Pliocene extensional tectonics in the Eastern Central Patagonian Cordillera: geochronological constraints and new field evidence

Recent field work and review of radiometric data obtained from Neogene lavas and plutonic rocks exposed in the Eastern Central Patagonian Cordillera (46–48ºS), which overlie subducted segments of the South Chile Ridge, suggest important Late Miocene to Pleistocene morphological changes in relation to base level variations and/or tectonic events. We present new field observations from a region south of Lago General Carrera‐Buenos Aires, between the main Cordillera and the Meseta del Lago Buenos Aires, demonstrating that normal faulting controlled valley incisions and occurred during lava emplacement at 5–4 Ma and after 3 Ma. We also show that the 12 Ma basaltic flows of the Meseta del Lago Buenos Aires (∼2000 m a.s.l.) have been subjected to deep incision, with younger lavas dated at 1.2 Ma partially filling the valleys. These incisions are thought to reflect progressive eastward tilting of the entire meseta. Our new observations, together with additional features from Central Patagonia, strongly suggest that tectonic events led to a regional widespread morphological change after 5 Ma. The coincidence in time and space between the subduction of segments of the South Chile Ridge at 6 and 3 Ma causing opening of a slab window, and strong base level variations in the studied area, suggests a cause‐and‐effect relationship. In Central Patagonia, compressional tectonics ended well before extensional events reported here. Causes of uplift and further extension are probably completely disconnected. The uplift is purely tectonic in origin and occurred prior to the subduction of the South Chile Ridge. Extension should be a consequence of this subduction.     

Beach dynamics and oscillations of shoreline position in recent years at Miramar Beach,Goa, India: a study from a GPR survey

Consideration of human influences is crucial to understanding the coastal sediment supply and associated shoreline responses prior to undertaking coastal hazard management studies. Observation of the widening of some selected Indian beaches, especially over the last 6 decades, is of significance. From this perspective, Miramar Beach, Goa, India, was studied using three ground-penetrating radar shallow subsurface profiles (4 m depth). Based on a series of depositional siliciclastic packages, six progradational packages were recognised, which were interrupted by sharp erosional boundaries. These erosional boundaries represent transgressive phases of the shoreline migration. It was observed that the shoreline migration is coupled with the deposition and erosion of sediments, and this is supported by the historical admiralty charts. The optically simulated luminescence dating of the sediments collected at the first progradation period reveals that the age corresponds to the years 1952–1957, which also corroborates the information provided by the local populace. In the past 6 decades, the shoreline growth has been rapid because of the heavy sediment influx from the Mandovi River caused by increased mining activities (since the 1950s) in upstream areas. Since the 1950s, the shoreline has prograded rapidly, building a beach from ~40 to ~280 m wide (average rate of 4 m/year) in response to enhanced sediment supply from the Mandovi River created by mining activities upstream. Superimposed on this overall regressive trend is a series of deposition and erosion cycles. Perhaps, if a similar trend continues, then there will possibly be a further widening of the beach in the future. A close monitoring network is needed to understand the causes of the cycles in shoreline position and to predict their future behaviour. The present investigation on the nature of the coastal response to anthropogenic activities in a river basin as well as the role of short-time cycles on shoreline behaviour in the last 6 decades could be an ideal reference study and motivate the search for similar areas along other coastal locations.     

Pesticides Removal by Filtration over Cactus Pear Leaves: A Cheap and Natural Method for Small‐Scale Water Purification in Semi‐Arid Regions

This study aims to examine the efficiency of Opuntia ficus‐indica for removing organochlorine pesticides from surface waters. Adsorption properties such as size, dose, and time of O. ficus‐indica for aldrin, dieldrin, and dichlorodiphenyltrichloroethane (DDT) were studied through stirring and column methods. Because of their high affinity and swelling characteristics, dried O. ficus‐indica was studied in stirring while fresh unpeeled O. ficus‐indica was applied in both stirring and column experiments and proved to be well‐suited to column application. Before removing pesticides, the column was flashed with distilled water eliminate the turbidity and smell from fresh unpeeled cactus. The removal of pesticides increased with an increasing adsorbent dose and decreased with adsorbent particle sizes. The optimum adsorbent dose is 10 g for dried and 15 g for fresh unpeeled O. ficus‐indica. The experimental results show that O. ficus‐indica possesses strong adsorption ability for aldrin, dieldrin, and DDT, and the adsorption isotherm data obeyed the Freundlich model. The results of our small‐scale experiments suggest a strong potential to develop local small‐scale water treatment units that can be used at the level of individual households or local communities, using a widely available adsorbent.     

Microscopy and rock magnetism of fine grain-size titanomagnetite from the Jacupiranga Alkaline Complex,Brazil: unearthing Ti-magnesioferrite nanoparticles

Very fine samples from the mineralized zones of the Jacupiranga complex at the Cajati mine were selected for crystallographic identification of Ti-magnesioferrite (TMf) nanostructures embedded in titanomagnetite (TM) using high-resolution transmission electron microscopy (TEM). A magnetic concentrate obtained of pyroxenite samples (sites 4 to 7) was reduced and divided into fractions of distinct range sizes: 26±2 μm, 19±1 μm, 13±1 μm, 9±1 μm, 6±1 μm and 6-0.1 μm. The mineralized samples of carbonatite and pyroxenite were characterized by X-ray diffraction, transmitted and reflected light microscope, and scanning electron microscope with multielemental analysis. The finest magnetic concentrate sample (MC₆) was analyzed under high-resolution transmitted electron microscopy (TEM) and high angle annular dark field and Raman spectroscopy. Magnetic properties were measured for the distinct granulometric fractions, showing drastic changes when grain sizes go beyond the frontier from micro to nanometer sizes. Frequency-dependent magnetic susceptibility percentage (÷_fd%) report higher values (10.2%) for the finer fractions (6±1 μm and 6-0.1 μm) attributed to dominant fractions of superparamagnetic particles. Nanometer and < 6 μm grain size TMf in TM particles require a magnetic field up to 249 mT to reach saturation during the isothermal remanent magnetization experiment. Coercivity and remanent magnetization of these samples increase when the particle size decreases, probably due to parallel coupling effects. Magnetic susceptibility versus temperature experiments were conducted two times on the same (< 35 nm) sample, showing that the repetition during the second heating is probably due to the formation of new TMf nanoparticles and growth of those already present during the first heating process.     

Metal-enriched nanoparticles and black carbon: A perspective from the Brazil railway system air pollution

Having a better understanding of air pollutants in railway systems is crucial to ensure a clean public transport. This study measured, for the first time in Brazil, nanoparticles (NPs) and black carbon (BC) on two ground-level platforms and inside trains of the Metropolitan Area of Porto Alegre (MAPA). An intense sampling campaign during thirteen consecutive months was carried out and the chemical composition of NPs was examined by advanced microscopy techniques. The results showed that highest concentrations of the pollutants occur in colder seasons and influenced by variables such as frequency of the trains and passenger densities. Also, internal and external sources of pollution at the stations were identified. The predominance of NPs enriched with metals that increase oxidative stress like Cd, Fe, Pb, Cr, Zn, Ni, V, Hg, Sn, and Ba both on the platforms and inside trains, including Fe-minerals as hematite and magnetite, represents a critical risk to the health of passengers and employees of the system. This interdisciplinary and multi-analytical study aims to provide an improved understanding of reported adverse health effects induced by railway system aerosols.     

Trend analysis of nutrient loadings in a large prairie catchment

Nutrient loadings in many river catchments continue to increase due to rapid expansion of agriculture, urban and industrial development, and population growth. Nutrient enrichment of water bodies has intensified eutrophication which degrades water quality and ecosystem health. In this study, we carried out a trend analysis of total phosphorus and total nitrogen loads in the South Saskatchewan River (SSR) catchment using a novel approach to analyse nutrient time series. Seasonal analysis of trends at each of the water quality stations was performed to determine the relationships between annual flow regimes and nutrient loads in the catchment, in particular, the influence of the high spring runoff on nutrient export. Decadal analysis was also performed to determine the long-term relationships of nutrients with anthropogenic changes in the catchment. Although it was found that seasonal and historical variability of nutrient load trends is mainly determined by streamflow regime changes, there is evidence that increases in nitrogen concentration can also be attributed to anthropogenic changes.     

Freezing as a method of sample preservation for the analysis of dissolved inorganic nutrients in seawater

It is often desirable or necessary to store collected seawater samples prior to analysis for dissolved inorganic nutrients. It is therefore important to establish preservation and storage techniques that will ensure sample integrity and will not alter the precision or accuracy of analysis. We have performed a series of experiments on the storage of nutrient samples collected at the oligotrophic North Pacific benchmark Station ALOHA, using both standard autoanalyses and low-level techniques. Our results reveal that for oligotrophic oceanic waters, the immediate freezing of an unfiltered water sample in a clean polyethylene bottle is a suitable preservation method. This procedure is simple, it avoids potentially contaminating sample manipulations and chemical additions, and it adequately preserves the concentrations of nitrate + nitrite, soluble reactive phosphate, and soluble reactive silicate within a single water sample.     

Reconstruction of fluvio-lacustrine landscapes and settlement history in the Texcoco region,Mexico, using a modern geomorphic analog

Located in the Basin of Mexico, the eastern shore of former Lake Texcoco sustained a variety of human occupations throughout the Holocene, including preceramic hunter-gatherers, incipient agriculturalists, and a variety of settlements in the ceramic periods. Nonetheless, the environmental dynamics of occupations on the lakeshore have not been fully addressed. The Archaic preagricultural Texcoco Man site (>5000 B.C.E.) and the Late Formative TX-LF-14 site (c. 550-200 B.C.E.), among others, occupy this fluvio-lacustrine transitional environment. Few stratigraphic works in and around the sites have been performed. Consequently, it is difficult to understand the dynamics of the sedimentary system in space and time. This work highlights and describes the fluvio-lacustrine sedimentary dynamics and the resulting landscape that past societies inhabited on the eastern shore of Texcoco Lake. Because the study area has been altered by historic and modern draining, our work employs Lake Santiaguillo and its main tributary, the Tejamen River in the Durango state, as a modern analog to study their sedimentary dynamics. The analyses of surface geomorphology in the Texcoco study area were employed to corroborate the modern analog interpretation. To achieve these goals, we conducted a GIS-based morphometric analysis and LANDSAT-8 imagery to study the variations in landforms through wet and dry events. The results indicate an increase in the lake volume, low bifurcation in the active fluvial channels, few inundated surfaces, and the presence of bird-foot deltaic channels during high precipitation events. In contrast, low precipitation events are characterized by reduced lake volume, increased fluvial channel bifurcation, and expanded floodplains. This heterogeneous landscape thus provided a rich source of diverse natural resources of saline and freshwater aquatic habitats. Simultaneously, constant or recurring flooding events generated a challenging landscape for prehistoric settlers who implemented diverse technologies, such as the construction of tlateles, on the levees of deltaic channels to reduce the risk and impact of flooding events.