of the two uranium deposits (Victorino and San Marcos I) of Sierra San Marcos, located 30 km northwest of Chihuahua City, Mexico, was studied by optical microscopy, powder X-ray diffraction with Rietveld analysis, scanning electron microscopy with energy dispersive X-ray analysis, inductively coupled plasma spectrometry, and gamma spectrometry. At the San Marcos I deposit, uranophane Ca(UO2)2Si2O7·6(H2O) (the dominant mineral at both deposits) and metatyuyamunite Ca(UO2)(V2O8)·3(H2O) were observed. Uranophane, uraninite (UO2+x), masuyite Pb(UO2)3O3(OH)·3(H2O), and becquerelite Ca(UO2)6O4(OH)6 ·(8H2O) are present at the Victorino deposit. Field observations, coupled with analytical data, suggest the following sequence of mineralization: (1) deposition of uraninite, (2) alteration of uraninite to masuyite, (3) deposition of uranophane, (4) micro-fracturing, (5) calcite deposition in the micro-fractures, and (6) formation of becquerelite. The investigated deposits were formed by high-to low-temperature hydrothermal activity during post-orogenic evolution of Sierra San Marcos. The secondary mineralization occurred through a combination of hydrothermal and supergene alteration events. Becquerelite was formed in situ by reaction of uraninite with geothermal carbonated solutions, which led to almost complete dissolution of the precursor uraninite. The Victorino deposit represents the second known occurrence of becquerelite in Mexico, the other being the uranium deposits at Peña Blanca in Chihuahua State. 相似文献
874.
Sylvia Bonilla Daniel Conde Luis Aubriot María del Carmen Pérez 《Estuaries and Coasts》2005,28(6):884-895
A survey was carried out to investigate the relationship of phytoplankton biovolume, structure, and species life strategies
with major abiotic factors in a subtropical choked coastal lagoon (34°33′S, 54°22′W) naturally connecting with the Atlantic
Ocean several times a year. Marine and limnetic influence areas were sampled on a monthly basis during two periods, one of
low rainfall and high conductivity (August 1996 to February 1998) and a second period with the opposite tendency (December
1998 to March 2000). Photosynthetically active radiation availability was high and reached the bottom (>1% of the incident
light), while dissolved inorganic nitrogen (0.6–18.4 μM), soluble reactive phosphorus (<0.3–2.7 μM), and reactive silica (5–386
μM) were highly variable. Life strategies were identified in the phytoplankton as a function of morphology. C-strategists,
invasive planktonic and epipelic species of small size, and R-strategists, mixing-dependent species of medium size, characterized
this permanently mixed system. High frequency of exchange with the ocean prevented high biomass accumulation. Phytoplankton
biomass was lower in the second period of high rainfall (2.3 and 1.1 mm3 1−1 for period 1 and 2 respectively). A canonical correspondence analysis showed that conductivity, nitrogen, phosphorus, and
silica were the main environmental variables explaining phytoplankton species composition patterns. During the first period,
Bacillariophyceae (mostly pennate species) and the potentially toxicPrococentrum minimum were dominant; during the second period a higher contribution of flagellates (Cryptophyceae, Euglenophyceae, Prasinophyceae,
and flagellates <7 μm) was found. Differences of phytoplankton biomass, main taxonomic groups, and strategies were found between
periods but not between limnic and marine areas, suggesting that hydrological dynamic is more relevant than seasonal and spatial
differences. 相似文献
875.
Avriel Venis L. Cirineo Akira Imai Ryohei Takahashi Redempta P. Baluda Noel C. Oliveros Victor B. Maglambayan Roy Ronald C. Luis Maria Lourdes M. Faustino Jacky Almadin 《Resource Geology》2021,71(1):1-40
The Southwest prospect is located at the southwestern periphery of the Sto. Tomas II porphyry copper–gold deposit in the Baguio District, northwestern Luzon, Philippines. The Southwest prospect hosts a copper‐gold mineralization related to a complex of porphyry intrusions, breccia facies, and overlapping porphyry‐type veinlets emplaced within the basement Pugo metavolcanics rocks and conglomerates of the Zigzag Formation. The occurrences of porphyry‐type veinlets and potassic alteration hosted in the complex are thought to be indications of the presence of blind porphyry deposits within the Sto. Tomas II vicinity. The complex is composed of at least four broadly mineralogically similar dioritic intrusive rocks that vary in texture and alteration type and intensity. These intrusions were accompanied with at least five breccia facies that were formed by the explosive brecciation, induced by the magmatic–hydrothermal processes and phreatomagmatic activities during the emplacement of the various intrusions. Hydrothermal alteration assemblages consisting of potassic, chlorite–magnetite, propylitic and sericite–chlorite alteration, and contemporaneous veinlet types were developed on the host rocks. Elevated copper and gold grades correspond to (a) chalcopyrite–bornite assemblage in the potassic alteration in the syn‐mineralization early‐mineralization diorite (EMD) and contemporaneous veinlets and (b) chalcopyrite‐rich mineralization associated with the chalcopyrite–magnetite–chlorite–actinolite±sericite veinlets contemporaneous with the chlorite–magnetite alteration. Erratic remarkable concentrations of gold were also present in the late‐mineralization Late Diorite (LD). High XMg of calcic amphiboles (>0.60) in the intrusive rocks indicate that the magmas have been oxidizing since the early stages of crystallization, while a gap in the composition of Al between the rim and the cores of the calcic amphiboles in the EMD and LD indicate decompression at some point during the crystallization of these intrusive rocks. Fluid inclusion microthermometry suggests the trapping of immiscible fluids that formed the potassic alteration, associated ore mineralization, and sheeted quartz veinlets. The corresponding formation conditions of the shallower and deeper quartz veinlets were estimated at pressures of 50 and 30 MPa and temperatures of 554 and 436°C at depths of 1.9 and 1.1 km. Temperature data from the chlorite indicate that the chalcopyrite‐rich mineralization associated with the chlorite–magnetite alteration was formed at a much lower temperature (ca. 290°C) than the potassic alteration. Evidence from the vein offsetting matrix suggests multiple intrusions within the EMD, despite the K‐Ar ages of the potassic alteration in EMD and hornblende in the LD of about the same age at 3.5 ± 0.3 Ma. The K‐Ar age of the potassic alteration was likely to be thermally reset as a result of the overprinting hydrothermal alteration. The constrained K‐Ar ages also indicate earlier formed intrusive rocks in the Southwest prospect, possibly coeval to the earliest “dark diorite” intrusion in the Sto. Tomas II deposit. In addition, the range of δ34S of sulfide minerals from +1.8‰ to +5.1‰ in the Southwest prospect closely overlaps with the rest of the porphyry copper and epithermal deposits in the Sto. Tomas II deposit and its vicinity. This indicates that the sulfides may have formed from a homogeneous source of the porphyry copper deposits and epithermal deposits in the Sto. Tomas II orebody and its vicinity. The evidence presented in this work proves that the porphyry copper‐type veinlets and the adjacent potassic alteration in the Southwest prospect are formed earlier and at a shallower level in contrast with the other porphyry deposits in the Baguio District. 相似文献
876.
Laura Maydagán Marta Franchini Massimo Chiaradia Verónica Bouhier Noelia Di Giuseppe Roger Rey Luis Dimieri 《地学前缘(英文版)》2017,8(5):1135-1159
We investigate the geology of Altar North (Cu–Au) and Quebrada de la Mina (Au) porphyry deposits located in San Juan Province (Argentina), close to the large Altar porphyry copper deposit (995 Mt, 0.35% Cu, 0.083 g/t Au), to present constraints on the magmatic processes that occurred in the parental magma chambers of these magmatic-hydrothermal systems. Altar North deposit comprises a plagioclase-amphibole-phyric dacite intrusion (Altar North barren porphyry) and a plagioclase-amphibole-biotite-phyric dacite stock (Altar North mineralized porphyry, 11.98 ± 0.19 Ma). In Quebrada de la Mina, a plagioclase-amphibole-biotite-quartz-phyric dacite stock (QDM porphyry, 11.91 ± 0.33 Ma) crops out. High Sr/Y ratios (92–142) and amphibole compositions of Altar North barren and QDM porphyries reflect high magmatic oxidation states (fO2 = NNO +1.1 to +1.6) and high fH2O conditions in their magmas. Zones and rims enriched in anorthite (An37–48), SrO (0.22–0.33 wt.%) and FeO (0.21–0.37 wt.%) in plagioclase phenocrysts are evidences of magmatic recharge processes in the magma chambers. Altar North and Quebrada de la Mina intrusions have relatively homogeneous isotopic compositions (87Sr/86Sr(t) = 0.70450–0.70466, εNd(t) = +0.2 to +1.2) consistent with mixed mantle and crust contributions in their magmas. Higher Pb isotopes ratios (207Pb/204Pb = 15.6276–15.6294) of these intrusions compared to other porphyries of the district, reflect an increase in the assimilation of high radiogenic Pb components in the magmas. Ages of zircon xenocrysts (297, 210, 204, 69 Ma) revealed that the magmas have experienced assimilation of Miocene, Cretaceous, Triassic and Carboniferous crustal rocks.Fluids that precipitated sulfides in the Altar deposit may have remobilized Pb from the host rocks, as indicated by the ore minerals being more radiogenic (207Pb/204Pb = 15.6243–15.6269) than their host intrusions. Au/Cu ratio in Altar porphyries (average Au/Cu ratio of 0.14 × 10?4 by weight in Altar Central) is higher than in the giant Miocene porphyry deposits located to the south: Los Pelambres, Río Blanco and Los Bronces (Chile) and Pachón (Argentina). We suggest that the increase in Au content in the porphyries of this region could be linked to the assimilation of high radiogenic Pb components in the magmas within these long-lived maturation systems. 相似文献
877.
The effects of climate change will be felt by most farmers in Europe over the next decades. This study provides consistent
results of the impact of climate change on arable agriculture in Europe by using high resolution climate data, socio-economic
data, and impact assessment models, including farmer adaptation. All scenarios are consistent with the spatial distribution
of effects, exacerbating regional disparities and current vulnerability to climate. Since the results assume no restrictions
on the use of water for irrigation or on the application of agrochemicals, they may be considered optimistic from the production
point of view and somewhat pessimistic from the environmental point of view. The results provide an estimate of the regional
economic impact of climate change, as well as insights into the importance of mitigation and adaptation policies. 相似文献
878.
Concepción Rodríguez-Puebla Ascensión H. Encinas Luis Alberto García-Casado Susana Nieto 《Climatic change》2010,100(3-4):667-684
The aims of this study are to identify the trend of warm days and cold nights over the Iberian Peninsula and to connect the variations with large-scale variables. The reasons for performing this analysis are the effects that extremes events have on different ecosystems. Here, we present the results on spatial and temporal variability of warm days (TX90), or those exceeding the 90th percentile of maximum temperature, and cold nights (TN10), or those falling below the 10th percentile of minimum temperature. The extreme indices were derived from daily observations at stations and gridded data over land area for the period 1950 to 2006. Significant trends of more warm days and fewer cold nights were found. The trend to fewer cold nights is within the interval of global results given by the IPCC AR4 report; however, the trend to warm days is greater than the corresponding global trend. The influence of large-scale variables on these extreme indices was examined by means of the Empirical Orthogonal Function, correlation, composite maps and multiple regression analyses. Changes in TX90 are connected with the Scandinavian teleconnection index and a preferred mode of geopotential height at 500 hPa over the North Atlantic. Changes in TN10 are connected with the East Atlantic teleconnection index and the leading mode of Sea Surface Temperature (SST) variability over the North Atlantic area. Based on the links between the extreme indices and the large-scale variables we derived statistical models to describe the response of TX90 and TN10 to atmospheric circulation and SST variations. The models characterized the observed variations of TX90 and TN10 reasonably well. The results of this study encourage us to analyze, in further work, how temperature extremes might change over the Iberian Peninsula under warmer climate conditions. 相似文献
879.
A Simple Method of Estimating Scalar Fluxes Over Forests 总被引:1,自引:0,他引:1
Nelson Luis Dias Jinkyu Hong Monique Y. Leclerc T. Andrew Black Z. Nesic P. Krishnan 《Boundary-Layer Meteorology》2009,132(3):401-414
A simple aerodynamic-variance method is proposed to fill gaps in continuous CO2 flux measurements in rainy conditions, when open-path analysers do not function. The method requires turbulent conditions
(friction velocity greater than 0.1 ms–1), and uses measurements of mean wind speed, and standard deviations of temperature and CO2 concentration fluctuations to complement, and at times replace, eddy-covariance measurements of friction velocity, sensible
heat flux and CO2 flux. Friction velocity is estimated from the mean wind speed with a flux-gradient relationship modified for the roughness
sublayer. Since normalised standard deviations do not follow Monin-Obukhov similarity theory in the roughness sublayer, a
simple classification scheme according to the scalar turbulence scale was used. This scheme is shown to produce sensible heat
and CO2 flux estimates that are well correlated with the measured values. 相似文献
880.
Cleivison Souza de Jesus Andre Luis Batista Ribeiro Christine Cordula Dantas 《Astronomische Nachrichten》2024,345(1):e220081
In this work, we study how to improve well-known techniques for detecting progenitors/descendants of galaxies, such as the NDpredict program, when applied to galaxies in clusters. The improvement of this particular method is based on the use of the red sequence of galaxies in those environments. Objects close to the red sequence in the color and magnitude diagram are more likely to belong to the cluster. This defines a probability scale which is then combined with the one generated by NDpredict. This procedure is optimized for the study of galaxies in clusters over different epochs. Our main result is that, for a sample composed of clusters, with masses greater than , selected from the IllustrisTNG simulations (namely, the TNG100 runs). In of the cases (i.e., systems), we obtain better performance with the red sequence method in comparison to the original NDpredict, and the average gain obtained is in the identification of descendants for this sample of cluster galaxies. 相似文献